Elastic film/fiber formulations
View Patent ↗The present invention relates to elastic film formulations that have surprisingly high tensile strengths in addition to good viscosity stability and are based on a blend of two styrene block copolymers, namely, styrene-isoprene/butadiene-styrene and styrene-butadiene-styrene. The blend of these two styrenic block copolymers in the range set forth and described herein yield high tensile strength that is at least 50% higher than that of the prior art based styrenic block copolymers and have good viscosity stability. Moreover, the present invention relates to a blend of two different styrene block copolymers that can be made by dry blending the block copolymer components. Then the blend can be extruded into uncross-linked film, fiber, or plurality of fibers.
1. An elastomeric composition, for elastic film or fiber, comprising:
a styrenic block copolymer containing from about 50 wt. % to about 75 wt. % of styrene-butadiene-styrene block copolymer, and
from about 20 wt. % to about 50 wt. % of styrene-isoprene/butadiene-styrene block copolymer, where the melt flow rates of the individual S-B-S and S-I/B-S polymers are about 5 g polymer per 10 minutes, or greater, when measured at 200° C. and 5 kg weight according to ASTM D1238; wherein said styrenic block copolymer has a butadiene content of at least about 45 wt. %,
said composition optionally further including:
0.0 to about 0.5 wt. % of a primary antioxidant;
0.0 to about 0.5 wt. % of a secondary antioxidant; and
0 to about 0.8 wt. % carbon radical scavenger;
wherein the total wt. % of all components is 100%, while said styrenic block copolymer composition exhibits a viscosity change of <25% after 30 minutes continuous exposure to nitrogen at 400° F.
2. The elastomeric composition of claim 1 , wherein said styrenic block copolymer composition has a tensile strength of at least 1600 psi.
3. The elastomeric composition of claim 1 , wherein said primary antioxidant is present in a range from 0.01 to 0.4 wt. %.
4. The elastomeric composition of claim 1 , wherein said secondary antioxidant is present in a range from 0.01 to 0.4 wt. %.
5. The elastomeric composition of claim 1 , wherein the recovered energy is at least 70% after 100% hysteresis measurement.
6. The elastomeric composition of claim 1 , wherein the permanent set is less than 10% after 100% hysteresis measurement.
7. The elastomeric composition of claim 1 , wherein the recovered energy is at least 60% after 300% hysteresis measurement.
8. The elastomeric composition of claim 1 , wherein the permanent set is less than 20% at 300% hysteresis.