Compatibilizer and blend polymer composition including the same
A blend polymer composition includes a styrene-based polymer, a non-styrene-based polymer, and a compatibilizer having a block copolymer. The block copolymer includes: a first block including a first monomer unit having an epoxy group, and a second monomer unit selected from an acrylate-based monomer unit, a methacrylate-based monomer unit, and a combination thereof; and a second block including a styrene-based monomer unit. The block copolymer has an epoxy equivalent ranging from 1000 g/eq to 20000 g/eq and a molecular weight distribution index ranging from 1.0 to 2.0.
1. A blend polymer composition, comprising:
a styrene-based polymer;
a non-styrene-based polymer; and
a compatibilizer having a block copolymer that consists essentially of:
a first block consisting of a first monomer unit which includes an unsaturated carboxylic acid glycidyl ester unit that has an epoxy group, and a second monomer unit which is free of an epoxy group, and which is selected from the group consisting of an acrylate-based monomer unit, a methacrylate-based monomer unit and a combination thereof; and
a second block including a styrene-based monomer unit and an acrylonitrile-based monomer unit;
wherein said block copolymer has an epoxy equivalent ranging from 1000 g/eq to 20000 g/eq and a molecular weight distribution index ranging from 1.0 to 2.0; and
wherein said second block is free of an epoxy group.
2. The blend polymer composition of claim 1 , wherein said styrene-based monomer unit in said second block is in an amount greater than 50 wt % based on the total weight of said second block.
3. The blend polymer composition of claim 1 , wherein said non-styrene-based polymer is selected from a group consisting of a polymer capable of reacting with an epoxy group, a methacrylate-based polymer, an acrylate-based polymer, and combinations thereof.
4. The blend polymer composition of claim 1 , wherein said non-styrene-based polymer is selected from the group consisting of polymethyl methacrylate, polymethyl acrylate, methyl methacrylate-methyl acrylate copolymer, polylactic acid, starch polymer, polycarbonate, polyamide, polyethylene terephthalate, polybutylene terephthalate, thermoplastic polyurethane, and combinations thereof.
5. The blend polymer composition of claim 1 , wherein the epoxy equivalent of said block copolymer ranges from 1000 g/eq to 10000 g/eq.
6. The blend polymer composition of claim 1 , wherein said block copolymer has a number average molecular weight ranging from 3000 to 80000, and said first block has a number average molecular weight ranging from 1000 to 55000.
7. The blend polymer composition of claim 1 , wherein the molecular weight distribution index of said block copolymer ranges from 1.0 to 1.8.
8. The blend polymer composition of claim 1 , wherein said second monomer unit is in an amount greater than 80 wt % based on the total weight of the first block.
9. The blend polymer composition of claim 1 , wherein said unsaturated carboxylic acid glycidyl ester unit is selected from a group consisting of glycidyl acrylate unit, glycidyl methacrylate unit, glycidyl ethacrylate unit, glycidyl itaconate unit, and combinations thereof.
10. The blend polymer composition of claim 1 , wherein said block copolymer is synthesized using a tellurium-containing compound to serve as an initiator.
11. The blend polymer composition of claim 1 , wherein the weight ratio of said styrene-based polymer to said non-styrene-based polymer is from 2:98 to 98:2.
12. The blend polymer composition of claim 1 , wherein the amount of said block copolymer ranges from 0.1 part to 30 parts by weight, based on 100 parts by weight of said styrene-based polymer plus said non-styrene-based polymer.
13. The blend polymer composition of claim 1 , wherein said block copolymer has a number average molecular weight ranging from 30291 to 41238.