Filtration of dangerous or undesirable contaminants
View Patent ↗Nanoparticle-treated substrates, such as screens, sand beds or proppant beds, may effectively filter and purify fluids such as waste water or fluids produced from a formation, as well as other liquids. When tiny contaminant particles in a fluid such as waste water flow contact the nanoparticle-treated substrate, the nanoparticles will capture and hold the tiny contaminant particles on the substrate due to the nanoparticles' surface forces, including, but not necessarily limited to van der Waals and electrostatic forces or other associative forces. Coating agents such as alcohols, glycols, polyols, vegetable oil, and mineral oils may help apply the nanoparticles to the surfaces of structures in the filter beds or packs.
1. A method for removing contaminants from a fluid originating from a subterranean reservoir comprising:
contacting the subterranean reservoir fluid containing contaminants of at least one type with a structure comprising a substrate and a plurality of nanoparticles coated on the substrate, where the nanoparticles:
have a mean particle size of less than 500 nm,
are selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides, piezoelectric crystals, pyroelectric crystals, and mixtures thereof, where if the contaminant comprises a metal, the metal is different than the metal in the particles, and
are present in an amount effective to at least partially remove the contaminants from the fluid; and
at least partially removing the contaminants from the subterranean reservoir fluid by an association of the nanoparticles with the contaminants.
2. The method of claim 1 where the subterranean reservoir fluid is aqueous.
3. The method of claim 1 where the substrate is selected from the group of structures consisting of proppants, gravel, beads, screens, slotted liners, packed and consolidated metal beads, foams, relative permeability additives, resins, rock formations, substrate particles having a mean particle size between about 45 to about 2000 microns, and combinations thereof.
4. The method of claim 1 where the contaminants are selected from the group consisting of sediments, soil particles, mining particles, water treatment particles, heavy metals, heavy metal compounds, heavy metal complexes, radioactive metals, radioactive compounds, radioactive complexes and combinations thereof.
5. The method of claim 4 where the heavy metal is selected from the group consisting of mercury, arsenic, cadmium, uranium, plutonium, lead, vanadium, tungsten, cobalt, copper, iron, manganese, zinc, molybdenum, selenium, and combinations thereof.
6. The method of claim 1 where in the nanoparticles:
the alkali metal is selected from the group consisting of lithium, sodium, potassium,
the alkaline earth metal is selected from the group consisting of magnesium, calcium, strontium, and barium,
the transition metal is selected from the group consisting of titanium, zirconium, cobalt, nickel, and zinc, and
the post-transition metal is aluminum, and mixtures thereof.
7. The method of claim 1 where the mean particle size of the nanoparticles is 250 nanometers or less.
8. The method of claim 1 further comprising at least partially coating the substrate with a coating agent comprising a carrier fluid selected from the group consisting of alcohol, glycol, polyol, vegetable oil, mineral oil, and combinations thereof, and the nanoparticle.
9. A method for removing contaminants from a fluid comprising:
contacting the fluid containing contaminants of at least one type with at least one nanoparticle-coated substrate, where the at least one nanoparticle-coated substrate is adjacent to or within a subterranean reservoir, where the nanoparticles:
have a mean particle size of less than 500 nm,
are selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, alkali metal oxides, alkali metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides, piezoelectric crystals, pyroelectric crystals, and mixtures thereof, where if the contaminant comprises a metal, the metal is different than the metal in the particles, and
are present in an amount effective to at least partially remove the contaminants from the fluid; and
where the substrate is selected from the group of structures consisting of proppants, gravel, beads, screens, slotted liners, packed and consolidated metal beads, foams, relative permeability additives, resins, rock formations, substrate particles having a mean particle size between about 45 to about 2000 microns, and combinations thereof; and
at least partially removing the contaminants from the fluid by an association of the nanoparticles with the contaminants, where the contaminants are selected from the group consisting of sediments, soil particles, mining particles, water treatment particles, heavy metals, heavy metal compounds, heavy metal complexes, radioactive metals, radioactive compounds, radioactive complexes and combinations thereof.
10. The method of claim 9 where the fluid is aqueous.
11. The method of claim 9 where the heavy metal is selected from the group consisting of mercury, arsenic, cadmium, uranium, plutonium, lead, vanadium, tungsten, cobalt, copper, iron, manganese, zinc, molybdenum, selenium, and combinations thereof.
12. The method of claim 9 where in the nanoparticles:
the alkali metal is selected from the group consisting of lithium, sodium, potassium,
the alkaline earth metal is selected from the group consisting of magnesium, calcium, strontium, and barium,
the transition metal is selected from the group consisting of titanium, zirconium, cobalt, nickel, and zinc, and
the post-transition metal is aluminum, and mixtures thereof.
13. The method of claim 9 where the mean particle size of the nanoparticles is 250 nanometers or less.
14. The method of claim 9 where the substrate coated with nanoparticles exists at a location selected from the group consisting of a subterranean reservoir, a wellbore adjacent the subterranean reservoir, and combinations thereof, and the fluid is produced from the subterranean reservoir.
15. The method of claim 9 further comprising at least partially coating the substrate with a coating agent comprising a carrier fluid selected from the group consisting of alcohol, glycol, polyol, vegetable oil, mineral oil, and combinations thereof, and the nanoparticles.
16. A method for removing dangerous or undesirable contaminants from a fluid produced from a subterranean reservoir, the method comprising:
placing at least one nanoparticle-coated substrate adjacent to or within the subterranean reservoir, where the nanoparticles on the substrate comprise a plurality of particles:
having an average particle size of less than 1000 nanometers, and
selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides, transition metal oxides, transition metal hydroxides, post-transition metal oxides, post-transition metal hydroxides, piezoelectric crystals, pyroelectric crystals, and mixtures thereof;
contacting the nanoparticle-coated substrate with a fluid originating from within the subterranean reservoir, where the fluid comprises:
a carrier selected from the group consisting of water, hydrocarbons, and mixtures thereof; and
at least one dangerous or undesirable contaminant; and
at least partially removing the at least one dangerous or undesirable contaminant from the fluid by an association of the nanoparticles with the contaminant.
17. The method of claim 16 where the substrate is selected from the group of structures consisting of proppants, gravel, beads, screens, slotted liners, packed and consolidated metal beads, foams, relative permeability additives, resins, rock formations, substrate particles having a mean particle size between about 45 to about 2000 microns, and combinations thereof.
18. The method of claim 16 where in the nanoparticles:
the alkali metal is selected from the group consisting of lithium, sodium, potassium,
the alkaline earth metal is selected from the group consisting of magnesium, calcium, strontium, and barium,
the transition metal is selected from the group consisting of titanium, zirconium, cobalt, nickel, and zinc, and
the post-transition metal is aluminum, and mixtures thereof.
19. The method of claim 16 where the mean particle size of the nanoparticles is 500 nanometers or less.
20. The method of claim 16 where the fluid is selected from the group consisting of water, hydrocarbons and mixtures thereof.