Perpendicular magnetic recording medium
View Patent ↗An object is to provide a perpendicular magnetic recording medium including a ground layer that prevents corrosion, while achieving a primary object of promoting finer magnetic particles of a magnetic recording layer and isolation of these magnetic particles. The structure of a perpendicular magnetic recording medium 100 according to the present invention includes, at least on a base 110 : a magnetic recording layer 122 on which a signal is recorded; a ground layer 118 provided below the magnetic recording layer; a non-magnetic layer 116 for controlling crystal orientation of the ground layer; and a soft magnetic layer 114 provided below the non-magnetic layer. The ground layer 118 is configured to have three layers including, in an order from bottom, a first ground layer 118 a and a second ground layer 118 b that contain ruthenium, and a third ground layer 118 c that contains a metal. A gas pressure at film formation by sputtering for the second ground layer 118 b is the highest among those for the above three layers.
1. A perpendicular magnetic recording medium comprising:
a base;
a magnetic recording layer formed on the base and on which a signal is recorded;
a ground layer provided below the magnetic recording layer;
a non-magnetic granular layer disposed between the magnetic recording layer and the ground layer for controlling crystal orientation of the ground layer; and
a soft magnetic layer provided below the ground layer,
wherein the ground layer is configured to have three layers including, in an order from the base, a first ground layer that contains ruthenium, a second ground layer that contains ruthenium, the second ground layer having crystal particles finer than those of the first ground layer, and a third ground layer that contains a metal and no oxygen, and
a gas pressure at film formation by sputtering for the second ground layer is the highest among those for the three layers, thereby providing a finer crystal structure in the second ground layer than in the first ground layer or third ground layer,
wherein the non-magnetic granular layer has a chemical composition different from said third ground layer.
2. The perpendicular magnetic recording medium according to claim 1 , wherein
the metal contained in the third ground layer has a hcp structure (a hexagonal close-packed crystal lattice).
3. A perpendicular magnetic recording medium comprising:
a base;
a magnetic recording layer formed on the base and on which a signal is recorded;
a ground layer provided below the magnetic recording layer;
a non-magnetic granular layer disposed between the magnetic recording layer and the ground layer for controlling crystal orientation of the ground layer; and
a soft magnetic layer provided below the ground layer,
wherein
the ground layer is configured to have three layers including, in an order from the base, a first ground layer and a second ground layer that both contain ruthenium, the second ground layer having crystal particles finer than those of the first ground layer, and a third ground layer that contains a metal, and
a gas pressure at film formation by sputtering for the second ground layer is the highest among those for the three layers,
wherein the non-magnetic granular layer has a chemical composition different from said third ground layer,
wherein the metal contained in the third ground layer is selected from ruthenium, a chromium-tantalum alloy, and a chromium-titanium alloy and the third ground layer contains no oxygen.
4. A perpendicular magnetic recording medium comprising:
a base;
a magnetic recording layer formed on the base and on which a signal is recorded;
a ground layer provided below the magnetic recording layer;
a non-magnetic granular layer disposed between the magnetic recording layer and the ground layer for controlling crystal orientation of the ground layer; and
a soft magnetic layer provided below the ground layer,
wherein
the ground layer is configured to have three layers including, in an order from the base, a first ground layer and a second ground layer that both contain ruthenium, the second ground layer having crystal particles finer than those of the first ground layer, and a third ground layer that contains a metal, and
a gas pressure at film formation by sputtering for the second ground layer is the highest among those for the three layers,
wherein the non-magnetic granular layer has a chemical composition different from said third ground layer,
wherein the gas pressures at film formation are 1 Pa for the first ground layer, 3.5 Pa for the second ground layer, and 0.5 Pa to 0.6 Pa for the third ground layer and the gas at film formation of the first ground layer and the third ground layer contains no oxygen.
5. A perpendicular magnetic recording medium comprising:
a base;
a magnetic recording layer formed on the base and on which a signal is recorded;
a ground layer provided below the magnetic recording layer;
a non-magnetic granular layer disposed between the magnetic recording layer and the ground layer for controlling crystal orientation of the ground layer; and
a soft magnetic layer provided below the ground layer,
wherein
the ground layer is configured to have three layers including, in an order from the base, a first ground layer and a second ground layer that both contain ruthenium, the second ground layer having crystal particles finer than those of the first ground layer, and a third ground layer that contains a metal, and
a gas pressure at film formation by sputtering for the second ground layer is the highest among those for the three layers,
wherein the non-magnetic granular layer has a chemical composition different from said third ground layer, wherein
the third ground layer has a film thickness of 1 nm to 1.5 nm.
6. The perpendicular magnetic recording medium according to claim 2 , wherein
the gas pressures at film formation are 1 Pa for the first ground layer, 3.5 Pa for the second ground layer, and 0.5 Pa to 0.6 Pa for the third ground layer and the gas at film formation of the first ground layer and the third ground layer contains no oxygen.
7. The perpendicular magnetic recording medium according to claim 3 , wherein
the gas pressures at film formation are 1 Pa for the first ground layer, 3.5 Pa for the second ground layer, and 0.5 Pa to 0.6 Pa for the third ground layer and the gas at film formation of the first ground layer and the third ground layer contains no oxygen.
8. The perpendicular magnetic recording medium according to claim 2 , wherein
the third ground layer has a film thickness of 1 nm to 1.5 nm.
9. The perpendicular magnetic recording medium according to claim 3 , wherein
the third ground layer has a film thickness of 1 nm to 1.5 nm.
10. The perpendicular magnetic recording medium according to claim 4 , wherein
the third ground layer has a film thickness of 1 nm to 1.5 nm.
11. The perpendicular magnetic recording medium according to claim 6 , wherein
the third ground layer has a film thickness of 1 nm to 1.5 nm.
12. The perpendicular magnetic recording medium according to claim 7 , wherein
the third ground layer has a film thickness of 1 nm to 1.5 nm.
13. The perpendicular magnetic recording medium according to claim 1 , wherein the second ground layer contains oxygen.
14. The perpendicular magnetic recording medium according to claim 3 , wherein the second ground layer contains oxygen.
15. The perpendicular magnetic recording medium according to claim 4 , wherein the gas at film formation of the second ground layer contains oxygen.
16. The perpendicular magnetic recording medium according to claim 6 , wherein the gas at film formation of the second ground layer contains oxygen.
17. The perpendicular magnetic recording medium according to claim 7 , wherein the gas at film formation of the second ground layer contains oxygen.
18. A perpendicular magnetic recording medium comprising:
a base;
a magnetic recording layer formed on the base and on which a signal is recorded;
a ground layer provided below the magnetic recording layer;
a non-magnetic layer disposed between the magnetic recording layer and the ground layer for controlling crystal orientation of the ground layer; and
a soft magnetic layer provided below the non-magnetic layer,
wherein
the ground layer is configured to have three layers including, in an order from the base, a first ground layer and a second ground layer that both contain ruthenium, and a third ground layer that contains a metal, and
a gas pressure at film formation by sputtering for the second ground layer is the highest among those for the three layers,
wherein the third ground layer has a density greater than a density of the second ground layer.
19. The perpendicular magnetic recording medium according to claim 1 , wherein the non-magnetic granular layer comprises Si.
20. The perpendicular magnetic recording medium according to claim 1 , wherein the non-magnetic granular layer comprises a substance selected from the group comprising SiOx, Cr, Cr 2 O 3 , TiO 2 , ZrO 2 and Ta 2 O 5 .
21. The perpendicular magnetic recording medium according to claim 1 , wherein the magnetic recording layer contains an oxide.
22. The perpendicular magnetic recording medium according to claim 1 , wherein the non-magnetic granular layer contains no oxides.
23. The perpendicular magnetic recording medium according to claim 1 , wherein the non-magnetic granular layer contains no ruthenium.
24. The perpendicular magnetic recording medium according to claim 5 , wherein
the metal contained in the third ground layer has a hcp structure (a hexagonal close-packed crystal lattice).
25. The perpendicular magnetic recording medium according to claim 5 , wherein
the metal contained in the third ground layer is selected from ruthenium, a chromium-tantalum alloy, and a chromium-titanium alloy and the third ground layer contains no oxygen.
26. The perpendicular magnetic recording medium according to claim 5 , wherein
the gas pressures at film formation are 1 Pa for the first ground layer, 3.5 Pa for the second ground layer, and 0.5 Pa to 0.6 Pa for the third ground layer and the gas at film formation of the first ground layer and the third ground layer contains no oxygen.