Digitally prepared stamp masters and methods of making the same
Positive and negative stamp masters derived from UV curable ink molds comprising ultraviolet (UV) curable inks and methods for digitally preparing those stamp masters. In particular, the digitally prepared molds provide a method of printing micropatterns of fine variable features or images in a more efficient manner than the methods currently available.
1. A method for digitally forming a mold for embossing or printing micropatterns comprising: inkjetting a first ultraviolet curable solid ink onto a first substrate to form a positive mold; radiation curing of the positive mold adding an elastomeric composition in a layer over the cured positive mold; inkjetting a second ultraviolet curable ink onto the elastomeric layer; curing the elastomeric layer and the second ultraviolet curable ink over the cured positive mold to form a negative mold; and removing the cured negative mold from the cured positive mold; wherein the ultraviolet curable ink comprises: an ink vehicle; a gellant; one or more waxes; and a photo initiator.
2. The method of claim 1 , wherein the positive mold is the master mold.
3. The method of claim 1 , wherein the negative mold is the master mold.
4. The method of claim 1 , wherein the elastomeric composition comprises an ultraviolet curable solid ink composition or a composition comprising a silicon resin and curing agent.
5. The method of claim 4 , wherein the elastomeric composition comprises an ultraviolet curable solid ink composition which is the same as or different from the ultraviolet curable solid ink composition of the positive mold.
6. The method of claim 1 , wherein the step of inkjetting the ultraviolet curable solid ink is performed multiple times in sequential order.
7. The method of claim 6 , wherein the step of inkjetting the ultraviolet curable solid ink is performed from about 1 to about 500 times in sequential order.
8. The method of claim 1 , wherein the positive mold has a thickness of from about 0.3 mm to about 0.7 mm.
9. The method of claim 1 , wherein the negative mold has a thickness of from about 0.3 mm to about 0.7 mm.
10. The method of claim 1 , wherein the step of inkjetting the ultraviolet curable solid ink is performed over a period of time from about 30 seconds to about 10 minutes.
11. The method of claim of claim 1 , wherein the step of curing the positive mold further comprises exposing the positive mold to radiation at a wavelength of from about 200 nanometers to about 480 nanometers.
12. The method of claim 1 , wherein the step of curing the positive mold further comprises exposing the positive mold to radiation for from about 0.2 second to about 30 seconds, or from about 1 second to 15 seconds.
13. The method of claim 1 , wherein the step of inkjetting the ultraviolet curable solid ink is performed by an inkjet printer.
14. The method of claim 1 , wherein the step of curing the elastomeric composition is performed at a temperature of about 20 to about 90° C. for about 15 to about 120 minutes.
15. A method for digitally forming a mold for embossing or printing micropatterns comprising: inkjetting a first ultraviolet curable solid ink onto a first substrate to form a positive mold; radiation curing of the positive mold; casting a film of or inkjetting an elastomeric composition in a layer over the cured positive mold; inkjetting a second ultraviolet curable ink onto the elastomeric layer; curing the elastomeric composition and the second ultraviolet curable ink over the cured positive mold to form a negative mold; and removing the cured negative mold from the cured positive mold; wherein the ultraviolet curable ink comprises: an ink vehicle; a gellant; one or more waxes; and a photoinitiator.
16. A method for embossing or printing micropatterns comprising: inkjetting an ultraviolet curable solid ink onto a first substrate to form a positive mold; radiation curing of the positive mold; casting a film of or inkjetting an elastomeric composition in a layer over the cured positive mold; curing the elastomeric composition over the cured positive mold to form a negative mold; removing the cured negative mold from the cured positive mold; and applying the positive mold or negative mold to a second substrate to form an embossing or micropattern; wherein the ultraviolet curable ink comprises: an ink vehicle; a gellant; one or more waxes; and a photo initiator.
17. The method of claim 16 , wherein the first substrate is selected from the group consisting of plain papers, ruled notebook paper, bond paper, silica coated papers, transparency materials, fabrics, textile products, plastics, polymeric films, metals, woods and mixtures thereof.
18. The method of claim 16 , wherein the second substrate is selected from the group consisting of plastics, polymeric films, metals, woods and mixtures thereof.