Adhesive composition, and polarizing plates and LCDs utilizing the adhesive composition
The present invention relates to a pressure-sensitive adhesive composition, and a polarizer and a liquid crystal display (LCD) device using the pressure-sensitive adhesive composition, and more particularly, to a pressure-sensitive adhesive composition including (A) an acrylic copolymer and (B) a liquid optically-anisotropic compound having a mesogen core in its structure. The liquid optically-anisotropic compound having a mesogen core in its structure according to the present invention has superior solubility and compatibility with pressure-sensitive adhesive resin, and thus the pressure-sensitive adhesive composition including the liquid optically-anisotropic compound can relax stress caused by shrinkage of the polarizer and effectively compensate negative birefringence. Therefore, the polarizer and the LCD device using the pressure-sensitive adhesive composition can prevent light leakage originating from stress concentration in spite of long-term use.
1. A pressure-sensitive adhesive composition, comprising:
(A) an acrylic copolymer having a weight-average molecular weight of 1,200,000 to 2,000,000; and
(B) a liquid optically-anisotropic compound containing a mesogen core in a structure thereof,
wherein the liquid optically-anisotropic compound has a melting point of less than room temperature and the mesogen core comprises tolan,
wherein the mesogen core is represented by the following Formula:
2. The pressure-sensitive adhesive composition of claim 1 , wherein the acrylic copolymer comprises 70 to 99.9 parts by weight of alkyl(meth)acrylic acid ester monomer having an alkyl group of 1 to 14 carbon atoms relative to 100 parts by weight of overall acrylic copolymer monomer content.
3. The pressure-sensitive adhesive composition of claim 2 , wherein the alkyl(meth)acrylic acid ester monomer is one or more selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, butyl (meth)acrylate, t-butyl (meth)acrylate, pentyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, isononyl (meth)acrylate, lauryl (meth)acrylate, tetradecyl (meth)acrylate.
4. The pressure-sensitive adhesive composition of claim 1 , wherein the acrylic copolymer comprises a vinyl monomer represented by the following Formula 1 in a content of less than 20 parts by weight relative to 100 parts by weight of overall acrylic copolymer monomer content:
where R 1 represents hydrogen or alkyl,
R 2 represents cyano, phenyl unsubstituted or substituted with alkyl, acetyloxy, or COR 3 ; and
R 3 represents amino unsubstituted or substituted with alkyl or alkoxy, or glycidyloxy.
5. The pressure-sensitive adhesive composition of claim 1 , wherein the acrylic copolymer comprises 0.1 to 10 parts by weight of a crosslinking functional group-containing monomer relative to 100 parts by weight of overall acrylic copolymer monomer content.
6. The pressure-sensitive adhesive composition of claim 5 , wherein the crosslinking functional group-containing monomer is one or more selected from the group consisting of a hydroxyl group-containing monomer, a carboxyl group-containing monomer, and a nitrogen-containing monomer.
7. The pressure-sensitive adhesive composition of claim 6 , wherein the hydroxyl group-containing monomer is one or more selected from the group consisting of 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 2-hydroxyethyleneglycol (meth)acrylate, and 2-hydroxypropyleneglycol (meth)acrylate.
8. The pressure-sensitive adhesive composition of claim 6 , wherein the carboxyl group-containing monomer is one or more selected from the group consisting of (meth)acrylic acid, acrylic acid dimer, itaconic acid, and maleic acid.
9. The pressure-sensitive adhesive composition of claim 6 , wherein the nitrogen-containing monomer is one or more selected from the group consisting of acryl amide, N-vinyl pyrrolidone, and N-vinyl caprolactam.
10. The pressure-sensitive adhesive composition of claim 1 , wherein the content of the liquid optically-anisotropic compound containing the mesogen core in the structure thereof (B) is 5 to 30 parts by weight with respect to 100 parts weight of the acrylic copolymer.
11. The pressure-sensitive adhesive composition of claim 1 , further comprising 0.01 to 5 parts by weight of a multifunctional crosslinking agent with respect to 100 parts by weight of the acrylic copolymer (A).
12. The pressure-sensitive adhesive composition of claim 11 , wherein the multifunctional crosslinking agent is one or more selected from the group consisting of an isocyanate compound, an epoxy compound, an aziridine compound, and a metal chelate compound.
13. The pressure-sensitive adhesive composition of claim 1 , further comprising 0.005 to 5 parts by weight of a silane coupling agent with respect to 100 parts by weight of the acrylic copolymer (A).
14. The pressure-sensitive adhesive composition of claim 1 , further comprising 1 to 100 parts by weight of tackifier resin with respect to 100 parts by weight of the acrylic copolymer (A).
15. A polarizer comprising:
a polarization film; and
a pressure-sensitive adhesive layer formed by the pressure-sensitive adhesive composition according to claim 1 on one side or both sides of the polarization film.
16. The polarizer of claim 15 , wherein the polarizer comprises one or more layers selected from the group consisting of a protective layer, a reflective layer, a phase retardation film, a compensation film for wide view angle, and a brightness enhancing film.
17. A liquid crystal display (LCD) device comprising a liquid crystal panel in which the polarizer according to claim 15 is attached onto one side or both sides of a liquid crystal cell.