Hydroxyl-functionalised polyurethane hot melt prepolymer
View Patent ↗The invention relates to hydroxyl-functionalised polyurethane hot melt prepolymers comprising the chemical reaction product of isocyanate-reactive starting materials with at least one isocyanate-containing starting material. Said prepolymers are characterized in that the isocyanate-reactive starting materials of the hydroxyl-functionalised polyurethane hot melt prepolymers have a polypropylene glycol with a functionality higher than two and a number-average molar mass higher than or equal to 3,000 g/mol, a polypropylene glycol with a functionality less than or equal to two and a number-average molar mass less than or equal to 1,000 g/mol, and a chain lengthener with a functionality less than or equal to 500 g/mol, and the isocyanate-containing starting material of the hydroxyl-functionalised polyurethane hot melt prepolymer has an aliphatic or alicyclic diisocyanate.
1. A hydroxyl-functionalized polyurethane hotmelt prepolymer comprising the chemical reaction product of isocyanate-reactive starting materials with at least one isocyanate-containing starting material, wherein the isocyanate-reactive starting materials of the hydroxyl-functionalized polyurethane hotmelt prepolymer comprise at least one polypropylene glycol PI having a functionality of more than two and a number-average molar mass of greater than or equal to 3000 g/mol, at least one polypropylene glycol PII having a functionality of less than or equal to two and a number-average molar mass of less than or equal to 1000 g/mol, and at least one chain extender KI having a functionality of less than or equal to two and a number-average molar mass of less than or equal to 400 g/mol, and wherein the isocyanate-containing starting material of the hydroxyl-functionalized polyurethane hotmelt prepolymer comprises an aliphatic or alicyclic diisocyanate.
2. The hydroxyl-functionalized polyurethane hotmelt prepolymer as claimed in claim 1 , wherein the numerical fraction of the hydroxyl groups that are introduced to form the hydroxyl-functionalized polyurethane hotmelt prepolymer and that originate from the polypropylene glycol PI is at least 2.5%.
3. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 wherein the number-average molar mass of the polypropylene glycol PI is greater than or equal to 4500 g/mol.
4. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 wherein the number-average molar mass of the polypropylene glycol PII is less than or equal to 800 g/mol.
5. The hydroxyl-functionalized polyurethane hotmelt prepolymer as claimed in claim 1 wherein the aliphatic or alicyclic diisocyanate comprises isophorone diisocyanate or dicyclohexylmethane diisocyanate.
6. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 wherein the ratio of the total number of isocyanate groups to the total number of hydroxyl groups of the substances involved in the chemical reaction to give the hydroxyl-functionalized polyurethane hotmelt prepolymer is between greater than or equal to 0.80 and less than or equal to 0.98.
7. A process for preparing a hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 wherein the chemical reaction to give the hydroxyl-functionalized polyurethane hotmelt prepolymer takes place with addition of a catalyst comprising bismuth and carbon.
8. A pressure sensitive adhesive comprising a hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 .
9. An adhesive tape carrier material comprising a hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 .
10. A method for producing polyurethane moldings or polyurethane layers comprising the steps of reacting the hydroxyl functionalized polyurethane hotmelt prepolymer according to claim 1 with one or more polyisocyanates to make a reaction product and shaping the reaction product.
11. The method according to claim 10 wherein the reaction product of the polyurethane hotmelt prepolymer with the polyisocyanate or polyisocyanates possesses pressure-sensitively adhesive properties.
12. The method according to claim 10 wherein the reaction of the polyurethane hotmelt prepolymer with the polyisocyanate or polyisocyanates takes place solventlessly in the melt.
13. The method according to claim 10 wherein the reaction of the polyurethane hotmelt prepolymer with the polyisocyanate or polyisocyanates takes place in a continuously operating mixing assembly.
14. The method according to claim 10 wherein the reaction time of the polyurethane hotmelt prepolymer with the polyisocyanate or polyisocyanates prior to shaping does not exceed 10 minutes.
15. The hydroxyl-functionalized polyurethane hotmelt prepolymer as claimed in claim 2 wherein the numerical fraction of the hydroxyl groups that are introduced to form the hydroxyl-functionalized polyurethane hotmelt prepolymer and that originate from the polypropylene glycol PI is between 5% to 20%.
16. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 wherein number-average molar mass of the polypropylene glycol PI is greater than or equal to 5500 g/mol.
17. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 4 wherein the number-average molar mass of the polypropylene glycol PII is less than or equal to 600 g/mol.
18. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 6 wherein the ratio of the total number of isocyanate groups to the total number of hydroxyl groups of the substances involved in the chemical reaction to give the hydroxyl-functionalized polyurethane hotmelt prepolymer is between greater than or equal to 0.90 and less than or equal to 0.96.
19. The process according to claim 7 wherein the catalyst comprises bismuth carboxylate or a bismuth carboxylate derivative.
20. The hydroxyl-functionalized polyurethane hotmelt prepolymer according to claim 1 wherein the chain extender KI has a number-average molar mass of less than or equal to 200 g/mol.