Insecticidal formulations with improved long-term effect on surfaces
View Patent ↗The present invention relates to compositions for the control of pests, in particular insecticidal suspension concentrates and spray solutions made from them, to processes for their preparation, and to the use of such formulations for the sustained control of animal pests (arthropods) on a variety of surfaces. The present invention furthermore relates to the use of certain polymer dispersions in pesticides, in particular to their use for extending the long-term activity of these compositions when they are applied to surfaces. The present invention furthermore relates to the use of the compositions according to the invention for controlling parasites, in particular ectoparasites, in animals.
1. A suspension concentrate composition comprising
at least one insecticide,
a nonionic and/or ionic dispersant, and
a grafted aqueous polymer dispersion,
wherein the insecticide is deltamethrin or beta-cyfluthrin,
wherein the polymer dispersion is prepared by radical-initiated emulsion copolymerization in the presence of a hydrocolloid comprising starch as a grafting base, of a monomer mixture comprising
a) 30 to 60% by weight, based on the monomer mixture weight, of at least one styrene or substituted styrene,
(b) 60 to 30% by weight, based on the monomer mixture weight, of at least one C1-C4-alkyl (meth)acrylate, and
(c) 0 to 10% by weight, based on the monomer mixture weight, of other ethylenically unsaturated copolymerizable monomers,
and wherein the starch (d) employed is 10 to 40% by weight of degraded starch with a molar weight M n =500 to 10 000, the total of (a)+(b)+(c)+(d) being 100%, and the radical-initiator employed for the radical-initiated emulsion polymerization is a graft-active, water-soluble redox system,
and wherein the polymer dispersion after drying has a glass transition temperature of 40° C. to 80° C.
2. The composition according to claim 1 , wherein the polymer dispersion at a concentration of 0.025% by weight in demineralized water at a wavelength of 535 nm and a path length of 1 cm has an absorbance of not more than 2.0.
3. A method for controlling pests comprising employing the composition according to claim 1 for controlling pests.
4. The method according to claim 3 comprising treating a surface with a deposition rate of 1.0 mg/m 2 to 2000 mg/m 2 polymer based on solids content.
5. An aqueous grafted polymer dispersion suitable for use in a pesticide which,
in demineralized water at a concentration of 0.025% by weight based on the solids content, has an absorbance, measured in a 1 cm cell at 535 nm, of <2.0 and
after drying has a glass transition temperature of 40° C. to 800° C.,
wherein the pesticide is deltamethrin or beta-cyfluthrin,
wherein the polymer dispersion is prepared by radical-initiated emulsion copolymerization in the presence of a hydrocolloid comprising starch as a grafting base, of a monomer mixture comprising
a) 30 to 60% by weight, based on the monomer mixture weight, of at least one styrene or substituted styrene,
(b) 60 to 30% by weight, based on the monomer mixture weight, of at least one C1-C4-alkyl (meth)acrylate, and
(c) 0 to 10% by weight, based on the monomer mixture weight, of other ethylenically unsaturated copolymerizable monomers,
and wherein the starch (d) employed is 10 to 40% by weight of degraded starch with a molar weight M n =500 to 10 000, the total of (a)+(b)+(c)+(d) being 100%, and the radical-initiator employed for the radical-initiated emulsion polymerization is a graft-active, water-soluble redox system.
6. A medicament comprising a composition according to claim 1 suitable for controlling ectoparasites in animals.
7. A method of extending the efficacy of a pesticide comprising adding a grafted polymer dispersion to a composition comprising said pesticide prior to application, which polymer dispersion, at a concentration of 0.025% by weight in demineralized water at a wavelength of 535 nm and a path length of 1 cm, has an absorbance of less than 2.0,
wherein the insecticide is deltamethrin or beta-cyfluthrin,
wherein the polymer dispersion is prepared by radical-initiated emulsion copolymerization in the presence of a hydrocolloid comprising starch as a grafting base, of a monomer mixture comprising
a) 30 to 60% by weight, based on the monomer mixture weight, of at least one styrene or substituted styrene,
(b) 60 to 30% by weight, based on the monomer mixture weight, of at least one C1-C4-alkyl (meth)acrylate, and
(c) 0 to 10% by weight, based on the monomer mixture weight, of other ethylenically unsaturated copolymerizable monomers,
and wherein the starch (d) employed is 10 to 40% by weight of degraded starch with a molar weight M n =500 to 10 000, the total of (a)+(b)+(c)+(d) being 100%, and the radical-initiator employed for the radical-initiated emulsion polymerization is a graft-active, water-soluble redox system.
8. The composition of claim 1 , wherein said at least one insecticide is deltamethrin.
9. The composition of claim 1 , wherein said insecticide is partially embedded on a surface by a layer of said polymer dispersion formed between said insecticide and said surface.
10. The composition of claim 1 , wherein said composition demonstrates longer-lasting insecticidal activity on both porous and non-porous surfaces than an identical composition without said polymer dispersion.
11. The composition of claim 1 , wherein said composition demonstrates longer-lasting insecticidal activity on an animal than an identical composition without said polymer dispersion.
12. The method according to claim 3 comprising treating a surface with a deposition rate of 5 mg/m 2 to 200 mg/m 2 polymer based on solids content.
13. The composition of claim 1 , wherein the C1-C4-alkyl (meth)acrylate comprises n-butyl acrylate and t-butyl acrylate.
14. The composition according to claim 1 , wherein in concentrated formulations, the amount of insecticide is between 0.01 to 40% by weight, and the amount polymer dispersion is between 1 and 50% by weight.
15. The composition according to claim 1 , wherein in ready-to-use compositions, the amount of insecticide is between 0.001 and 0.5% by weight, and the amount of polymer dispersion is between 0.002 and 1% by weight.
16. The composition of claim 1 , wherein said at least one insecticide is beta-cyfluthrin.