IP Library Granted Patent US 8,663,817
Granted Patent B2
US 8,663,817 · App. 12/994,965 · Granted Mar 4, 2014

Aluminum alloy strips for brazed heat exchanger tubes

Inventors: Sylvain Henry (Saint Jean de Moirans, FR); Elodie Perrin (Voiron, FR)
Assignee: Constellium France
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Quick Facts
Patent No.
US 8,663,817
App. No.
12/994,965
Granted
Mar 4, 2014
Kind
B2
Abstract

A brazing sheet made up of a core sheet made of aluminum alloy covered on at least one side with a layer of cladding forming a sacrificial anode. The layer of cladding is formed of an aluminum alloy of chemical composition, in % by weight: Si: >2.0-7.0; Fe<0.5; Cu<1.0; Mn: 1.0-2.0; Mg<0.5; Zn: 1.0-3.0; Cr<0.25; Ni<1.5; Ti<0.25; Co<1.5; V, In, Sn, Zr, Sc<0.25 each; other elements <0.05 each and 0.15 in total. A heat exchanger tube may be produced by folding and brazing from the brazing sheet, where the layer of cladding forms a sacrificial anode constituting the lining of the tube or “inner-liner.”

Claims (79)

1. Brazing sheet made up of a core sheet made of aluminum alloy clad on at least one side with a layer of cladding forming a sacrificial anode, characterized in that said layer of cladding consists of an aluminum alloy of chemical composition, expressed as percentages by weight:

Si: greater than 2.0 and up to 7.0;

Fe: less than 0.3;

Cu: less than 1.0;

Mn: 1.0 to 2.0;

Mg: less than 0.5;

Zn: 1.0 to 3.0;

Cr: less than 0.25;

Ni: less than 1.5;

Ti: less than 0.25;

Co: less than 1.5;

V, In, Sn, Zr, and Sc: less than 0.25 each;

other elements: less than 0.05 each and 0.15 in total;

wherein the remainder is aluminum.

2. Brazing sheet according to claim 1 , characterized in that the Cu content of the layer of cladding is lower than 0.8%.

3. Brazing sheet according to claim 1 , characterized in that the Cu content of the layer of cladding is lower than 0.05%.

4. Brazing sheet according to claim 1 , characterized in that the Mg content of the layer of cladding is lower than 0.3%.

5. Brazing sheet according to claim 1 , characterized in that the Mg content of the layer of cladding is lower than 0.05%.

6. Brazing sheet according to claim 1 , characterized in that the Mg content of the layer of cladding is lower than 0.01%.

7. Brazing sheet according to claim 1 , characterized in that the Zn content of the layer of cladding lies between 1.5 and 2.5%.

8. Brazing sheet according to claim 1 , characterized in that the layer of cladding is applied only to one side of the core sheet made of an aluminum alloy of the AA3xxx series.

9. Brazing sheet according to claim 8 , characterized in that the other side of the core sheet is clad with a layer of aluminum brazing alloy of the AA4xxx series.

10. Brazing sheet according to claim 9 , characterized in that the various layers of cladding, brazing and core sheet are assembled by co-rolling.

11. Heat exchanger tube made by folding and brazing from a brazing sheet according to claim 1 , characterized in that the layer of cladding forming a sacrificial anode constitutes the lining of the tube or “inner-liner.”

12. Brazing sheet made up of a core sheet made of aluminum alloy clad on at least one side with a layer of cladding forming a sacrificial anode, characterized in that said layer of cladding consists of an aluminum alloy of chemical composition, expressed as percentages by weight:

Si: 3.0 to 5.0;

Fe: less than 0.5;

Cu: less than 1.0;

Mn: 1.0 to 2.0;

Mg: less than 0.5;

Zn: 1.0 to 3.0;

Cr: less than 0.25;

Ni: less than 1.5;

Ti: less than 0.25;

Co: less than 1.5;

V, In, Sn, Zr, and Sc: less than 0.25 each;

other elements: less than 0.05 each and 0.15 in total;

wherein the remainder is aluminum.

13. Brazing sheet according to claim 12 , characterized in that the Si content of the layer of cladding lies between 3.0 and 4.0%.

14. Brazing sheet according to claim 12 , characterized in that the Cu content of the layer of cladding is lower than 0.8%.

15. Brazing sheet according to claim 12 , characterized in that the Cu content of the layer of cladding is lower than 0.05%.

16. Brazing sheet according to claim 12 , characterized in that the Mg content of the layer of cladding is lower than 0.3%.

17. Brazing sheet according to claim 12 , characterized in that the Mg content of the layer of cladding is lower than 0.05%.

18. Brazing sheet according to claim 12 , characterized in that the Mg content of the layer of cladding is lower than 0.01%.

19. Brazing sheet according to claim 12 , characterized in that the Zn content of the layer of cladding lies between 1.5 and 2.5%.

20. Brazing sheet according to claim 12 , characterized in that the layer of cladding is applied only to one side of the core sheet made of an aluminum alloy of the AA3xxx series.

21. Brazing sheet according to claim 20 , characterized in that the other side of the core sheet is clad with a layer of aluminum brazing alloy of the AA4xxx series.

22. Brazing sheet according to claim 21 , characterized in that the various layers of cladding, brazing and core sheet are assembled by co-rolling.

23. Brazing sheet according to claim 12 , characterized in that the layer of cladding is applied only to one side of a core sheet made of alloy 3915.

24. Brazing sheet according to claim 12 , characterized in that the layer of cladding is applied only to one side of a core sheet made of alloy 3916.

25. Heat exchanger tube made by folding and brazing from a brazing sheet according to claim 12 , characterized in that the layer of cladding forming a sacrificial anode constitutes the lining of the tube or “inner-liner.”

26. Brazing sheet made up of a core sheet made of aluminum alloy clad on at least one side with a layer of cladding forming a sacrificial anode, characterized in that said core sheet consists of alloy 3915, and said layer of cladding consists of an aluminum alloy of chemical composition, expressed as percentages by weight:

Si: greater than 2.0 and up to 7.0;

Fe: less than 0.5;

Cu: less than 1.0;

Mn: 1.0 to 2.0;

Mg: less than 0.5;

Zn: 1.0 to 3.0;

Cr: less than 0.25;

Ni: less than 1.5;

Ti: less than 0.25;

Co: less than 1.5;

V, In, Sn, Zr, and Sc: less than 0.25 each;

other elements: less than 0.05 each and 0.15 in total;

wherein the remainder is aluminum.

27. Brazing sheet made up of a core sheet made of aluminum alloy clad on at least one side with a layer of cladding forming a sacrificial anode, characterized in that said core sheet consists of alloy 3916, and said layer of cladding consists of an aluminum alloy of chemical composition, expressed as percentages by weight:

Si: greater than 2.0 and up to 7.0;

Fe: less than 0.5;

Cu: less than 1.0;

Mn: 1.0 to 2.0;

Mg: less than 0.5;

Zn: 1.0 to 3.0;

Cr: less than 0.25;

Ni: less than 1.5;

Ti: less than 0.25;

Co: less than 1.5;

V, In, Sn, Zr, and Sc: less than 0.25 each;

other elements: less than 0.05 each and 0.15 in total;

wherein the remainder is aluminum.

Assignments (6)
CHANGE OF ADDRESS Recorded Oct 2, 2015
From: CONSTELLIUM NEUF-BRISACH SAS
To: CONSTELLIUM NEUF-BRISACH SAS
Reel/Frame 036744/0341 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2015
From: CONSTELLIUM FRANCE SAS
To: CONSTELLIUM NEUF-BRISACH SAS
Reel/Frame 036437/0381 →
CHANGE OF NAME Recorded Jan 5, 2012
From: ALCAN RHENAULU SAS
To: CONSTELLIUM FRANCE
Reel/Frame 027701/0227 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 31, 2011
From: RIO TINTO ALCAN INTERNATIONAL LIMITED
To: ALCAN RHENALU SAS
Reel/Frame 026106/0115 →
CHANGE OF NAME Recorded Mar 30, 2011
From: ALCAN INTERNATIONAL LIMITED
To: RIO TINTO ALCAN INTERNATIONAL LIMITED
Reel/Frame 026087/0938 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 13, 2010
From: HENRY, SYLVAIN; PERRIN, ELODIE
To: ALCAN INTERNATIONAL LIMITED
Reel/Frame 025485/0587 →
Priority Claims (1)
FR 08 03018 · Jun 2, 2008 · national
Continuity (1)
Related Publication 20110100615A1 · May 5, 2011