Trench capacitor and method for producing the same
View Patent ↗A method of fabricating a trench capacitor, and a trench capacitor fabricated thereby, are disclosed. The method involves the use of a vacuum impregnation process for a sol-gel film, to facilitate effective deposition of high-permittivity materials within a trench in a semiconductor substrate, to provide a trench capacitor having a high capacitance while being efficient in utilization of semiconductor real estate.
1. A method of fabricating a trench capacitor comprising the steps of:
(a) forming a trench in a substrate
(b) depositing a layer of an electrically conductive material in the trench,
(c) depositing a layer of a material having a high electrical permittivity within the trench by vacuum infiltration of a sol-gel precursor, the sol-gel precursor material comprising the material having a high electrical permittivity,
(d) depositing a further layer of electrically conductive material in the trench, and
(e) heating the substrate to anneal the layers.
2. A method according to claim 1 , wherein the material has an electrical permittivity of at least 8 and is a ferroelectric material or a ferroic material.
3. A method according to claim 1 , wherein the material is a Perovskite material.
4. A method according to claim 3 , wherein the material is selected from the group consisting of PZT, PLZT and BST.
5. A method according to claim 1 wherein the substrate is silicon, step (a) comprises dry etching of the silicon through an etch-mask and an oxide layer is provided to line the sidewalls and base of the trench prior to step (b).
6. A method according to claim 1 , wherein the trench has width which is between about 1 μm and about 10 μm and a high aspect ratio such that it has a depth which is between twice and twenty times its width.
7. A method according to claim 1 wherein an adhesion layer is deposited subsequent to step (a) and preceding step (b).
8. A method according to claim 1 , wherein step (c) is carried out a plurality of times prior to step (d).
9. A method according to claim 1 , wherein the sequence of steps (c) and (d) is repeated at least once, to achieve a stacked capacitor.
10. A method according to claim 1 , wherein the substrate is cleaned between steps (c) and (d) by any one of more of wiping with a swab, shaking, or evaporation under vacuum or wiping whilst in an inverted orientation.
11. A method according to claim 1 , wherein step (d) comprises subjecting the substrate to a first environment of between about 150° C. and about 300° C. for between 1 and 2 minutes, followed by subjecting it to a second environment of between about 300° C. and about 700° C. for between about 5 and about 10 minutes.
12. A method according to claim 10 , wherein at least one of the first and second environment has a controlled oxygen level associated with it.
13. A method according to claim 1 , wherein the layer of electrically conductive material and the further layer of electrically conductive material each comprise one of LNO, palladium or platinum.