Method for producing catalyst reforming tar-containing gas, method for reforming tar and method for regenerating catalyst for reforming tar-containing gas
The present invention provides a method for producing a highly active catalyst for reforming tar-containing gas used to treat crude gas for chemical energy conversion consisting of converting to a fuel composition consisting mainly of methane, hydrogen and the like, by utilizing sensible heat possessed by crude gas generated during thermal decomposition of carbonaceous raw materials, and using the high chemical reaction activity of high-temperature tar contained in and incidental to the crude gas to convert the tar to light hydrocarbons in the presence of a catalyst; a tar reforming method; and, a method for regenerating a catalyst for reforming tar-containing gas.
1. A method for producing a catalyst for reforming tar-containing gas, the method comprising:
adding a precipitating agent to a mixed solution of a nickel compound and a magnesium compound, thus co-precipitating nickel and magnesium, and forming a precipitate;
adding alumina powder and water or an alumina sol to the precipitate and mixing, thus forming a mixture,
drying the mixture; and
baking the mixture, thus producing a catalyst,
wherein the precipitating agent causes the pH of the mixed solution to change to neutral or basic pH at which nickel and magnesium precipitate, and
wherein a temperature of the baking is within the range of 700 to 1300° C.
2. The method for producing a catalyst for reforming tar-containing gas according to claim 1 , the method further comprising at least one of calcining, crushing, and molding the mixture.
3. A method for producing a catalyst for reforming tar-containing gas, the method comprising:
adding a precipitating agent to a mixed solution of a nickel compound and a magnesium compound, thus co-precipitating nickel and magnesium, and forming a precipitate;
adding alumina powder and water or an alumina sol to the precipitate and mixing, thus forming a mixture,
drying the mixture; and
baking the mixture, thus producing a catalyst,
wherein the precipitating agent causes the pH of the mixed solution to change to neutral or basic pH at which nickel and magnesium precipitate, and
wherein the catalyst for reforming tar-containing gas has a nickel content of 1 to 50% by weight, a magnesium content of 5 to 45% by weight, and an alumina content of 20 to 80% by weight.
4. The method for producing a catalyst for reforming tar-containing gas according to claim 3 , wherein the catalyst for reforming tar-containing gas has a nickel content of 1 to 35% by weight, a magnesium content of 10 to 25% by weight, and an alumina content of 20 to 80% by weight.
5. A method for producing a catalyst for reforming tar-containing gas, the method comprising:
adding a precipitating agent to a mixed solution of a nickel compound and a magnesium compound, thus co-precipitating nickel and magnesium, and forming a precipitate;
adding alumina powder and water or an alumina sol to the precipitate and mixing, thus forming a first mixture,
drying and calcining the first mixture,
adding the alumina powder and the water or the alumina sol to the dried and calcined first mixture and mixing, thus forming a second mixture,
drying the second mixture; and
baking the second mixture, thus producing a catalyst,
wherein the precipitating agent causes the pH of the mixed solution to change to neutral or basic pH at which nickel and magnesium precipitate.
6. The method for producing a catalyst for reforming tar-containing gas according to claim 5 , the method further comprising at least one of calcining, crushing, and molding the second mixture.
7. The method for producing a catalyst for reforming tar-containing gas according to claim 5 , wherein the catalyst for reforming tar-containing gas has a nickel content of 1 to 50% by weight, a magnesium content of 5 to 45% by weight, and an alumina content of 20 to 80% by weight.
8. The method for producing a catalyst for reforming tar-containing gas according to claim 7 , wherein the catalyst for reforming tar-containing gas has a nickel content of 1 to 35% by weight, a magnesium content of 10 to 25% by weight, and an alumina content of 20 to 80% by weight.