Liquid crystal composition and liquid crystal display device
View Patent ↗The subject is to provide a liquid crystal composition that satisfies at least one characteristic of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a negatively large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced regarding two characteristics thereof. The subject is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The invention provides a liquid crystal composition having a negative dielectric anisotropy that includes a specific four-ring compound replaced by fluorine having a high maximum temperature as a first component, and a specific compound having a negatively large anisotropy as a second component, and provides a liquid crystal display device containing the composition.
1. The invention concerns a liquid crystal composition having a negative dielectric anisotropy that includes two components, wherein the first component is at least one compound selected from the group of compounds represented by formulas (1), the second component is at least one compound selected from the group of compounds represented by formulas (2):
wherein R 1 , R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 4 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons; one of X 1 and X 2 is oxygen and the other is fluorine; ring A is independently 1,4-cyclohexylene or 1,4-phenylene, arbitrary one —CH 2 — in 1,4-cyclohexylene may be replaced by —O—; Z 1 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; and m is 1 or 2.
2. The liquid crystal composition according to claim 1 , wherein the ratio of the first component is from approximately 5% by weight to approximately 30% by weight, and the ratio of the second component is from approximately 30% by weight to approximately 95% by weight, based on the total weight of liquid crystal composition.
3. The liquid crystal composition according to claim 1 , that in addition to a first, a second component, further includes at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 5 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring B and ring C are each independently 1,4-cyclohexylene or 1,4-phenylene; Z 2 is a single bond, ethylene, methyleneoxy or carbonyloxy.
4. The liquid crystal composition according to claim 3 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1):
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
5. In the above formula (1-1) of the first component, the liquid crystal composition according to claim 4 , wherein at least one of R 1 and R 2 is one compound selected from the group of compounds represented by alkenyl having 2 to 12 carbons.
6. The liquid crystal composition according to claim 3 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to (2-7):
wherein R 3 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 4 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons.
7. The liquid crystal composition according to claim 3 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to (3-3):
wherein R 5 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons; R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
8. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1).
9. The liquid crystal composition according to claim 3 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1), the second component is at least one compound selected from the group of compounds represented by formula (2-1) to (2-7), and the third component is at least one compound selected from the group of compounds represented by formula (3-1):
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 is alkyl having 1 to 12 carbons or alkenyl having 2 to 12 carbons; R 4 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons; R 5 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons; R 6 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
10. The liquid crystal composition according to claim 3 , wherein a ratio of the first component is from 5% by weight to 30% by weight, a ratio of the second component is from 30% by weight to 80% by weight, and a ratio of the third component is from 5% by weight to 50% by weight, based on the total weight of the liquid crystal composition.
11. The liquid crystal composition according to claim 3 , that in addition to a first, second, and third component and further includes at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 7 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons; R 8 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons; ring D and ring E are each independently 1,4-cyclohexylene, 1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 3 is a single bond, ethylene, methyleneoxy or carbonyloxy.
12. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by the formula (4-1) to (4-3):
wherein R 7 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons; R 8 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, or alkenyl having 2 to 12 carbons.
13. The liquid crystal composition according to claim 12 , wherein the fourth component is at least one compound selected from the group of compounds represented by the formula (4-1).
14. The liquid crystal composition according to claim 11 , wherein a ratio of the fourth component is from 5% by weight to 30% by weight, based on the total weight of the liquid crystal composition.
15. The liquid crystal composition according to claim 1 , wherein the composition has a maximum temperature of a nematic phase of 70° C. or more, an optical anisotropy (25° C.) at a wavelength of 589 nm of 0.08 or more, and a dielectric anisotropy (25° C.) at a frequency of 1 kHz of −2 or less.
16. A liquid crystal device display that includes the liquid crystal composition according to claim 1 .
17. The liquid crystal composition according to claim 16 , wherein the liquid crystal display device has an operation mode of a VA mode, an IPS mode or a PSA mode, and has a driving mode of an active matrix mode.