DECOMPOSITION OF MATERIALS CONTAINING CARBOHYDRATES USING INORGANIC CATALYSTS
The invention relates to a method for depolymerizing materials containing carbohydrates comprising the following steps: (a) treating a material containing carbohydrates with an inorganic catalyst in order to release defined monomeric or oligomeric building blocks from the material containing the carbohydrates; and (b) separating the defined monomeric or oligomeric building blocks produced in step (a) from the rest of the carbohydrate-containing material. Preferably, the inorganic catalyst used in step (a) comprises tectosilicates, phyilosilicates or hydrotalcites and more preferably zeolites or bentonites. The carbohydrate-containing material further comprises preferably LCB and the defined monomeric or oligomeric building blocks are preferably glucoses, xyloses, arabinoses and oligomers thereof. Other aspects of the invention refer to the use of solution promoters in combination with the inorganic catalyst.
1 . Method for treating a carbohydrate-containing material with an inorganic catalyst, comprising the following steps:
a. treating the carbohydrate-containing material with an inorganic catalyst in order to release defined monomeric or oligomeric building blocks from the carbohydrate-containing material;
b. separating the defined monomeric or oligomeric building blocks produced in step a. from the rest of the carbohydrate-containing material.
2 . Method according to claim 1 , wherein tectosilicates, phyllosilicates or hydrotalcite are used as the catalyst.
3 . Method according to one of the preceding claims, wherein zeolites or bentonites are used as the catalyst.
4 . Method according to one of the preceding claims, wherein doped inorganic catalysts are used.
5 . Method according to one of the preceding claims, wherein the carbohydrate-containing material is preliminarily treated in at least one physical, chemical or physicochemical step.
6 . Method according to one of the preceding claims, wherein the treatment of the carbohydrate-containing material is carried out with an inorganic catalyst in a solvent system.
7 . Method according to claim 6 , wherein the solvent system contains at least one solubilizer.
8 . Method according to one of the preceding claims, wherein the solvent system contains at least one acid, in particular a strong inorganic acid, more preferably hydrochloric acid.
9 . Method according to claim 8 , wherein the quantity of acid in the solvent system lies between approximately 0.1 and 5% by weight, more preferably between approximately 0.5 and 2% by weight relative to the total quantity of solvent system.
10 . Use of an inorganic catalyst, selected from the group comprising tectosilicates, phyllosilicates, hydrotalcites and mixtures thereof for the treatment, in particular the depolymerisation of a carbohydrate-containing material.