Tire with a tread comprising an SNBR elastomer
View Patent ↗The present invention relates to a tire having a tread comprising a rubber composition that comprises at least: as a first diene elastomer, between 5 and 25 phr of a styrene-nitrile-butadiene terpolymer (SNBR) having a nitrile monomer content between 4 and 18% by weight; a second diene elastomer other than SNBR; a reinforcing filler; a liquid plasticizer, the glass transition temperature of which is below −20° C. The invention makes it possible to improve the properties of rolling resistance and of grip on wet ground of tire treads.
1. A tire having a tread comprising a rubber composition that comprises at least:
as a first diene elastomer between 5 and 25 phr of a styrene-nitrile-butadiene terpolymer (SNBR) having a nitrile monomer content between 4 and 18% by weight;
a second diene elastomer other than SNBR;
a reinforcing filler;
a liquid plasticizer, the glass transition temperature (T g ) of which is below −20° C.
2. The tire according to claim 1 , wherein the second diene elastomer is chosen from the group consisting of polybutadienes, natural rubber, synthetic polyisoprenes, butadiene copolymers, isoprene copolymers and mixtures of these elastomers.
3. The tire according to claim 2 , wherein the second diene elastomer is a styrene-butadiene copolymer (SBR).
4. The tire according to claim 3 , wherein the SBR content is between 75 and 95 phr.
5. The tire according to claim 1 , wherein the SNBR content is less than 20 phr.
6. The tire according to claim 5 , wherein the SNBR content is between 5 and 15 phr.
7. The tire according to claim 1 , wherein the nitrile monomer content of the SNBR is between 5 and 15% by weight.
8. The tire according to claim 1 , wherein the reinforcing filler comprises carbon black and/or silica.
9. The tire according to claim 1 , wherein the reinforcing filler is present in an amount between 20 and 200 phr.
10. The tire according to claim 9 , wherein the amount of reinforcing filler is between 30 and 150 phr.
11. The tire according to claim 1 , wherein the liquid plasticizer having a T g below −20° C. is chosen from the group consisting of naphthenic oils, paraffinic oils, MES oils, TDAE oils, ester plasticizers, phosphate plasticizers and mixtures of these compounds.
12. The tire according to claim 1 , wherein the rubber composition further comprises a hydrocarbon resin having a T g above 0° C.
13. The tire according to claim 12 , wherein the hydrocarbon resin is chosen from the group consisting of cyclopentadiene (abbreviated to CPD) or dicyclopentadiene (abbreviated to DCPD) homopolymer or copolymer resins, terpene homopolymer or copolymer resins, C 5 fraction homopolymer or copolymer resins and mixtures of these resins.
14. The tire according to claim 1 , wherein the nitrile monomer is acrylonitrile.