Process for the preparation of an artificial latex
View Patent ↗Accordingly, the invention provides a process for the preparation of an artificial latex, comprising the steps: (a) emulsification of a cement comprising a rubber dissolved in a suitable organic solvent, together with an aqueous surfactant solution, thus forming an oil-in-water emulsion; (b) step-wise reduction of the solvent content of the oil-in-water emulsion in two or more stages resulting in an artificial latex. In addition, the invention provides a continuous stirred vessel for removing an organic solvent from an oil-in-water emulsion comprising rubber dissolved in an organic solvent.
1. Process for the preparation of an artificial latex, comprising the steps:
(a) emulsification of a cement comprising a rubber dissolved in a suitable organic solvent, together with an aqueous surfactant solution, thus forming an oil-in-water emulsion;
(b) step-wise reduction of the solvent content of the oil-in-water emulsion in two or more stages resulting in an artificial latex characterized in that in stage 1 of step (b) part of the solvent is removed via use of a reboiling loop by mixing part of the artificial latex, heated to a temperature above the boiling point of the solvent with the oil-in-water emulsion and allowing the solvent to evaporate, said artificial latex and the oil-in-water emulsion are mixed in a weight ratio of at least 20:1.
2. The process as claimed in claim 1 , wherein the artificial latex and the emulsion are mixed in a volume ratio such that the solvent content of the combined mixture is at most 5% by weight (5% w).
3. The process as claimed in claim 1 , wherein a foam control agent is used in one or more stages of step (b) to reduce foaming.
4. The process as claimed in claim 1 , wherein a continuous stirred vessel is utilized, which is equipped with a stirring means, a feed inlet, a vent outlet and a product outlet, wherein the feed inlet and the product outlet are part of a reboiling loop for recycling part of the artificial latex, wherein the reboiling loop further comprises a product discharge outlet, optionally an inlet for a foam control agent, a circulation pump, a heating means, an inlet for the oil-in-water emulsion, and optionally a steam-inlet.
5. A The process as claimed in claim 1 , wherein the emulsion has an initial solvent content in the range of from 50 to 60% w, based on the entire emulsion.
6. A The process as claimed in claim 1 , wherein the artificial latex prepared in stage 1 of step (b) has a reduced solvent content vis-à-vis the initial content, in the range of from 0.05 to 3% w, based on the entire emulsion.
7. The process as claimed in claim 1 , wherein the artificial latex at the end of step (b) has a solvent content of less than 150 ppm.
8. The process as claimed in claim 1 , wherein the first stage of step (b) is conducted by stripping the solvent under elevated temperature and about atmospheric pressure conditions, above the boiling point of the solvent but below the boiling point of water, at a temperature in the range of 50-85 degrees Centigrade, at 0 to 100 millibar gauge.
9. The process as claimed in claim 4 , wherein the reboiling loop is equipped with a heat exchanger as heating means, upstream of the joint combining the recycled artificial latex and the oil-in-water emulsion.
10. The process as claimed in claim 9 , wherein the heat exchanger increases the temperature of the recycled artificial latex by 2 to 10 degrees Centigrade.
11. The process as claimed in claim 1 , carried out at a temperature sufficient to reduce the solvent content of the emulsion in stage 1 of step (b) to a range of from 0.5 to 1.0% w.
12. The process as claimed in claim 11 , carried out at a temperature of from 75 to 85 degrees Centigrade.
13. The process as claimed in claim 1 , carried out at a temperature sufficient to reduce the solvent content of the emulsion in stage 1 of step (b) to a range of from 1.0 to 3.0% w.
14. The process as claimed in claim 13 , carried out at a temperature of from 50 to 70 degrees Centigrade.
15. The process as claimed in claim 1 , wherein the second stage of step (b) is conducted by stripping the solvent under elevated temperature and reduced pressure conditions, above the boiling point of the solvent but below the boiling point of water, at a temperature from 70 to 85 degrees Centigrade, and a reduced pressure from 200 to 600 millibars.
16. The process as claimed in claim 1 , wherein the rubber is isoprene rubber.
17. The process as claimed in claim 1 , wherein the amount of rubber dissolved in the solvent is less than about 20 percent by weight.
18. The process as claimed in claim 1 , wherein the solvent is an organic solvent having a boiling point of at most 82 degrees Centigrade, and selected from the group consisting of pentane, cyclopentane, hexane, cyclohexane, isomers and mixtures thereof.