Biodegradable starch-containing blend
View Patent ↗Disclosed is a composition comprising an aliphatic-aromatic copolyester consisting essentially of a dicarboxylic acid component that includes a terephthalic acid component and a linear aliphatic dicarboxylic acid component, a glycol component consisting essentially of a linear aliphatic glycol component and 0 to 4 mole percent based on 100 mole percent total glycol component of a dialkylene glycol component and at least one additional component; starch; water; and polyol plasticizer. Also described are shaped articles such as films which exhibit greater than expected tear strength and methods for preparing the films.
1. A composition comprising, based on the weight of the composition, 40 to 70 weight % of an aliphatic-aromatic copolyester, 20 to 50 weight % of starch, 5 to 10 weight % of polyol plasticizer, and 0 to 10 weight % of water wherein
the copolyester comprises a dicarboxylic acid component and a glycol component;
the dicarboxylic acid component comprises, based on 100 mole % total acid component, about 80 to 40 mole % of a first aromatic dicarboxylic acid consisting essentially of a terephthalic acid component, about 10 to 60 mole percent of a linear aliphatic dicarboxylic acid component; and 0 to 30 mole percent of an additional dicarboxylic acid component;
the additional dicarboxylic acid is selected from the group consisting of a second aromatic dicarboxylic acid, an alicyclic dicarboxylic acid, a branched dicarboxylic acid component, and combinations of two or more thereof;
the glycol component consists essentially of, based on 100 mole percent total glycol component, about 100 to 60 mole percent of a linear aliphatic glycol component, 0 to about 4 mole percent of a dialkylene glycol component; and 0 to 40 mole percent of an additional glycol;
the additional glycol component is selected from the group consisting of an alicyclic glycol component and a branched glycol component;
the additional dicarboxylic acid component, the additional glycol component, and the branched hydroxy-carboxylic acid component is at least 2 mole % of the copolyester; and
a film prepared from the composition has a tear strength measured in the machine direction at least 3 times greater than the tear strength measured in the machine direction of a film made from the copolyester.
2. The composition of claim 1 wherein the aliphatic glycol component is 1,3-propanediol or 1,4-butanediol.
3. The composition of claim 1 wherein the aliphatic dicarboxylic acid component is azelaic acid, sebacic acid, brassylic acid, azelaic acid alkyl ester, sebacic acid alkyl ester, brassylic acid alkyl ester, or combinations of two or more thereof.
4. The composition of claim 1 wherein the aliphatic glycol component is 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, or combinations of two or more thereof.
5. The composition of claim 4 wherein the dicarboxylic acid component consists essentially of, based on 100 mole % total acid component, about 80 to 40 mole % of the first aromatic dicarboxylic acid, about 10 to 60 mole percent of the aliphatic dicarboxylic acid component; and 2 to 30 mole percent the additional dicarboxylic acid component.
6. The composition of claim 5 wherein the additional dicarboxylic acid is a phthalic acid.
7. The composition of claim 6 wherein the aliphatic dicarboxylic acid component is sebacic acid.
8. The composition of claim 7 wherein the aliphatic glycol component comprises 1,3-propanediol.
9. The composition of claim 4 wherein the copolyester comprises copolymerized repeat units of a terephthalic acid or derivative, a sebacic acid or derivative, a phthalic acid derivative, and 1,3-propanediol.
10. The composition of claim 9 wherein the copolyester is semicrystalline.
11. The composition of claim 1 wherein the aliphatic glycol component is 1,3-propanediol.
12. The composition of claim 11 wherein the aliphatic dicarboxylic acid is sebacic acid or sebacic acid alkyl ester.
13. An article comprising a composition wherein the article is a film, a sheet, a fiber, a melt blown container, a molded part, or a foamed part; and the composition is as recited in claim 1 .
14. The article of claim 13 wherein the article is the film.
15. The shaped article of claim 14 wherein the tear strength of the film measured in the machine direction is at least 4 times greater than the tear strength measured in the machine direction of a film made from the copolyester.
16. The shaped article of claim 14 wherein the tear strength of the film measured in the machine direction is at least 9 times greater than the tear strength measured.