Polyethylene composition for large diameter pipe stability
Pipe articles and methods of forming the same are described herein. The methods generally include providing an ethylene based polymer; contacting the ethylene based polymer with a secondary stabilizer including a diphosphite to form a modified polyethylene; and forming the modified polyethylene into a pipe.
1. A method of forming pipe comprising:
providing an ethylene based polymer, wherein the ethylene based polymer is formed by a Ziegler-Natta catalyst formed by:
contacting an alkyl magnesium compound with an alcohol to form a magnesium dialkoxide compound;
contacting the magnesium dialkoxide compound with a plurality of first agents to form reaction product “A”;
contacting reaction product “A” with a second agent to form reaction product “B”, wherein the second agent comprises a transition metal and a halogen;
contacting reaction product “B” with a third agent to form reaction product “C”, wherein the third agent comprises a first metal halide and wherein the third agent is a stronger halogenating agent than the second agent;
contacting reaction product “C” with a fourth agent to form reaction product “D”, wherein the fourth agent comprises a second metal halide and wherein the fourth agent is a stronger halogenating agent than the third agent; and
contacting reaction product “D” with fifth agent to form a Ziegler-Natta catalyst component, wherein the fifth agent comprises an organoaluminum compound;
contacting the ethylene based polymer with a secondary stabilizer comprising a diphosphite to form a modified polyethylene; and
forming the modified polyethylene into a pipe.
2. The method of claim 1 , wherein the pipe comprises a diameter of at least 8 inches and an Oxidative Induction Time (OIT) of at least 30 minutes at 230° C.
3. The method of claim 1 further comprising contacting the ethylene based polymer with a primary stabilizer to form the modified polyethylene.
4. The method of claim 1 , wherein the pipe is a gas distribution pipe and the method further comprises flowing a gas through the gas distribution pipe.
5. The method of claim 4 , wherein the gas is selected from fuel gas and natural gas.
6. The method of claim 1 , wherein the ethylene based polymer exhibits a bimodal molecular weight distribution.
7. The method of claim 1 , wherein the ethylene based polymer is a homopolymer.
8. The method of claim 1 , wherein the ethylene based polymer is formed in a plurality of loop reactors in series.
9. The method of claim 1 , wherein the ethylene based polymer comprises high density polyethylene.
10. The method of claim 1 , wherein the secondary stabilizer is selected from trisarylphosphite, bis(2,4-di-tert-butylphenyl)pentaerythritol diphosphite, bis(phenyl)pentaerythritol diphosphite, bis(2,6-di-tert-butyl-4-methylphenyl)pentaerythritol diphosphite, bis(2,4-cumylphenyl)pentaerythritol diphosphite, 2,4,5-tri-t-butylphenyl 2-butyl-2-ethyl-1,3-propanediol phosphate and combinations thereof.
11. The method of claim 1 , wherein the secondary stabilizer is selected from the group consisting of unsubstituted bis(phenyl)pentaerythritol diphosphite, bis(2,4-cumylphenyl)pentaerythritol diphosphite, 2,4,5-tri-t-butylphenyl 2-butyl-2-ethyl-1,3-propanediol phosphate, and combinations thereof.
12. The method of claim 3 , wherein the primary stabilizer comprises a sterically hindered phenol.
13. The method of claim 3 , wherein the primary stabilizer is selected from thiobisphenol, alkylidene-bisphenol, alkylphenol, hydroxybenzyl compounds, acylaminophenols, hydroxyphenylpropionates, secondary aromatic amines and combinations thereof.
14. The method of claim 1 , wherein the ethylene based polymer is contacted with from about 500 ppm to about 5000 ppm of the secondary stabilizer.
15. The method of claim 3 , wherein the ethylene based polymer is contacted with from about 100 ppm to about 5000 ppm of the primary stabilizer.
16. The method of claim 3 , wherein the primary stabilizer and secondary stabilizer are blended with one another prior to contact with the ethylene based polymer.
17. A method of forming pipe comprising:
providing an ethylene based polymer, wherein the ethylene based polymer is formed by a Ziegler-Natta catalyst formed by:
contacting an alkyl magnesium compound with an alcohol to form a magnesium dialkoxide compound;
contacting the magnesium dialkoxide compound with a plurality of first agents to form reaction product “A”;
contacting reaction product “A” with a second agent to form reaction product “B”, wherein the second agent comprises a transition metal and a halogen;
contacting reaction product “B” with a third agent to form reaction product “C”, wherein the third agent comprises a first metal halide and wherein the third agent is a stronger halogenating agent than the second agent;
contacting reaction product “C” with a fourth agent to form reaction product “D”, wherein the fourth agent comprises a second metal halide and wherein the fourth agent is a stronger halogenating agent than the third agent; and
contacting reaction product “D” with fifth agent to form a Ziegler-Natta catalyst component, wherein the fifth agent comprises an organoaluminum compound;
contacting the ethylene based polymer with an anti-oxidant, a primary stabilizer and a secondary stabilizer to form modified polyethylene, wherein the secondary stabilizer is selected from the group consisting of unsubstituted bis(phenyl)pentaerythritol diphosphite, bis(2,4-cumylphenyl)pentaerythritol diphosphite, 2,4,5-tri-t-butylphenyl 2-butyl-2-ethyl-1,3-propanediol phosphate and combinations thereof; and
forming the modified polyethylene into a pipe, wherein the pipe comprises a diameter of at least 8 inches and an Oxidative Induction Time (OIT) of at least 30 minutes at 230° C.
18. The method of claim 17 , wherein the ethylene based polymer comprises at least a first ethylene based polymer and a second ethylene based polymer and the first ethylene based polymer is absent the secondary stabilizer.
19. The method of claim 3 , wherein the primary stabilizer is selected from alkylidene-bisphenol, alkylphenol, acylaminophenols, secondary aromatic amines and combinations thereof.
20. The method of claim 1 , wherein the ethylene based polymer exhibits a bimodal molecular weight distribution and comprises a high molecular weight fraction and a low molecular weight fraction, wherein the high molecular weight fraction exhibits a molecular weight of from 50,000 to 10,000,000, and wherein the low molecular weight fraction exhibits a molecular weight of from 500 to 50,0000.