Liquid crystal composition and liquid crystal display device
View Patent ↗The subject is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a negatively large dielectric anisotropy, a large specific resistance and a high stability to ultraviolet light or heat, or that is suitably balanced regarding at least two of the characteristics. The subject is to provide a AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The invention provides a liquid crystal composition that has negative dielectric anisotropy, including a specific four-ring compound having a high maximum temperature and a negatively large dielectric anisotropy as a first component, a two-ring compound having a small viscosity as a second component, and optionally including a specific compound having a negatively large dielectric anisotropy as a third component, a specific compound having small viscosity as a fourth component and a specific compound having a negatively large dielectric anisotropy as a fifth component. The invention provides also a liquid crystal display device containing this composition.
1. A liquid crystal composition that has negative dielectric anisotropy and comprises two components, wherein a first component is at least one compound selected from the group of compounds represented by formula (1), and a second component is at least one compound selected from the group of compounds represented by formula (2):
wherein R 1 , R 2 , R 3 and R 4 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring A and the ring B are each independently 1,4-cyclohexylene or 1,4-phenylene; one of the ring C and the ring D is 2,3-difluoro-1,4-phenylene and the other is 1,4-cyclohexylene or 1,4-phenylene; Z 1 and Z 3 are each independently a single bond, ethylene or difluoromethyleneoxy; and Z 2 is methyleneoxy, difluoromethyleneoxy or carbonyloxy.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1) to formula (1-6):
wherein R 1 and R 2 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
3. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1).
4. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-2).
5. The liquid crystal composition according to claim 1 , wherein the ratio of the first component is in the range of approximately 5% to approximately 40% by weight and the ratio of the second component is in the range of approximately 10% to approximately 95% by weight, based on the total weight of the liquid crystal composition.
6. The liquid crystal composition according to claim 1 , further comprising at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 5 and R 6 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring E is independently 1,4-cyclohexylene, 1,4-phenylene, tetrahydropyran-2,5-diyl, 2-fluoro-1,4-phenylene or 2,3-difluoro-1,4-phenylene; Z 4 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; X 1 and X 2 are each independently fluorine or chlorine; Y 1 is hydrogen or methyl; and p is 1 or 2, q is 0 or 1, and the sum of p and q is 2 or less.
7. The liquid crystal composition according to claim 6 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to formula (3-20):
wherein R 5 and R 6 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
8. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1).
9. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-2) and at least one compound selected from the group of compounds represented by formula (3-5).
10. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-14).
11. The liquid crystal composition according to claim 7 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-16) to formula (3-19).
12. The liquid crystal composition according to claim 6 , wherein the ratio of the third component is in the range of approximately 10% to approximately 70% by weight based on the total weight of the liquid crystal composition.
13. The liquid crystal composition according to claim 6 , further comprising at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 7 and R 8 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring F, the ring G and the ring I are each independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene or 3-fluoro-1,4-phenylene; Z 5 and Z 6 are each independently a single bond, ethylene, methyleneoxy or carbonyloxy; r is 0, 1 or 2; and wherein at least one of the ring G and the ring I is 1,4-phenylene when r is 0.
14. The liquid crystal composition according to claim 13 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-1) to formula (4-12):
wherein R 7 and R 8 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
15. The liquid crystal composition according to claim 14 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-4).
16. The liquid crystal composition according to claim 14 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-7).
17. The liquid crystal composition according to claim 13 , wherein the ratio of the fourth component is in the range of approximately 5% to approximately 40% by weight based on the total weight of the liquid crystal composition.
18. The liquid crystal composition according to claim 13 , further comprising at least one compound selected from the group of compounds represented by formula (5) as a fifth component:
wherein R 9 and R 10 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring J and the ring K are each independently 1,4-cyclohexylene, 1,4-phenylene, tetrahydropyran-2,5-diyl or 2,3-difluoro-1,4-phenylene; Z 7 and Z 8 are each independently a single bond, ethylene, methyleneoxy or carbonyloxy; and s and t are each independently 0, 1, 2 or 3, and the sum of s and t is 3 or less.
19. The liquid crystal composition according to claim 18 , wherein the fifth component is at least one compound selected from the group of compounds represented by formula (5-1) to formula (5-5):
wherein R 9 and R 10 are each independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
20. The liquid crystal composition according to claim 19 , wherein the fifth component is at least one compound selected from the group of compounds represented by formula (5-4).
21. The liquid crystal composition according to claim 18 , wherein the ratio of the fifth component is in the range of approximately 5% to approximately 30% by weight based on the total weight of the liquid crystal composition.
22. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is approximately 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nanometers is approximately 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is approximately −2 or less.
23. A liquid crystal display device containing the liquid crystal composition according to claim 1 .
24. The liquid crystal display device according to item 23, wherein an operating mode of the liquid crystal display device is a VA mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display device is an active matrix mode.