Epoxy silane oligomer and coating composition containing same
View Patent ↗A process for producing an epoxy silane oligomer including a reaction glycidoxy silane and/or cycloaliphatic epoxy silane having 2 or 3 alkoxy groups and, optionally, a copolymerizable silane other than glycidoxy and cycloaliphatic epoxy silane, with less than 1.5 equivalents of water in the presence of a catalyst, wherein said water is continuously fed during the reaction.
1. A process for producing a waterborne coating composition comprising an epoxysilane oligomer, a particulate metal, a surfactant and water, said method comprising: reacting glycidoxy silane having 2 alkoxy groups with water in the presence of a catalyst selected from the group consisting of an ion exchange resin, an alkylammonium salt, and a reaction product of a quaternary ammonium organofunctional silane and a ceramic, silica gel, precipitated silica, alumina or aluminosilicate support, wherein said water is continuously fed during the reaction and the molar ratio of water to silane monomer is from 0.1 to 1.5.
2. The process of claim 1 , wherein the molar ratio of water to silane monomer is from 0.4 to 1.0.
3. The process of claim 1 , wherein the molar ratio of water to silane monomer is from 0.1 to 0.5.
4. The process of claim 1 wherein the catalyst is at least one member selected from the group consisting of, hexadecyltrimethylammonium chloride, tetra-n-butylammonium chloride, benzyl trimethylammonium chloride, hexadecyltrimethylammonium bromide, tetra-n-butylammonium bromide, benzyl trimethylammonium bromide, hexadecyltrimethylammonium hydroxide, tetra-n-butylammonium hydroxide and benzyl trimethylammonium hydroxide.
5. The process of claim 1 wherein the glycidoxy silane is selected from the group consisting of gamma-glycidoxypropyl methyldimethoxysilane and gamma-glycidoxypropyl methyldiethoxysilane.
6. The process of claim 1 which further comprises continuously removing by-product alcohol produced during the reaction.
7. A waterborne coating composition, comprising:
a particulate metal;
a surfactant;
epoxy silane oligomer made by the process of reacting glycidoxy silane having 2 alkoxy group with water in the presence of a catalyst selected from the group consisting of an ion exchange resin, an alkylammonium salt, and a reaction product of a quaternary ammonium organofunctional silane and a ceramic, silica gel, precipitated silica, alumina or aluminosilicate support, wherein said water is continuously fed during the reaction and the molar ratio of water to silane monomer is from 0.1 to 1.5;
water; and,
one or more optional ingredients selected from the group consisting of pH adjusting agent, cosolvent, epoxy silane monomer, surfactant, binder, and pigment paste dispersion.
8. The waterborne coating composition of claim 7 wherein the particulate metal is present in an amount of from 0.1 to 80 weight percent, the surfactant is present in an amount of from 0.05 to 10 weight percent, the epoxy silane oligomer is present in an amount of from 0.1 to 30 weight percent, and water is present in an amount of from 5 to 99 weight percent.
9. The waterborne coating composition of claim 7 wherein the particulate metal is selected from the group consisting of finely divided aluminum, manganese, cadmium, nickel, stainless steel, tin, ferroalloys, magnesium and zinc.
10. The waterborne composition of claim 7 including a pH adjusting agent comprising at least one member selected from the group consisting of boric acid, orthophosphoric acid, acetic acid, and citric acid in an amount sufficient to provide a pH of from 4 to 6.
11. The waterborne composition of claim 7 including a co-solvent present in an amount of from 0.1 to about 60 weight percent based upon the total weight of the composition, wherein said co-solvent is at least one member of the group consisting of dipropylene glycol methyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monomethyl ether acetate, ethylene glycol monohexyl ether, ethylene glycol mono-2-ethylhexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, butyl carbitol, dipropylene glycol dimethyl ether, butyl glycol, butyldiglycol, ethylene glycol monobutyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, n-propyl acetate, n-butyl acetate, isobutyl acetate, methoxypropylacetate, butyl cellosolve actetate, butylcarbitol acetate, propylene glycol n-butyl ether acetate, t-butyl acetate, n-butanol, n-propanol, isopropanol and ethanol.
12. The waterborne composition of claim 7 including an epoxy silane monomer present in an amount of up to 10 weight percent based on the total weight of the composition, wherein said epoxy silane monomer is selected from the group consisting of gamma-glycidoxypropyl trimethoxy silane, gamma-glycidoxypropyl triethoxy silane, gamma-glycidoxypropyl methyldimethoxy silane and gamma-glycidoxypropyl methyldiethoxy silane.
13. An adhesive, sealant or coating composition which comprises the waterborne composition of claim 7 .