Composition and energy storage device
View Patent ↗In one embodiment, a cathode composition comprises a transition metal and/or a transition metal salt, wherein the transition metal is selected from the group consisting of nickel, iron, cobalt, chromium, manganese, molybdenum, zinc, and antimony, and a combination comprising at least one of the foregoing; an alkali metal halide; an electrolyte salt comprising an alkali metal halide and a metal halide; and a sulfide compound selected from the group consisting of gallium sulfide, antimony sulfide, and a combination comprising at least one of the foregoing. An energy storage device comprising the electrode composition is also provided.
1. A cathode composition comprising:
a transition metal and/or a transition metal salt, wherein the transition metal is selected from the group consisting of nickel, iron, cobalt, chromium, manganese, molybdenum, zinc, antimony, and a combination comprising at least one of the foregoing;
a first alkali metal halide;
an electrolyte salt comprising a second alkali metal halide different from the first alkali metal halide, and a metal halide, wherein the salt has a melting point of less than about 300° C.; and
a sulfide compound selected from the group consisting of gallium sulfide, antimony sulfide, and a combination comprising at least one of the foregoing.
2. The cathode composition according to claim 1 , wherein the transition metal comprises nickel.
3. The cathode composition according to claim 2 , wherein the transition metal further comprises iron.
4. The cathode composition according to claim 1 , wherein the alkali metal of the first alkali metal halide and the alkali metal of the second metal halide independently comprise sodium, potassium, lithium or a combination comprising at least one of the foregoing.
5. The cathode composition according to claim 1 , wherein the electrolyte salt comprises a halogen selected from the group consisting of chlorine, bromine, fluorine, and a combination comprising at least one of the foregoing.
6. The cathode composition according to claim 1 , wherein the electrolyte salt comprises an alkali metal halide and a metal halide, said electrolyte salt having a melting point of about 150° C. to about 300° C.
7. The cathode composition according to claim 6 , wherein the electrolyte salt comprises sodium chloride and aluminum chloride in a molar ratio of about 0.52:0.48 to about 0.45:0.55.
8. The cathode composition according to claim 1 , further comprising aluminum metal.
9. The cathode composition according to claim 1 , further comprising an additional sulfide compound having the formula MS n wherein M is a metal and n is equal or greater than 0.5.
10. The cathode composition according to claim 1 , wherein the sulfide compound is present in an amount of about 0.5 wt % to about 5.0 wt % based on the total weight of the cathode composition.
11. The cathode composition according to claim 1 , wherein the sulfide compound is gallium sulfide.
12. The cathode composition according to claim 1 , wherein the sulfide compound is antimony sulfide.
13. An article comprising:
a cathode; wherein the cathode comprises:
a transition metal and/or a transition metal salt, wherein the transition metal is selected from the group consisting of nickel, iron, cobalt, chromium, manganese, molybdenum, zinc, antimony, and a combination comprising at least one of the foregoing;
a first alkali metal halide;
an electrolyte salt comprising a second alkali metal halide different from the first alkali metal halide, and a metal halide, wherein the salt has a melting point of less than about 300° C.; and
a sulfide compound selected from the group consisting of gallium sulfide, antimony sulfide, and a combination comprising at least one of the foregoing.
14. The article according to claim 13 , wherein the article is part of an energy storage device.
15. The energy storage device of claim 14 , further comprising: a first compartment comprising a metallic alkali metal and a solid separator capable of transporting alkali metal ions between the cathode and the second compartments.
16. The energy storage device according to claim 15 , wherein said device is rechargeable over a plurality of cycles.
17. The energy storage device according to claim 15 , wherein the solid separator comprises a beta-alumina, a beta″-alumina, a gamma alumina, a micromolecular sieve, a silicon nitride, a silicophosphate, or nasicon.
18. The energy storage device according to claim 15 , wherein the solid separator comprises a shape which is flat, undulate, domed or dimpled, and/or comprises a shape with a cross-sectional profile that is an ellipse, triangle, cross, star, circle, cloverleaf, rectangular, square, or other multilobal configuration.
19. The energy storage device according to claim 15 , wherein the sulfide compound is gallium sulfide.
20. The energy storage device according to claim 15 , wherein the sulfide compound is antimony sulfide.