Lacquer composition and use thereof
View Patent ↗The present invention relates to a lacquer composition, particularly an adhesive and corrosion-protective lacquer for rare earth magnets, on the basis of an epoxy resin mixture, a setting accelerator, a silane-based epoxy functional adhesion promoter and a solvent or a solvent mixture, wherein the lacquer composition includes 5 to 20 wt. %, with respect to the amount of solid resin in the base of the epoxy resin mixture, of a highly viscous epoxy resin based on bisphenol-A with an elastomer content of more than 30 wt. %.
1. An adhesive and corrosion-protective lacquer composition for rare earth permanent magnets comprising a solid resin mixture, a setting accelerator, a silane-based epoxy functional adhesion promoter and a solvent or a solvent mixture, wherein the solid resin mixture includes, based upon the weight of the solid resin mixture:
a) 1 to 94 wt. % of at least one solid epoxy resin with an epoxide number of at most 2 Eq/kg,
b) 1 to 50 wt. % of at least one multifunctional solid epoxy resin with an epoxide number of >4 Eq/kg, and
c) 5 to 40 wt. % of a setting agent with a melting point >30° C., which is selected from a phenol novolac, a cresol novolac, or a combination thereof,
wherein the lacquer composition further comprises 5 to 20 wt. % with respect to the amount of solid resin in the solid resin mixture, of a highly viscous epoxy resin based on bisphenol-A having an elastomer content of >30 wt. % and wherein the viscosity of the highly viscous epoxy resin based on bisphenol-A is >50,000 mPas at 23° C.
2. An adhesive and corrosion-protective lacquer composition for rare earth permanent magnets comprising a solid resin mixture, a setting accelerator, a silane-based epoxy functional adhesion promoter and a solvent or a solvent mixture, wherein the solid resin mixture includes, based upon the weight of the solid resin mixture:
a) 1 to 94 wt. % of at least one solid epoxy resin with an epoxide number of at most 2 Eq/kg,
b) 1 to 50 wt. % of at least one multifunctional solid epoxy resin with an epoxide number of >4 Eq/kg, and
c) 5 to 40 wt. % of a setting agent with a melting point >30° C., which is selected from a phenol novolac, a cresol novolac, or a combination thereof,
wherein the lacquer composition further comprises 5 to 20 wt. % with respect to the amount of solid resin in the solid resin mixture, of a highly viscous epoxy resin based on bisphenol-A having an elastomer content of >30 wt. %, wherein the elastomer content of the highly viscous epoxy resin based on bisphenol-A comprises nitrile butadiene rubber; and wherein the viscosity of the highly viscous epoxy resin based on bisphenol-A is >5,000 mPas at 23° C.
3. An adhesive and corrosion-protective lacquer composition for rare earth permanent magnets comprising a solid resin mixture, a setting accelerator, a silane-based epoxy functional adhesion promoter and a solvent or a solvent mixture, wherein the solid resin mixture includes, based upon the weight of the solid resin mixture:
a) 1 to 94 wt. % of at least one solid epoxy resin with an epoxide number of at most 2 Eq/kg, comprising:
1 to 80 wt. % of a solid epoxy resin with an epoxide number <1 Eq/kg, and 1 to 80 wt. % of a solid epoxy resin having an epoxide number of 1 to 2 Eq/kg;
b) 1 to 50 wt. % of at least one multifunctional solid epoxy resin with an epoxide number of >4 Eq/kg, and
c) 5 to 40 wt. % of a setting agent with a melting point >30° C., which is selected from a phenol novolac, a cresol novolac, or a combination thereof,
wherein the lacquer composition further comprises 5 to 20 wt. % with respect to the amount of solid resin in the solid resin mixture, of a highly viscous epoxy resin based on bisphenol-A having an elastomer content of >30 wt. % and wherein the viscosity of the highly viscous epoxy resin based on bisphenol-A is >5,000 mPas at 23° C.
4. A lacquer composition as claimed in claim 3 , wherein in that the highly viscous epoxy resin based on bisphenol-A comprises a bisphenol-A diglycidyl ether.
5. The lacquer composition as claimed in claim 3 , wherein the at least one solid epoxy resin with an epoxide number of at most 2 Eq/kg is an epoxy resin based on bisphenol-A, bisphenol-F or a combination thereof.
6. The lacquer composition as claimed in claim 3 , wherein the multifunctional solid epoxy resin with an epoxide number >4 Eq/kg is selected from the group consisting of epoxy phenol novolacs, epoxy cresol novolacs, triglycidyl isocyanurate and mixtures thereof.
7. The lacquer composition as claimed in claim 3 , wherein the setting agent with a melting point >30° C. is present in an amount of 10 to 20 wt. %.
8. The lacquer composition as claimed in claim 3 , wherein the setting accelerator comprises tertiary amines, imidazole derivatives or a combination thereof.
9. The lacquer composition according to claim 8 , wherein the imidazole derivative is 2-ethyl-4-methylimidazole.
10. The lacquer composition as claimed in claim 3 , wherein the silane-based epoxy functional adhesion promoter is selected from the group consisting of γ-glycidyloxypropyltrimethoxysilane and β-(3,4-epoxycyclohexyl)-ethyltrimethoxysilane.
11. The lacquer composition as claimed claim 3 , wherein the silane-based epoxy functional adhesion promoter is present in the amount of 0.1 to 5 wt. %, with respect to the total amount of solid resin.
12. The lacquer composition according to claim 11 , wherein the silane-based epoxy functional adhesion promoter is present in an amount of 1-3 wt. % with respect to the total amount of solid resin.
13. The lacquer composition as claimed in claim 3 , wherein the solvent or solvent mixture comprises aliphatic and aromatic hydrocarbons, ethers, esters, glycol ethers, alcohols, ketones, or mixtures thereof.
14. The lacquer composition as claimed in claim 3 , wherein the lacquer composition has a solids content of 1 to 50 wt. %.
15. The lacquer composition according to claim 14 , wherein the solids content is 10 to 20 wt. %.
16. The lacquer composition as claimed in claim 3 , further comprising rust-protective pigments, or at least one salt-like compound selected from the group consisting of vanadates, tungstenates, niobates, molybdates and mixtures thereof.
17. The lacquer composition as claimed in claim 16 , wherein the at least one salt-like compound comprises zinc molybdate.
18. The lacquer composition according to claim 16 , wherein the rust-protective pigments comprise zinc phosphate, zinc chromate, or zinc hydroxyphosphite.
19. The lacquer composition as claimed in claim 3 , further comprising one or more additional additives, selected from one or more soluble colorants, flowing agents and defoamers, non-metallic fillers, dispersible colouring pigments, dispersing adjuvants, rheological additives, or an anti-deposition adjuvants.
20. The lacquer composition according to claim 19 , wherein the non-metallic fillers comprise quartz flour, mica, or talcum.
21. The lacquer composition according to claim 19 , wherein the dispersible colouring pigment comprise carbon black or rutile.
22. The lacquer composition according to claim 19 , wherein the anti-deposition adjuvant comprise bentonites or fumed silicas.
23. The lacquer composition according to claim 3 , wherein the setting agent has a melting point >100° C.
24. A magnet system obtained by: forming a layer of the lacquer composition as claimed in claim 3 with a thickness of between 10 and 50 μm between two magnets or between a magnet and another workpiece; and curing the layer of lacquer composition, wherein the magnet system has a minimum compression strength of 10 N/mm 2 , a long-term temperature resistance of 150° C., a resistance to cooling lubricants of >1000 hours, a corrosion strength of >1000 hours at 85° C. and 85% air humidity and a resistance in a salt spray test of >250 hours.
25. A method of manufacturing magnet systems using the lacquer composition as claimed in claim 3 , comprising:
coating a first magnet with the lacquer composition to form a first coated magnet;
initially drying the lacquer layer;
joining together the first coated magnet with another coated magnet or another workpiece at a pressure of 0.1 to 3 N/mm 2 at a temperature of between 20 and 30° C. for a period of time of 3 to 30 seconds to form a magnet system with a shear strength of >0.25 N/mm 2 ; and
fixing the magnet system in position in an oven.
26. The method according to claim 25 , wherein the joining together of the first coated magnet with another coated magnet or another workpiece is effected with the aid of a robot arm.
27. The method according to claim 25 , further comprising curing the lacquer composition in the oven.
28. The method according to claim 27 , wherein said curing results from heating the magnet system in said oven at a temperature between 150 and 250° C.