Sunscreen compositions comprising an ultraviolet radiation-absorbing polymer
View Patent ↗Aqueous compositions including a discontinuous oil phase containing an ultraviolet radiation-absorbing polymer stabilized in a continuous aqueous phase, an oil-gelling polymer, and which are substantially free of non-polymeric ultraviolet radiation-absorbers.
1. A composition comprising: a continuous water phase; a discontinuous oil phase comprising a UV-absorbing polyester that is formed by a polycondensation reaction of dimerdiol (monomer 1), di-trimethylolpropane (monomer 2), dimethyladipate (monomer 3) and benzenepropanoic acid (monomer 4), in an amount effective to provide said composition with an SPF of about 2 or more in the absence of a UV-screening compound, wherein the mole ratio of the four monomers (monomer 1: monomer 2: monomer 3: monomer 4) is selected from the group consisting of 2.4:3.1:4.0:8.0 and 3.4:2.1:4.0:6.0; wherein said discontinuous oil phase is stable in said continuous water phase; and an oil gelling polymer, wherein said composition is substantially free of a non-polymeric UV-absorber.
2. The composition of claim 1 , wherein said composition further comprises a fatty alcohol.
3. The composition of claim 1 , wherein said composition further comprises a fatty acid ester selected from the group consisting of a fatty acid ester of butylene and a fatty acid ester of propylene glycol.
4. The composition of claim 3 wherein said oil gelling polymer comprises a C 2 -C 4 alkylcellulose.
5. The composition of claim 1 , wherein said UV-absorbing polyester comprises at least one UV-absorbing moiety selected from the group consisting of a UV-A absorbing moiety and a UV-B absorbing moiety.
6. The composition of claim 5 , wherein said UV-A absorbing moiety selected from the group consisting of a tertrahydroxybenzophenones, dicarboxydihydroxybenzophenones and alkane ester or acid halide derivatives thereof, dihydroxy-, dicarboxy-, and hydroxycarboxydibenzoylmethanes and alkane ester or acid halide derivatives thereof, dihydroxy-, dicarboxy-, and hydroxycarboxystilbenes and alkane ester or acid halide derivatives thereof, bis(hydroxystyrenyl) benzenes, bis(carboxystyrenyl)benzenes and alkane ester or acid halide derivatives thereof, dihydroxy-, dicarboxy, and hydroxycarboxycarotenes and alkane ester or acid halide derivatives thereof, and 2cyano-3,3-diphenyl acrylic acid, 2-ethyl hexyl ester.
7. The composition of claim 5 , wherein said UV-A absorbing moiety is selected from the group consisting of a UV-absorbing triazole and a UV-absorbing dibenzoylmethane.
8. The composition of claim 5 , wherein said UV-B absorbing moiety selected from the group consisting of a 4-aminobenzoic acid and alkane esters thereof, anthranilic acid and alkane esters thereof, salicylic acid and alkane esters thereof, hydroxycinnamic acid and alkane esters thereof, dihydroxy-, dicarboxy-, and hydroxycarboxybenzophenones and alkane ester or acid halide derivatives thereof, dihydroxy-, dicarboxy-, and hydroxycarboxychalcones and alkane ester or acid halide derivatives thereof, and dihydroxy-, dicarboxy-, and hydroxycarboxycoumarins and alkane ester or acid halide derivatives thereof.
9. The composition of claim 1 , wherein said oil gelling polymer is selected from the group consisting of a C 2 -C 4 alkylcellulose, dibutyl ethylheaxanoyl glutamide and dibutyl lauroyl glutamide.
10. The composition of claim 1 , wherein said composition is substantially free of emulsifiers having a molecular weight of about 2000 daltons or less.
11. The composition of claim 10 comprising about 1 percent or less of said non-polymeric UV-absorbers and about 1 percent or less of said emulsifiers having a molecular weight of about 2000 daltons or less.
12. The composition of claim 10 comprising about 0.5 percent or less of said non-polymeric UV-absorbers and about 0.5 percent or less of said emulsifiers having a molecular weight of about 2000 daltons or less.
13. The composition of claim 1 comprising from about 0.5 percent to about 40 percent of said UV-absorbing polyester.
14. The composition of claim 1 wherein said discontinuous oil phase is stable from phase separation from said continuous water phase for about one month or more when maintained at about 20° C. to about 25° C.
15. The composition of claim 1 wherein the molecular weight of said UV-absorbing polyester is about 2000 or more.
16. The composition of claim 1 , wherein the composition is prepared by a method comprising:
mixing at least said UV-absorbing polyester with said oil-gelling polymer to form a continuous oil phase;
mixing at least water and a water-gelling polymer to form said continuous water phase; and
mixing said continuous oil phase and said continuous water phase under conditions effective to form said composition comprising said discontinuous oil phase stabilized in said continuous water phase.
17. The composition of claim 1 , wherein said composition is substantially free of a UV-screening particle.