IP Library Granted Patent US 8,045,245
Granted Patent B2
US 8,045,245 · App. 13/021,885 · Granted Oct 25, 2011

Multicolor holgraphic replication by masking

Assignee: E. I. du Pont de Nemours and Company
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Quick Facts
Patent No.
US 8,045,245
App. No.
13/021,885
Granted
Oct 25, 2011
Kind
B2
Abstract

A multicolor hologram (e.g., a two-color hologram) is replicated (copied) into a photosensitive layer by masking to produce a copy (replicate) of the hologram in a manner such that the copy is an accurate and true replication of the hologram (e.g., master hologram) and the copy is characterized to possess a high brightness level and color fidelity comparable to that of the multicolor hologram that was replicated. Both flood and scan modes can be employed in the replication.

Claims (38)

1. A method for replicating a volume reflection master hologram comprising, in sequence as listed below:

a) providing a photosensitive layer having a side and an opposing side,

b) placing the side of the photosensitive layer in contact with or proximate to the master hologram;

c) placing a first mask in contact with or proximate to the opposing side of the photosensitive layer masking at least one area of the photosensitive layer;

d) exposing the photosensitive layer through the first mask with coherent actinic radiation of a first wavelength λ 1 resulting in a first wavelength exposed layer;

e) removing the first mask;

f) placing a second mask in contact with or proximate to the opposing side of the photosensitive layer that is now the first wavelength exposed layer masking at least one area of the first wavelength exposed layer;

g) exposing the first wavelength exposed layer with coherent actinic radiation of a second wavelength λ 2 resulting in a first and second wavelength exposed layer;

h) removing the second mask; and

i) exposing the first and second wavelength exposed layer with coherent actinic radiation of a third wavelength λ 3 resulting in a first, second and third wavelength exposed layer, wherein the first, second and third wavelength exposed layer is a replicate of the volume reflection master hologram.

2. The method of claim 1 wherein, after exposing the second mask to the coherent actinic radiation, the second mask is replaced with a third mask prior to i) being executed.

3. The method of claim 2 wherein the second mask is chosen such that it will effectively block actinic radiation during the second exposure from reaching areas of the first wavelength exposed layer that were previously exposed during the first exposure.

4. The method of claim 1 wherein coherent actinic radiation of the first wavelength λ 1 , coherent actinic radiation of the second wavelength λ 2 , and coherent actinic radiation of the third wavelength λ 3 are within a visible region of the electromagnetic spectrum.

5. The method of claim 1 wherein coherent actinic radiation of the first wavelength λ 1 , coherent actinic radiation of the second wavelength λ 2 , or coherent actinic radiation of the third wavelength λ 3 corresponds to blue light and wherein at least one of the first wavelength exposed layer, the first and second wavelength exposed layer, and the first, second and third wavelength exposed layer is color-tuned such that the replicate of the volume reflection master hologram plays back in a green region of visible light.

6. The method of claim 1 wherein coherent actinic radiation of the first wavelength λ 1 , coherent actinic radiation of the second wavelength λ 2 , or coherent actinic radiation of the third wavelength λ 3 corresponds to green light and wherein at least one of the first wavelength exposed layer, the first and second wavelength exposed layer or the first, second, and third exposed layer is color-tuned such that the replicate of the two-color master hologram plays back in a red region of visible light.

7. The method of claim 1 wherein the photosensitive layer is a photopolymer.

8. The method of claim 7 wherein the photopolymer is a holographic recording film.

9. The method of claim 1 wherein the exposing steps d) and g) and i) are done in a flood exposure mode.

10. The method of claim 1 wherein the exposing steps d) and g) and i) are done in a scan exposure mode with a moving beam of coherent actinic radiation.

11. The method of claim 1 wherein the absolute values of λ 1 -λ 2 , λ 1 -λ 3 , and λ 2 -λ 3 are each at least 7 nm.

12. The method of claim 1 wherein the at least one area masked in step c) is also masked in step f).

13. The method of claim 1 wherein the placing of the side of the photosensitive layer is such that the side of the photosensitive layer is in contact with the master hologram.

14. The method of claim 1 wherein the placing of the first mask in c) is such that the first mask is in contact with the opposing side of the photosensitive layer.

15. A method for replicating a volume reflection master hologram comprising:

a) providing a photosensitive layer having a side and an opposing side;

b) placing the side of the photosensitive layer in contact with or proximate to the master hologram;

c) placing a first mask in contact with or proximate to the opposing side of the photosensitive layer masking at least one area of the photosensitive layer;

d) exposing the photosensitive layer through the first mask with coherent actinic radiation of a first wavelength λ 1 resulting in a first wavelength exposed layer;

e) removing the first mask;

f) placing a second mask in contact with or proximate to the opposing side of the photosensitive layer that is now the first wavelength exposed layer masking at least one area of the first wavelength exposed layer;

g) exposing the first wavelength exposed layer with coherent actinic radiation of a second wavelength λ 2 resulting in a first and second wavelength exposed layer;

h) removing the second mask;

i) placing a third mask in contact with or proximate to the opposing side of the photosensitive layer that is now the first and second wavelength exposed layer masking at least one area of the photosensitive layer;

j) exposing the first and second wavelength exposed layer with coherent actinic radiation of a third wavelength λ 3 resulting in a first, second and third wavelength exposed layer; and

k) removing the third mask;

wherein the first, second, and third wavelength exposed layer is a replicate of the volume reflection master hologram.

16. The method of claim 15 wherein absolute values of λ 1 -λ 2 , λ 1 -λ 3 , and λ 2 -λ 3 are each at least 7 nm.

17. The method of claim 15 wherein the at least one area masked in step c) is also masked in steps f) and i).

Assignments (4)
RELEASE OF SECURITY INTEREST Recorded May 1, 2025
From: GLAS TRUST CORPORATION LIMITED, LLC
To: DE LA RUE AUTHENTICATION SOLUTIONS INC.
Reel/Frame 070993/0794 →
IP SECURITY AGREEMENT SUPPLEMENT Recorded Aug 14, 2023
From: DE LA RUE AUTHENTICATION SOLUTIONS INC.
To: GLAS TRUST CORPORATION LIMITED, AS SECURITY AGENT
Reel/Frame 064584/0686 →
CHANGE OF NAME Recorded Jan 12, 2018
From: DUPONT AUTHENTICATION, INC.
To: DE LA RUE AUTHENTICATION SOLUTIONS INC.
Reel/Frame 045066/0192 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2016
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT AUTHENTICATION, INC
Reel/Frame 040742/0004 →
Continuity (3)
Continuation 12080620 · Apr 4, 2008
Provisional Application 60910272 · Apr 5, 2007
Related Publication 20110122375A1 · May 26, 2011