Industrial polyolefin piping system
View Patent ↗Industrial polyolefin piping system with improved stiffness, impact strength for use at high service temperature, comprising single or multilayer pipes, fitting, chambers, valves and vessels, consisting of β-nucleated propylene homopolymers with an IRτ≧0.98 having a tensile modulus ≧1500 MPa, a Charpy impact strength, notched, at +23° C.≧30 kJ/m 2 and a Vicat B temperature >90° C. and a Heat Distortion Temperature >100° C. The industrial polyolefin piping system is suitable for chemical plant constructions comprising single or multilayer pipes, fittings, chambers, valves and vessels with improved stiffness, impact strength and high service temperature, preferred for conveyance of natural gas, dangerous liquids and/or toxic liquids.
1. Industrial piping system comprised of propylene polymer and comprising single- or multi-layer pipes, fittings, valves, chambers and vessels, the propylene polymer comprising a propylene homopolymer having a melt index of 0.05 to 40 g/10 min at 230° C./2.16 kg, wherein the propylene homopolymer is β-nucleated and has an IRτ≧0.98, a tensile modulus ≧1500 MPa, a Charpy impact strength, using notched test specimens, at +23° C.≧30 kJ/m 2 , a Vicat B temperature >90° C., and a heat distortion temperature >100° C.
2. Industrial piping system according to claim 1 , wherein the propylene homopolymer has a melt index of 0.05 to 15 g/10 min at 230° C./2.16 kg.
3. Industrial piping system according to claim 1 , wherein the propylene polymer is obtained by polymerization with a Ziegler-Natta catalyst system comprising titanium-containing solid components, an organoaluminum, magnesium or titanium compound as cocatalyst and an external donor according to the formula
R x R′ y Si(MeO) 4−x−y ,
wherein R and R′ are identical or different and are branched or cyclic aliphatic or aromatic hydrocarbon residues, and y and x independently from each other are 0 or 1, provided that x+y is 1 or 2.
4. Industrial piping system according to claim 3 , wherein the external donor is dicyclopentyldimethoxysilane.
5. Industrial piping system according to claim 1 , wherein the β-nucleated propylene polymer contains 0.0001 to 2.0 wt %, based on the polypropylene:
dicarboxylic acid derivative diamide compounds from C 5 -C 8 -cycloalkyl monoamines or C 6 -C 12 -aromatic monoamines and C 5 -C 8 -aliphatic, C 5 -C 8 -cycloaliphatic or C 6 -C 12 -aromatic dicarboxylic acids, and/or
diamine derivative diamide compounds from C 5 -C 8 -cycloalkyl monocarboxylic acids or C 6 -C 12 -aromatic monocarboxylic acids and C 5 -C 8 -cycloaliphatic or C 6 -C 12 -aromatic diamines, and/or
-amino acid derivative diamide compounds from amidation reaction of C 5 -C 8 -alkyl-, C 5 -C 8 -cycloalkyl- or C 6 -C 12 -arylamino acids, C 5 -C 8 -alkyl-, C 5 -C 8 -cycloalkyl- or C 6 -C 12 -aromatic monocarboxylic acid chlorides and C 5 -C 8 -alkyl-, C 5 -C 8 -cycloalkyl- or C 6 -C 12 -aromatic monoamines, as β-nucleating agent.
6. Industrial piping system according to claim 1 , wherein the β-nucleated propylene polymer contains 0.0001 to 2.0 wt %, based on the polypropylene, quinacridone compounds; quinacridonequinone compounds; and/or dihydroquinacridone compounds, as β-nucleating agent.
7. Industrial piping system according to claim 1 , wherein the β-nucleated propylene polymer contains 0.01 to 2.0 wt %, based on the polypropylene, dicarboxylic acid salts of metals from group IIa of the periodic system and/or mixtures of dicarboxylic acids and salts of metals from group IIa of the periodic system, as β-nucleating agent.
8. Industrial piping system according to claim 1 , wherein the β-nucleated propylene polymer contains 0.01 to 2.0 wt %, based on the polypropylene, of imido acid salts of metals from group IIa of the periodic system, the imido acids having the formula
wherein x=1 to 4; R=H, —COOH, C 1 -C 12 -alkyl, C 5 -C 8 -cycloalkyl or C 6 -C 12 -aryl, and Y=C 1 -C 12 -alkyl, C 5 -C 8 -cycloalkyl or C 6 -C 12 -aryl- substituted bivalent C 6 -C 12 -aromatic residues, as β-nucleating agent.
9. Industrial piping system according to claim 6 , wherein the quinacridone compounds are quinacridone, dimethylquinacridone and/or dimethoxyquinacridone, the quinacridonequinone compounds are quinacridonequinone, a mixed crystal of 5,12-dihydro(2,3b)acridine-7, 14-dione with quino(2,3b)acridine-6, 7, 13, 14-(5H, 12H)-tetrone and/or dimethoxyquinacridonequinone and the dihydroquinacridone compounds are dihydroquinacridone, dimethoxydihydroquinacridone and/or dibenzodihydroquinacridone.
10. Industrial piping system according to claim 7 , wherein the dicarboxylic acid salts from group IIa of the periodic system are pimelic acid calcium salt and/or suberic acid calcium salt.
11. Industrial piping system according to claim 8 , wherein the imido acid salts of metals from group IIa of the periodic system are calcium salts of phthaloylglycine, hexahydrophthaloylglycine, N-phthaloylalanine and/or N-4-methylphthaloylglycine.
12. Industrial piping system according to claim 7 , wherein the dicarboxylic acid salts from group IIa of the periodic system comprise pimelic acid calcium salt.
13. Industrial piping system according to claim 7 , wherein the dicarboxylic acid salts from group IIa of the periodic system comprise suberic acid calcium salt.
14. Process for producing an industrial piping system comprised of propylene polymer and comprising single- or multi-layer pipes, fittings, valves, chambers and vessels, comprising producing industrial single- or multi-layer pipes comprised of propylene polymer for use at high service temperature, comprising extruding a melt, the melt being at a temperature of 195 to 250° C. and being comprised of a propylene homopolymer having a melt index of 0.05 to 40 g/10 min at 230° C./2.16 kg, the propylene homopolymer being β-nucleated and having an IRτ≧0.98, a tensile modulus ≧1500 MPa, a Charpy impact strength, using notched test specimens, at 23° C.≧30 kJ/m 2 , a Vicat B temperature >90° C. and a heat distortion temperature >100° C.
15. Process for producing an industrial piping system comprised of propylene polymer and comprising single- or multi-layer pipes, fittings, valves, chambers and vessels, comprising injection molding a melt, the melt being at a temperature of 195 to 250° C. and being comprised of a propylene homopolymer having a melt index of 2 to 40 g/10 min at 230° C./2.16 kg, the propylene homopolymer being β-nucleated and having an IRτ≧0.98, a tensile modulus ≧1500 MPa, a Charpy impact strength, using notched test specimens, at 23° C.≧30 kJ/m 2 , a Vicat B temperature >90° C. and a heat distortion temperature >100° C.
16. Process for producing an industrial piping system comprised of propylene polymer and comprising single- or multi-layer pipes, fittings, valves, chambers and vessels, comprising producing an industrial vessel comprised of propylene polymer, comprising blow molding a melt, the melt being at a temperature of 185 to 230° C. and being comprised of a propylene homopolymer having a melt index of 1 to 20 g/10 min at 230° C./2.16 kg, the propylene homopolymer being β-nucleated and having an IRτ≧0.98, a tensile modulus ≧1500 MPa, a Charpy impact strength, using notched test specimens, at 23° C.≧30 kJ/m 2 , a Vicat B temperature >90° C. and a heat distortion temperature >100° C.