Process for producing hemicellulose sugars and energy from biomass
View Patent ↗A method for the production of alcohol and other bioproducts hemicelluloses extracted from biomass prior to thermal conversion of the biomass to energy. The process can be integrated with the host plant process to minimize the energy loss from extracting hemicelluloses. Also disclosed is a Stepwise enzymatic break down of cellulose fibers from a pulping operation which is performed with the redeployment of equipment and vessels contained within typical existing pulp and paper manufacturing mills. The preferred feedstock is highly delignified pulp from acid or alkaline pulping process or from bleaching stage.
1. A process for producing hemicellulose sugars and energy from cellulosic biomass, said process comprising:
(a) extracting hemicelluloses from cellulosic biomass by a batch or continuous extraction reactor in the presence of steam, to produce a cellulose-rich solids stream and a liquid extract comprising water, wherein hemicelluloses and acetyl groups are released from the cellulosic biomass;
(b) concentrating said liquid extract in a first evaporation stage that removes a majority of said water from said liquid extract, to produce a low-solids extract, wherein said first evaporation stage is operated at a pH of 4.8 or less, wherein a first amount of acetic acid, is obtained from acetyl groups released from the cellulosic biomass, and wherein the first amount of acetic acid is evaporated from said first evaporation stage;
(c) hydrolyzing said low-solids extract from step (b) in the presence of sulfuric acid, heat, or hemicellulase enzymes, to produce a hydrolyzate comprising hemicellulose sugars and additional acetyl groups released during said hydrolyzing said low-solids extract;
(d) introducing said hydrolyzate to a second evaporation stage, to produce a concentrated extract, wherein said second evaporation stage is operated at a pH of 4.8 or less, wherein a second amount of acetic acid, derived from said acetyl groups released during said hydrolyzing said low-solids extract, is evaporated from said second evaporation stage, and wherein said concentrated extract comprises said hemicellulose sugars;
(e) recovering or further processing said hemicellulose sugars;
(f) dewatering said cellulose-rich solids stream from step (a), to produce dewatered solids;
and
(g) combusting said dewatered solids, to produce energy.
2. The process of claim 1 , wherein the steam has a pressure selected from 5 to 30 atmospheres.
3. The process of claim 1 , wherein said extracting in step (a) utilizes a mineral acid.
4. The process of claim 1 , wherein said extracting in step (a) utilizes acetic acid.
5. The process of claim 1 , wherein said extracting in step (a) utilizes sulfur dioxide.
6. The process of claim 1 , wherein extraction time is selected from 2 minutes to 1 hour.
7. The process of claim 1 , comprising a step of washing said cellulose-rich solids stream to produce said liquid extract.
8. The process of claim 1 , wherein said first evaporation stage is operated to produce a low-solids extract with a solids concentration up to about 25 wt %.
9. The process of claim 1 , wherein said second evaporation stage is operated to produce a concentrated extract with a solids concentration up to about 50 wt %.
10. The process of claim 1 , wherein mechanical-vapor recompression is employed for said first evaporation stage, said second evaporation stage, or both of these evaporation stages.
11. The process of claim 1 , wherein said second evaporation stage is controlled at a pH selected from 3 to 4.8.
12. The process of claim 1 , wherein said dewatered solids contain from 40 wt % to 60 wt % solids.
13. The process of claim 1 , wherein said dewatered solids contain about the same moisture content as contained in said cellulosic biomass.
14. The process of claim 1 , said process further comprising fermenting said hemicellulose sugars to an alcohol, and then distilling and drying said alcohol to produce a purified alcohol and a distillation bottoms stream.
15. The process of claim 14 , said process further comprising introducing said distillation bottoms stream to a third evaporation stage, to produce residual solids, and then combusting said residual solids.
16. The process of claim 15 , wherein at least a portion of said residual solids is combined with said dewatered solids prior to combustion.
17. The process of claim 1 , wherein said process is a zero-liquid-discharge process.
18. A process for producing hemicellulose sugars and energy from cellulosic biomass, said process comprising:
(a) extracting hemicelluloses from cellulosic biomass by charging said cellulosic biomass into a batch or continuous extraction reactor in the presence of steam, to produce a cellulose-rich solids stream and a liquid extract comprising water wherein hemicelluloses and acetyl groups are released from said cellulosic biomass, and wherein said liquid extract contains at least 5 wt % solids;
(b) hydrolyzing said liquid extract in the presence of sulfuric acid, heat, or enzymes, to produce a hydrolyzate comprising hemicellulose sugars and additional acetyl groups released during said hydrolyzing said liquid extract;
(c) introducing said hydrolyzate to an evaporation stage, to produce a concentrated extract, wherein said evaporation stage is operated at a pH of 4.8 or less, wherein acetic acid obtained from said acetyl groups released from said cellulosic biomass and said additional acetyl groups released during said hydrolyzing said liquid extract, are evaporated from said evaporation stage, and wherein said concentrated extract comprises said hemicellulose sugars;
(d) recovering or further processing said hemicellulose sugars;
(e) dewatering said cellulose-rich solids stream from step (a), to produce dewatered solids;
and
(f) combusting said dewatered solids, to produce energy.
19. A process for producing hemicellulose sugars from cellulosic biomass, said process comprising:
(a) extracting hemicelluloses from cellulosic biomass by a batch or continuous extraction reactor in the presence of steam, to produce a cellulose-rich solids stream and a liquid extract comprising water, wherein said hemicelluloses and acetyl groups are released from said cellulosic biomass;
(b) concentrating said liquid extract in a first evaporation stage that removes a majority of said water from said liquid extract, to produce a low-solids extract, wherein said first evaporation stage is operated at a pH of 4.8 or less, and wherein a first amount of acetic acid, is obtained from said acetyl groups released from said cellulosic biomass, is evaporated from said first evaporation stage;
(c) hydrolyzing said low-solids extract from step (b) in the presence of sulfuric acid, heat, or hemicellulase enzymes, to produce a hydrolyzate comprising hemicellulose sugars and additional acetyl groups released during said hydrolyzing said low-solids extract;
(d) introducing said hydrolyzate to a second evaporation stage, to produce a concentrated extract, wherein said second evaporation stage is operated at a pH of 4.8 or less, wherein a second amount of acetic acid is obtained from said acetyl groups released during said hydrolyzing said low-solids extract, is evaporated from said second evaporation stage, and wherein said concentrated extract comprises said hemicellulose sugars; and
(e) recovering or further processing said hemicellulose sugars.