Polycrystalline compacts including metallic alloy compositions in interstitial spaces between grains of hard material, cutting elements and earth-boring tools including such polycrystalline compacts, and related methods
View Patent ↗Polycrystalline compacts include a polycrystalline material comprising a plurality of inter-bonded grains of hard material, and a metallic material disposed in interstitial spaces between the inter-bonded grains of hard material. At least a portion of the metallic material comprises a metal alloy that includes two or more elements. A first element of the two or more elements comprises at least one of cobalt, iron, and nickel. A second element of the two or more elements comprises at least one of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium. The metal alloys may comprise eutectic or near-eutectic compositions, and may have relatively low melting points. Cutting elements and earth-boring tools include such polycrystalline compacts. Methods include the formation of such polycrystalline compacts, cutting elements, and earth-boring tools.
1. A polycrystalline compact, comprising:
a polycrystalline material comprising a plurality of inter-bonded grains of hard material; and
a metallic material disposed in interstitial spaces between the inter-bonded grains of hard material, at least a portion of the metallic material comprising a metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less, the metal alloy comprising two or more elements, a first element of the two or more elements selected from the group consisting of cobalt, iron, and nickel, a second element of the two or more elements selected from the group consisting of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium.
2. The polycrystalline compact of claim 1 , wherein the second element comprises at least about five weight percent (5 wt %) or more of the metal alloy.
3. The polycrystalline compact of claim 1 , wherein the metal alloy comprises a near-eutectic composition.
4. The polycrystalline compact of claim 3 , wherein the metal alloy is a eutectic composition.
5. The polycrystalline compact of claim 4 , wherein the metal alloy is selected from the group consisting of a binary eutectic composition, a ternary eutectic composition, and a quaternary eutectic composition.
6. The polycrystalline compact of claim 3 , wherein the near-eutectic composition is selected from the group consisting of a near-eutectic composition of cobalt and dysprosium, a near-eutectic composition of cobalt and yttrium, a near-eutectic composition of cobalt and terbium, a near-eutectic composition of cobalt and gadolinium, a near-eutectic composition of cobalt and germanium, a near-eutectic composition of cobalt and samarium, a near-eutectic composition of cobalt and neodymium, and a near-eutectic composition of cobalt and praseodymium.
7. The polycrystalline compact of claim 3 , wherein the near-eutectic composition is selected from the group consisting of a near-eutectic composition of iron and dysprosium, a near-eutectic composition of iron and yttrium, a near-eutectic composition of iron and terbium, a near-eutectic composition of iron and gadolinium, a near-eutectic composition of iron and germanium, a near-eutectic composition of iron and samarium, a near-eutectic composition of iron and neodymium, and a near-eutectic composition of iron and praseodymium.
8. The polycrystalline compact of claim 3 , wherein the near-eutectic composition is selected from the group consisting of a near-eutectic composition of nickel and dysprosium, a near-eutectic composition of nickel and yttrium, a near-eutectic composition of nickel and terbium, a near-eutectic composition of nickel and gadolinium, a near-eutectic composition of nickel and germanium, a near-eutectic composition of nickel and samarium, a near-eutectic composition of nickel and neodymium, and a near-eutectic composition of nickel and praseodymium.
9. The polycrystalline compact of claim 1 , wherein the metal alloy has a melting temperature of about three hundred degrees Celsius (300° C.) or more.
10. The polycrystalline compact of claim 9 , wherein the metal alloy has a melting temperature of about six hundred fifty degrees Celsius (650° C.) or less.
11. The polycrystalline compact of claim 10 , wherein the metal alloy has a melting temperature of between about five hundred fifty degrees Celsius (550° C.) and about six hundred fifty degrees Celsius (650° C.).
12. The polycrystalline compact of claim 1 , wherein the polycrystalline material comprises between about eighty percent by volume (80 vol %) and about ninety-nine percent by volume (99 vol %) of the polycrystalline compact.
13. The polycrystalline compact of claim 10 , wherein the metallic material comprises between about one percent by volume (1 vol %) and about twenty percent by volume (20 vol %) of the polycrystalline compact.
14. The polycrystalline compact of claim 1 , wherein the polycrystalline material comprises:
a first region, the metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less disposed in the first region of the polycrystalline material; and
a second region, the metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less not disposed in the second region of the polycrystalline material.
15. The polycrystalline compact of claim 1 , wherein the metallic material is not disposed in a portion of the interstitial spaces between the inter-bonded grains of hard material, the portion of the interstitial spaces between the inter-bonded grains of hard material comprising voids between the inter-bonded grains of hard material.
16. The polycrystalline compact of claim 1 , wherein the hard material comprises diamond.
17. A polycrystalline compact, comprising:
a polycrystalline material comprising a plurality of inter-bonded grains of hard material; and
a metallic material disposed in interstitial spaces between the inter-bonded grains of hard material, at least a portion of the metallic material comprising a metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less, the metal alloy comprising a near-eutectic composition of at least two elements, a first element of the at least two elements selected from the group consisting of cobalt, iron, and nickel, a second element of the at least two elements selected from the group consisting of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium.
18. The polycrystalline compact of claim 17 , wherein the metal alloy is a eutectic composition.
19. A cutting element, comprising:
a cutting element substrate; and
a polycrystalline compact bonded to the cutting element substrate, the polycrystalline compact comprising:
a polycrystalline material comprising a plurality of inter-bonded grains of hard material; and
a metallic material disposed in interstitial spaces between the inter-bonded grains of hard material, at least a portion of the metallic material comprising a metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less, the metal alloy comprising two or more elements, a first element of the two or more elements selected from the group consisting of cobalt, iron, and nickel, a second element of the two or more elements selected from the group consisting of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium.
20. The cutting element of claim 19 , wherein the metal alloy comprises a near-eutectic composition.
21. The cutting element of claim 20 , wherein the hard material comprises diamond.
22. The cutting element of claim 21 , wherein the metal alloy has a melting temperature of between about five hundred fifty degrees Celsius (550° C.) and about six hundred fifty degrees Celsius (650° C.).
23. A cutting element, comprising:
a cutting element substrate; and
a polycrystalline compact bonded to the cutting element substrate, the polycrystalline compact comprising:
a polycrystalline material comprising a plurality of inter-bonded grains of hard material; and
a metallic material disposed in interstitial spaces between the inter-bonded grains of hard material, at least a portion of the metallic material comprising a metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less, the metal alloy comprising a near-eutectic composition of at least two elements, a first element of the at least two elements selected from the group consisting of cobalt, iron, and nickel, a second element of the at least two elements selected from the group consisting of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium.
24. The cutting element of claim 23 , wherein the metal alloy is a eutectic composition.
25. An earth-boring tool, comprising:
a tool body; and
at least one cutting element attached to the tool body, the at least one cutting element comprising a polycrystalline compact comprising:
a polycrystalline material comprising a plurality of inter-bonded grains of hard material; and
a metallic material disposed in interstitial spaces between the inter-bonded grains of hard material, at least a portion of the metallic material comprising a metal alloy, having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less, the metal alloy comprising two or more elements, a first element of the two or more elements selected from the group consisting of cobalt, iron, and nickel, a second element of the two or more elements selected from the group consisting of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium.
26. The earth-boring tool of claim 25 , wherein the metal alloy comprises a near-eutectic composition.
27. A method of forming a polycrystalline compact, comprising:
forming an unsintered compact preform comprising a plurality of grains of hard material;
sintering the compact preform in the presence of a catalyst material for catalyzing the formation of inter-granular bonds between the grains of hard material of the plurality of grains of hard material, sintering the compact preform comprising forming a polycrystalline material comprising interbonded grains of hard material formed by bonding together the plurality of grains of hard material;
providing a metal alloy having a melting temperature of about seven hundred fifty degrees Celsius (750° C.) or less in at least some interstitial spaces between the inter-bonded grains of hard material;
formulating the metal alloy to comprise at least two elements;
selecting a first element of the at least two elements from the group consisting of cobalt, iron, and nickel; and
selecting a second element of the at least two elements from the group consisting of dysprosium, yttrium, terbium, gadolinium, germanium, samarium, neodymium, and praseodymium.
28. The method of claim 27 , further comprising sintering the compact preform at a pressure greater than about five gigapascals (5.0 GPa) and a temperature greater than about one thousand three hundred degrees Celsius (1,300° C.).
29. The method of claim 28 , further comprising selecting the plurality of grains of hard material to comprise a plurality of diamond grains.
30. The method of claim 27 , further comprising formulating the metal alloy to comprise a near-eutectic composition.
31. The method of claim 30 , further comprising formulating the metal alloy to comprise a eutectic composition.
32. The method of claim 31 , further comprising formulating the eutectic composition to comprise one of a binary eutectic composition, a ternary eutectic composition, and a quaternary eutectic composition.
33. The method of claim 30 , further comprising formulating the near-eutectic composition to comprise at least one of a near-eutectic composition of cobalt and dysprosium, a near-eutectic composition of cobalt and yttrium, a near-eutectic composition of cobalt and terbium, a near-eutectic composition of cobalt and gadolinium, a near-eutectic composition of cobalt and germanium, a near-eutectic composition of cobalt and samarium, a near-eutectic composition of cobalt and neodymium, and a near-eutectic composition of cobalt and praseodymium.
34. The method of claim 30 , further comprising formulating the near-eutectic composition to comprise at least one of a near-eutectic composition of iron and dysprosium, a near-eutectic composition of iron and yttrium, a near-eutectic composition of iron and terbium, a near-eutectic composition of iron and gadolinium, a near-eutectic composition of iron and germanium, a near-eutectic composition of iron and samarium, a near-eutectic composition of iron and neodymium, and a near-eutectic composition of iron and praseodymium.
35. The method of claim 30 , further comprising formulating the near-eutectic composition to comprise at least one of a near-eutectic composition of nickel and dysprosium, a near-eutectic composition of nickel and yttrium, a near-eutectic composition of nickel and terbium, a near-eutectic composition of nickel and gadolinium, a near-eutectic composition of nickel and germanium, a near-eutectic composition of nickel and samarium, a near-eutectic composition of nickel and neodymium, and a near-eutectic composition of nickel and praseodymium.
36. The method of claim 27 , further comprising formulating the metal alloy to have a melting temperature of about six hundred fifty degrees Celsius (650° C.) or less.
37. The method of claim 36 , further comprising formulating the metal alloy to have a melting temperature of between about five hundred fifty degrees Celsius (550° C.) and about six hundred fifty degrees Celsius (650° C.).
38. The method of claim 27 , further comprising causing the polycrystalline material to comprise between about eighty percent by volume (80 vol %) and about ninety-nine percent by volume (99 vol %) of the polycrystalline compact.
39. The method of claim 38 , further comprising causing the metal alloy to comprise between about one percent by volume (1 vol %) and about twenty percent by volume (20 vol %) of the polycrystalline compact.
40. The method of claim 27 , further comprising:
providing the metal alloy in a first region of the polycrystalline material; and
forming a second region of the polycrystalline material to be at least substantially free of the metal alloy.
41. The method of claim 27 , wherein selecting the first element further comprises selecting the first element to comprise at least a portion of the catalyst material.
42. The method of claim 27 , wherein providing the metal alloy in at least some interstitial spaces between the inter-bonded grains of hard material comprises alloying at least a portion of the catalyst material with at least the second element of the at least two elements.
43. The method of claim 27 , further comprising removing the metal alloy from at least a portion of the interstitial spaces between the inter-bonded grains of hard material.
44. The method of claim 43 , wherein removing the metal alloy comprises heating the metal alloy to a temperature of about seven hundred fifty degrees Celsius (750° C.) or less to melt the metal alloy, and removing the molten metal alloy from the polycrystalline compact prior to using the polycrystalline compact in an earth-boring process.
45. The method of claim 44 , wherein removing the metal alloy comprises removing the metal alloy from the polycrystalline compact during use of the polycrystalline compact in an earth-boring process.