Method and device for cleaning an absorptive polyester
View Patent ↗In a method for cleaning an absorptive polyester, the polymer is dissolved in a first solvent ( 12 ) and subsequently the polymer solution is brought into tight contact with a second solvent ( 41 ) in a turbulent shear field under the influence of strong shear forces. Here, the second solvent ( 41 ) represents a non-solvent for the absorptive polyester and is mixable with the first solvent ( 12 ) to an unlimited extent. Subsequently, the polymer suspension resulting from the addition of the second solvent ( 41 ) is conveyed onto or into a rotating, cylindrical screen body ( 71 ) of a drum shear screen ( 70 ) and then the moist polymer mass is removed from the screen body ( 71 ) and subsequently dried. The method is suitable for the production of absorptive polyester with a high degree of quality and may be performed in a cost-effective fashion on an industrial scale as well.
1. A process for purifying a resorbable polyester, comprising:
(a) dissolving the resorbable polyester in a first solvent to form a polymer solution, wherein the polyester is soluble in the first solvent;
(b) intimately contacting the polymer solution with a second solvent under action of high shear forces in a turbulent shear field to form a polymer suspension, wherein the resorbable polyester is not soluble in the second solvent and the second solvent is miscible with the first solvent;
(c) introducing the polymer suspension into a rotating, cylindrical screen body of a drum shear screen wherein said drum shear screen is obliquely positioned downward along its length relative to the horizontal plane of the body of the apparatus;
(d) separating the polymer suspension into a moist polymer mass and a solvent mixture;
(e) removing the solvent mixture through a liquid outlet;
(f) conveying the moist polymer mass through the rotating, cylindrical screen body to a solid outlet of the drum shear screen wherein one or more helically attached conveyor rails and/or guide blades are present inside the rotating, cylindrical screen body;
(g) separating the moist polymer mass from the screen body through and
(h) drying the polymer mass to obtain a purified resorbable polyester.
2. The process according to claim 1 , wherein the first solvent is acetone, ethyl acetate, 1,4-dioxane, dimethylacetamide, tetrahydrofuran, toluene, dimethylformamide, dimethylsulphoxide, hexafluoroisopropanol or another halogenated hydrocarbon or a mixture of the aforementioned solvents.
3. The process according to claim 2 , wherein the first solvent is acetone, chloroform or dichloromethane.
4. The process according to any one of claims 1 to 3 , wherein the second solvent is ethanol, methanol or water or a mixture thereof.
5. The process according to claim 1 , further comprising:
filtering the polymer solution;
and subsequently mixing the filtered polymer solution with the second solvent via a two-fluid nozzle.
6. The process according to claim 1 , wherein the drying comprises passing nitrogen or air through the polymer mass in a dryer.
7. The process according to claim 1 , wherein the resorbable polyester is an amorphous polyester or partially crystalline polyester.
8. The process according to claim 1 , wherein the resorbable polyester comprises one or more units derived from a lactide glycolide, trimethylene carbonate, epsilon-caprolactone, gamma-butyrolactone, dioxanone, deltavalerolactone and/or similar polymerisable heterocycles and/or polyethylene glycols;
wherein said lactide is at least one member selected from the group consisting of L-lactide, D-lactide, DL-lactide, and meso-lactide.
9. The process according to claim 1 , wherein the resorbable polyester comprises a copolymer of lactide and glycolide and/or polyethylene glycols.
10. The process according to claim 1 , wherein a residual monomer content of the purified resorbable polyester is less than 1%.
11. The process according to claim 1 , wherein a solvent and/or moisture content of the purified resorbable polyester is less than 2%.
12. The process according to claim 1 , wherein the process is a continuously operating separation process and a residual monomer content of the separated resorbable polyester solid is less than 1%.
13. The process according to claim 1 , wherein the process is a continuously operating separation process and a residual monomer content of less than 1% and a solvent and/or moisture content of less than 2% of the purified resorbable polyester mass is obtained irrespective of the amount of polymer suspension.