Latex compositions and uses thereof
View Patent ↗The present technology provides a latex comprising: a mixture of microgels and sol polymers of an acrylic copolymer, wherein the M c of the acrylic copolymer is greater than or equal to the M e thereof; the M w of the sol polymers is greater than or equal to twice the M e of the acrylic copolymer; the amount of sol polymer having a M w less than twice the M e of the acrylic copolymer is about 20 wt % or less than 20 wt %. Such lattices may be used to form films for use as adhesives such as pressure sensitive adhesives. Also provided are methods for manufacturing the films and adhesives.
1. A latex comprising:
a mixture of microgels and sol polymers of an acrylic copolymer, wherein
the M c of the acrylic copolymer is greater than or equal to the M e thereof;
the M w of the sol polymers is greater than or equal to twice the M e of the acrylic copolymer;
the amount of sol polymer having a M w less than twice the M e of the acrylic copolymer is about 20 wt % or less than 20 wt %;
wherein the acrylic copolymer comprises copolymerized monomers of
a low T g acrylic monomer,
a high T g monomer, and
a hydroxyl-containing acrylic monomer; and
wherein the acrylic copolymer further comprises a cross-linker wherein the cross-linker is a copolymerized acrylic monomer containing a second carbon-carbon double bond.
2. The latex of claim 1 wherein the acrylic copolymer comprises about 90 wt % to about 98 wt % of copolymerized low T g acrylic monomer.
3. The latex of claim 1 wherein the low Tg acrylic monomer is selected from the group consisting of butyl acrylate, 2-ethylhexyl acrylate, methyl acrylate, octyl acrylate, sec-butyl acrylate, dodecyl methacrylate, 2-ethoxyethyl acrylate, isobutyl acrylate, 2-methoxyethyl acrylate, octyl methacrylate and any two or more thereof.
4. The latex of claim 1 wherein the acrylic copolymer comprises about 1 wt % to about 9 wt % of copolymerized high T g monomer.
5. The latex of claim 1 wherein the high T g monomer is selected from the group consisting of methyl methacrylate, ethyl methacrylate, phenyl methacrylate, isobornyl methacrylate, methacrylic acid, acrylic acid, cyclohexyl methacrylate, isobornyl acrylate, isopropyl methacrylate, styrene, vinyl acetate, and any two or more thereof.
6. The latex of claim 1 wherein the acrylic copolymer comprises about 1 wt % to about 9 wt % of copolymerized hydroxyl-containing acrylic monomer.
7. The latex of claim 1 wherein the hydroxyl-containing acrylic monomer is selected from the group consisting of 2-hydroxyethyl methacrylate, 2-hydroxyethyl acrylate, 3-hydroxypropyl methacrylate, 3-hydroxypropyl acrylate and any two or more thereof.
8. The latex of claim 1 wherein the cross-linker is selected from the group consisting of allyl methacrylate, allyl acrylate, ethylene glycol diacrylate, butanediol acrylate, 1,6-hexanediol diacrylate, and any two or more thereof.
9. The latex of claim 1 comprising a surfactant.
10. The latex of claim 9 wherein the surfactant is selected from the group consisting of sodium dodecyl sulfate, sodium dodecyl benzene sulfate and combinations thereof.
11. The latex of claim 1 which is gel-free.
12. The latex of claim 1 having a gel content of at least about 20 wt %.
13. The latex of claim 1 having a gel content of at least about 60 wt %.
14. The latex of claim 1 wherein the amount of the sol polymers having a M w greater than twenty times the M e of the acrylic copolymer is about 20 wt % or less than 20 wt %.
15. The latex of claim 1 wherein the latex is an adhesive.
16. A method of manufacturing a latex comprising:
polymerizing a monomer emulsion comprising water, a low T g acrylic monomer, a high T g monomer, a hydroxyl-containing acrylic monomer, and a cross-linker which is a copolymerized acrylic monomer containing a second carbon-carbon double bond, to provide a latex comprising a mixture of microgels and sol polymers of an acrylic copolymer; and
wherein
the M c of the acrylic copolymer is greater than or equal to the M e thereof;
the M w of the sol polymers is greater than or equal to twice the M e of the acrylic copolymer;
the amount of sol polymer having a M w less than twice the M e of the acrylic copolymer is about 20 wt % or less than 20 wt %.
17. A film formed from a latex comprising:
a mixture of microgels and sol polymers of an acrylic copolymer, wherein
the M c of the acrylic copolymer is greater than or equal to the M e thereof;
the M w of the sol polymers is greater than or equal to twice the M e of the acrylic copolymer;
the amount of sol polymer having a M w less than twice the M e of the acrylic copolymer is about 20 wt % or less than 20 wt %;
wherein the acrylic copolymer comprises copolymerized monomers of
a low T g acrylic monomer,
a high T g monomer, and
a hydroxyl-containing acrylic monomer; and
wherein the acrylic copolymer further comprises a cross-linker wherein the cross-linker is copolymerized acrylic monomer containing a second carbon-carbon double bond.
18. A method of manufacturing a film comprising casting a latex into a film and drying the film wherein the latex comprises:
a mixture of microgels and sol polymers of an acrylic copolymer, wherein
the M c of the acrylic copolymer is greater than or equal to the M e thereof;
the M w of the sol polymers is greater than or equal to twice the M e of the acrylic copolymer;
the amount of sol polymer having a M w less than twice the M e of the acrylic copolymer is about 20 wt % or less than 20 wt %;
wherein the acrylic copolymer comprises copolymerized monomers of
a low T g acrylic monomer,
a high T g monomer, and
a hydroxyl-containing acrylic monomer; and
wherein the acrylic copolymer further comprises a cross-linker wherein the cross-linker is a copolymerized acrylic monomer containing a second carbon-carbon bond.