IP Library Granted Patent US 8,882,912
Granted Patent B2
US 8,882,912 · App. 13/034,956 · Granted Nov 11, 2014

Method and system for forming a silicon ingot using a low-grade silicon feedstock

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Quick Facts
Patent No.
US 8,882,912
App. No.
13/034,956
Granted
Nov 11, 2014
Kind
B2
Abstract

Techniques for the formation of a silicon ingot using a low-grade silicon feedstock include forming within a crucible device a molten silicon from a low-grade silicon feedstock and performing a directional solidification of the molten silicon to form a silicon ingot within the crucible device. The directional solidification forms a generally solidified quantity of silicon and a generally molten quantity of silicon. The method and system include removing from the crucible device at least a portion of the generally molten quantity of silicon while retaining within the crucible device the generally solidified quantity of silicon. Controlling the directional solidification of the generally solidified quantity of silicon, while removing the more contaminated molten silicon, results in a silicon ingot possessing a generally higher grade of silicon than the low-grade silicon feedstock.

Claims (22)

1. A system for forming a silicon ingot using a low-grade silicon feedstock, said silicon ingot comprising higher grade silicon than said low-grade silicon feedstock, comprising:

a crucible device for receiving and heating a low-grade silicon feedstock and for forming a molten silicon in response to the heating;

temperature control means for performing a directional solidification of the molten silicon to form a silicon ingot within the crucible device, the temperature control means configured to form the silicon ingot from the bottom of the crucible device toward the top to form a solidified quantity of silicon and a molten quantity of silicon on top of the solidified quantity of silicon, wherein the temperature control means is configured so that the directional solidification increases the height of the combined solidified quantity of silicon and the molten quantity of silicon within the crucible device;

a pathway associated with the crucible device for removing from the crucible device at least a portion of the molten quantity of silicon while retaining within the crucible device the solidified quantity of silicon by flowing at least the portion of the molten quantity of silicon from the crucible device via the pathway, wherein the pathway is positioned at a height so that the increase in height due to the directional solidification allows at least the portion of the molten quantity of silicon to reach the height of the pathway.

2. The system of claim 1 , further comprising means for pre-conditioning the molten silicon for extracting impurities from the low-grade silicon.

3. The system of claim 1 , further comprising a bubble nucleation source associated with the crucible device for pre-conditioning the molten silicon by introducing bubble nucleation into the molten silicon.

4. The system of claim 1 , further comprising a bubble nucleation source for introducing gas bubble nucleation into the molten silicon using gases selected from the group consisting of oxygen, nitrogen, hydrogen, water vapor, carbon dioxide and chlorine-containing gases.

5. The system of claim 1 , further comprising an ultrasonic energy source associated with the crucible device for transmitting ultrasonic energy into the molten silicon for enhancing the extraction of impurities from the molten silicon.

6. The system of claim 1 , further comprising a means for adding an additive to the molten silicon for aiding in the extraction of the impurities from the molten silicon.

7. The system of claim 1 , wherein the temperature control means is configured to control the duration of the directional solidification to reduce material stresses arising from the crystallization of the silicon ingot.

8. The system of claim 1 , wherein the pathway comprises a lower interstitial wall separating a first volume of the crucible device from a second volume of the crucible device,

the first volume of the crucible device containing the solidified quantity of silicon and the molten quantity of silicon;

the lower interstitial wall further having a height approximating a height of a predetermined interface level between the solidified quantity of silicon and the molten quantity of silicon at a predetermined point during the directional solidification; and

the lower interstitial wall permitting at least the portion of the molten quantity of silicon to flow from the first volume of the crucible device to the second volume of the crucible device, thereby separating at least the portion of the molten quantity of silicon from the solidified quantity of silicon.

9. The system of claim 8 , wherein the second volume surrounds the first volume for flowing at least the portion of the molten quantity of silicon into the second volume surrounding the first volume.

10. The system of claim 1 , said pathway comprising:

a felt device for absorbing at least the portion of the molten quantity of silicon means for positioning the felt device into the portion of the molten quantity of silicon; and

means for removing the felt device including the absorbed portion of the molten quantity of silicon from the crucible device.

11. The system of claim 1 , wherein the pathway comprises a drain conduit and a plug device associated to control flow of the molten quantity of silicon through the drain conduit for controllably positioning the plug device, thereby controlling flow of the molten quantity of silicon from the crucible device and disassociating at least the portion of the molten quantity of silicon from the solidified quantity of silicon.

12. The system of claim 1 , wherein the pathway comprises a drain conduit separating a first volume of the crucible device from a second volume of the crucible device, and a plug device to control flow of the molten quantity of silicon through the drain conduit for controlling flow of the molten quantity of silicon from the first volume to the second volume, thereby disassociating at least the portion of the molten quantity of silicon from the solidified quantity of silicon.

13. The system of claim 12 , wherein the second volume surrounds the first volume for flowing at least the portion of the molten quantity of silicon into the second volume surrounding the first volume.

14. The system of claim 1 , wherein the temperature control means is configured to hold the silicon ingot at an elevated temperature following removal of the molten quantity of silicon to remove stress-related structural defects in the silicon ingot, thereby enhancing silicon ingot quality.

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2023
From: SUNNUVELLIR SLHF
To: HIGHLAND MATERIALS, INC.
Reel/Frame 064388/0757 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 25, 2023
From: SILICOR MATERIALS, INC.
To: SUNNUVELLIR SLHF
Reel/Frame 062511/0046 →
LIEN Recorded May 26, 2017
From: SILICOR MATERIALS, INC.
To: SCHWEGMAN, LUNDBERG & WOESSNER, P.A.
Reel/Frame 042592/0974 →
SECURITY INTEREST Recorded Dec 27, 2016
From: SILICOR MATERIALS, INC.
To: SUNNUVELLIR SLHF
Reel/Frame 040777/0104 →
LICENSE Recorded Oct 13, 2015
From: SILICOR MATERIALS, INC.
To: SMS GROUP GMBH
Reel/Frame 036811/0327 →
RELEASE Recorded Aug 25, 2015
From: SILICON VALLEY BANK
To: SILICOR MARTERIALS, INC. FKA CALISOLAR INC.
Reel/Frame 036448/0613 →
CHANGE OF NAME Recorded Nov 20, 2012
From: CALISOLAR INC.
To: SILICOR MATERIALS INC.
Reel/Frame 029397/0001 →
SECURITY AGREEMENT Recorded Oct 27, 2011
From: CALISOLAR INC.
To: SILICON VALLEY BANK
Reel/Frame 027131/0042 →
SECURITY AGREEMENT Recorded Oct 25, 2011
From: CALISOLAR INC.
To: GOLD HILL CAPITAL 2008, LP
Reel/Frame 027119/0928 →