Compartmentalized pellet for improved contaminant removal
This invention is to an improved method for cleaning contaminated polymer when that polymer is to be blended with clean material. The method involves combining the contaminated material and the clean material in a compartmentalized pellet wherein the contaminated material is placed in the outermost compartment, the clean material is placed in an inner compartment and then subjecting the pellet to an extraction process.
1. A method of purifying postconsumer polyester comprising:
cleaning comminuted pieces of postconsumer polyester to remove surface contaminants therefrom thereby producing surface cleaned postconsumer polyester pieces;
melting the surface-cleaned postconsumer polyester pieces to produce a postconsumer polyester melt;
extruding the postconsumer polyester melt to reduce the intrinsic viscosity of the postconsumer polyester melt and remove additional contaminants;
forming a compartmentalized strand comprised of at least an outer compartment and an inner compartment wherein the outer compartment is next to air and consists of postconsumer polyester melt and the inner compartment consists of virgin polyester melt;
solidifying and pelletizing the compartmentalized strand to make solid compartmentalized pellets; and
extracting contaminants from the solid compartmentalized pellets.
2. The process of claim 1 , wherein the postconsumer polyester is less than 35 weight percent of the compartmentalized pellet.
3. The process of claim 2 wherein the extraction step comprises maintaining the compartmentalized pellets in a temperature range of 150° C. and 5° C. less than the melt point of the pellet and removing the contaminants from the surface of the pellet.
4. The process of claim 3 , wherein the step of removing the contaminants from the surface comprises passing a vapor over the pellets.
5. The process of claim 4 , wherein the vapor is non-reactive to the postconsumer polyester in the compartmentalized pellet.
6. The process of claim 5 , wherein the vapor is an inert gas, or mixture of inert gases.
7. The process of claim 2 wherein the extraction step comprises exposing the compartmentalized pellets to a liquid which removes at least one contaminant.
8. The process of claim 7 wherein polyamide is soluble in the liquid.
9. The process of claim 8 the liquid is formic acid or ethylene glycol.