Electric storage device
View Patent ↗In an electric storage device, lithium electrodes are disposed on respective outermost portions of an electrode laminated unit in which a positive electrode and a negative electrode are laminated alternately via positive/negative electrode separators. The lithium electrode includes lithium metal serving as a lithium ion supply source, and a lithium electrode separator (a non-woven fabric separator) constituted by a non-woven fabric that satisfies the following conditions: (a) an average fiber diameter of 0.1 μm to 10 μm; and (b) a thickness of 5 μm to 500 μm is provided. By forming the lithium electrode separator that contacts the lithium electrode including the lithium ion supply source from a non-woven fabric in this manner, a dramatic improvement can be achieved in the cycle characteristic of the electric storage device.
1. An electric storage device comprising:
a positive electrode;
a negative electrode;
a separator facing the negative electrode which is formed of one material; and
a lithium electrode having a lithium ion supply source for supplying lithium ions to the positive electrode and/or the negative electrode,
wherein the lithium electrode is disposed at a distance from the positive electrode or the negative electrode via a lithium electrode separator made of a non-woven fabric that satisfies following conditions: (a) an average fiber diameter of 0.1 μm to 10 μm; (b) a thickness of 5 μm to 500 μm; (c) a gas permeability (seconds/100 cm3) of 100 or less; and (d) a polycarbonate liquid absorption rate (mm/10 minutes) of 20 or more;
wherein the non-woven fabric includes aramid fibers; and
wherein the separator facing the negative electrode formed of one material is of a different material than the lithium electrode separator facing the lithium electrode.
2. The electric storage device according to claim 1 , wherein the lithium electrode separator is disposed on the lithium ion supply source.
3. The electric storage device according to claim 1 , wherein the non-woven fabric includes fibers constituted by another polymeric material containing a hydrophilic functional group.
4. The electric storage device according to claim 3 , wherein the electric storage device is a lithium ion secondary battery.
5. The electric storage device according to claim 1 , wherein the separator facing the negative electrode is formed of a polyolefin-based porous membrane.