Substrate clean solution for copper contamination removal
View Patent ↗Embodiments of the invention generally relate to a method for selectively etching or otherwise removing copper or other metallic contaminants from a substrate, such as a gallium arsenide wafer. In one embodiment, a method for selectively removing metallic contaminants from a substrate surface is provided which includes exposing a substrate to a peroxide clean solution, exposing the substrate to a hydroxide clean solution, and exposing the substrate to a selective etch solution containing potassium iodide, iodine, sulfuric acid, and water during a selective etch process. The substrate generally contains gallium arsenide material, such as crystalline gallium arsenide, and is usually a growth substrate for an epitaxial lift off (ELO) process. The copper or other metallic contaminants disposed on the substrate may be selectively etched at a rate of about 500 times, about 1,000 times, about 2,000 times, or about 4,000 times or greater than the gallium arsenide material.
1. A method for selectively removing metallic contaminants from a substrate surface, comprising:
exposing a substrate to a peroxide clean solution subsequent an epitaxial lift off (ELO) process, wherein the substrate comprises gallium arsenide material, and disposing a copper contaminant on the substrate at a first copper contaminant concentration of at least 1×10 15 copper atoms/cm 2
exposing the substrate to a hydroxide clean solution; and
exposing the substrate to a selective etch solution comprising potassium iodide, iodine, sulfuric acid, and water during a selective etch process, wherein the copper contaminant is selectively etched at a rate of about 100 times or greater than the gallium arsenide material and the first copper contaminant concentration is lowered to a second copper contaminant concentration of about 1×10 14 copper atoms/cm 2 or less and wherein the substrate is exposed to a rinse step followed by a drying step using a drying gas comprising at least one of nitrogen (N2), argon, helium, neon, ambient air, dried air and hydrogen subsequent to being exposed to the hydroxide clean solution and prior to being exposed to the selective etch solution.
2. The method of claim 1 , wherein the second copper contaminant concentration is about 1×10 13 copper atoms/cm 2 or less.
3. A method for selectively removing metallic contaminants from a substrate surface, comprising:
exposing a substrate comprising a gallium arsenide material to an ELO etch solution comprising a complexing inhibitor compound during an epitaxial lift off process, wherein a sacrificial layer is disposed on the substrate and an epitaxial film is disposed on the sacrificial layer;
etching the sacrificial layer while peeling the substrate from the wafer;
forming the copper contaminant on the substrate; and
separating the epitaxial film from the substrate containing the copper contaminant;
rinsing the substrate to remove residues of the ELO etch solution;
exposing the substrate to a peroxide clean solution after said rinsing the substrate to remove residues of the ELO etch solution;
rinsing the substrate to remove residues of the peroxide clean solution;
exposing the substrate to a hydroxide clean solution;
rinsing the substrate to remove residues of the hydroxide clean solution; and
exposing the substrate to a selective etch solution comprising potassium iodide, iodine, sulfuric acid, and water during a selective etch process, wherein the copper contaminant is selectively etched at a rate of about 100 times or greater than the gallium arsenide material during the selective etch process and wherein the substrate is exposed to a drying step using a drying gas comprising at least one of nitrogen (N2), argon, helium, neon, ambient air, dried air and hydrogen subsequent to being exposed to the hydroxide clean solution and prior to being exposed to the selective etch solution.
4. The method of claim 3 , wherein the peroxide clean solution comprises hydrogen peroxide.
5. The method of claim 3 wherein the copper contaminant concentration is about 1×10 15 copper atoms/cm 2 or less.
6. The method of claim 3 , wherein the hydroxide clean solution comprises ammonium hydroxide.
7. The method of claim 3 wherein the rinsing is performed with deionized water.
8. The method of claim 3 , wherein said selective etch solution comprises a temperature range between −10° C. to 10° C.
9. The method of claim 3 , wherein the substrate is exposed to the selective etch solution during a second selective etch process for a time period within a range from about 5 seconds to about 20 seconds.
10. The method of claim 3 , wherein the substrate is exposed to the peroxide clean solution for a time period within a range from about 20 seconds to about 40 seconds.
11. A method for selectively removing metallic contaminants from a substrate surface, comprising:
exposing a substrate to a peroxide clean solution subsequent an epitaxial lift off (ELO) process, wherein the substrate comprises gallium arsenide material and a copper contaminant is disposed on the substrate;
exposing the substrate to a hydroxide clean solution; and
exposing the substrate to a selective etch solution comprising potassium iodide, iodine, sulfuric acid, and water during a selective etch process, wherein the copper contaminant is selectively etched at a rate of about 100 times or greater than the gallium arsenide material,
wherein the substrate is exposed to a rinse step followed by a drying step using a drying gas comprising at least one of nitrogen (N2), argon, helium, neon, ambient air, dried air and hydrogen subsequent to being exposed to the peroxide solution and prior to being exposed to the hydroxide solution, and
wherein the substrate is exposed to a rinse step followed by a drying step subsequent to being exposed to the hydroxide solution and prior to being exposed to the selective etch solution.
12. The method of claim 11 , wherein the substrate is exposed to the peroxide clean solution for a time period within a range from about 20 seconds to about 40 seconds.
13. The method of claim 11 , wherein the substrate is exposed to the hydroxide clean solution for a time period within a range from about 20 seconds to about 40 seconds.
14. The method of claim 11 , wherein the substrate is exposed to the selective etch solution during the selective etch process for a time period within a range from about 5 seconds to about 20 seconds.
15. The method of claim 11 , further comprising exposing the substrate to an ELO etch solution during an ELO process prior to exposing the substrate to the peroxide clean solution.
16. The method of claim 15 , wherein the ELO process comprises:
exposing the substrate containing an epitaxial film disposed thereon to the ELO etch solution, wherein a sacrificial layer is disposed between the substrate and the epitaxial film;
etching the sacrificial layer while peeling the epitaxial film from the substrate;
forming the copper contaminant on the substrate; and
separating the epitaxial film from the substrate containing the copper contaminant.
17. The method of claim 11 , further comprising:
removing the substrate from the selective etch solution;
rinsing the substrate to remove residues of the selective etch solution or other contaminants disposed thereon;
drying the substrate using a drying gas; and
exposing the substrate to the selective etch solution during a second selective etch process.
18. The method of claim 17 , wherein the substrate is rinsed with deionized water.
19. The method of claim 17 , wherein the substrate is exposed to the selective etch solution during the second selective etch process for a time period within a range from about 5 seconds to about 20 seconds.
20. The method of claim 17 , wherein the substrate is exposed to a rinse step with deionized water followed by a drying step subsequent to the second selective etch process.