Compositions and methods for UV-curable cosmetic nail coatings
View Patent ↗The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions that provide improved adhesion-promoting and improved solvent-susceptibility.
1. The removable, adhesion-promoting nail coating composition comprising a polymerizable (meth)acrylate, a urethane (meth)acrylate resin and an adhesion promoter selected from the group consisting of:
hydroxypropyl methacrylate (HPMA),
hydroxyethyl methacrylate (HEMA),
ethyl methacrylate (EMA),
tetrahydrofurfuryl methacrylate THFMA,
pyromellitic dianhydride di(meth)acrylate,
pyromellitic dianhydride glyceryl dimethacrylate (PMGDM),
pyromellitic dimethacrylate,
methacroyloxyethyl maleate,
2-hydroxyethyl methacrylate/succinate,
1,3-glycerol dimethacrylate/succinate adduct,
phthalic acid monoethyl methacrylate,
butyl methacrylate,
isobutyl methacrylate,
PEG-4 dimethacrylate,
PPG monomethacrylate,
trimethylolpropane trimethacrylate,
isopropylidenediphenyl bisglycidyl methacrylate,
lauryl methacrylate,
cyclohexyl methacrylate,
hexyl methacrylate,
urethane methacrylate,
triethylene glycol dimethacrylate,
ethylene glycol dimethacrylate,
tetraethylene glycol dimethacrylate,
trimethylolpropane trimethacrylate,
neopentylglycol dimethacylate,
acetoacetoxy methacrylate,
acetoacetoxyethyl methacrylate, (AAEMA)
polyetheramine,
glycidyl methacrylates,
maleic anhydride,
terpolymers containing vinyl acetate,
organosilanes,
organotitanates,
chlorinated polyolefins,
sucrose acetate isobutyrate,
caprylic/capric triglyceride,
glyceryl hydrogenated rosinate,
pentaerythryl hydrogenated rosinate,
styrene/methyl styrene/indene copolymer,
blocked isocyanate PVC,
polyamidoamine PVC,
and mixtures thereof;
wherein the polymerizable (meth)acrylate is different from the adhesion promoter, and the urethane (meth)acrylate resin is different from the adhesion promoter,
wherein said composition cures to a thermoset, and
removal of the cured coating from a nail surface upon exposure to an organic solvent is achieved in less than 20 minutes without abrading the coating or nail surface.
2. The removable, adhesion-promoting nail coating composition according to claim 1 , further comprising a solvent-sensitivity enhancing monomer or oligomer and a non-reactive, solvent-dissolvable polymer.
3. The removable, adhesion-promoting nail coating composition of claim 2 , wherein said non-reactive, solvent-dissolvable polymer is selected from the group consisting of:
cellulose esters,
polyvinylbutyral resins,
tosylamide (toluensulfonamide) formaldehyde resins,
ethyl tosylamide,
adipic acid/fumaric acid/phthalic acid/tricyclodecane dimethanol copolymer,
adipic acid/neopentyl glycol/trimellitic anhydride copolymer,
phthalic anhydride/trimellitic anhydride/glycols copolymer,
polyethyl cellulose,
polyhydroxypropyl cellulose,
polyethyl acrylate oxide,
poly lactic acid,
nitrocellulose,
and mixtures thereof.
4. The removable, adhesion-promoting nail coating composition of claim 3 , wherein said cellulose ester is selected from the group consisting of cellulose acetate butyrate, cellulose acetate propionate, and mixtures thereof.
5. The removable, adhesion-promoting nail coating composition of claim 1 , wherein said polymerizable (meth)acrylate is a polyol modified (meth)acrylate.
6. The removable, adhesion-promoting nail coating composition of claim 5 , wherein said polyol modified (meth)acrylate is a polyol modified urethane (meth)acrylate.
7. The removable, adhesion-promoting nail coating composition of claim 1 , wherein said polymerizable (meth)acrylate is a polyalkyleneglycol modified (meth)acrylate.
8. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising at least one PMMA-PMAA copolymer.
9. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the adhesion promoter comprises at least one PMGDM.
10. The removable, adhesion-promoting nail coating composition of claim 1 , wherein said thermoset remains intact to at least 150 acetone double rubs.
11. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising a non-reactive solvent.
12. The removable, adhesion-promoting nail coating composition of claim 2 , wherein said solvent-sensitivity enhancing monomer or oligomer is selected from the group consisting of:
polyethylene glycol (meth)acrylates,
polypropylene glycol (meth)acrylates,
polybutylene glycol (meth)acrylates,
propoxylated allyl methacrylate
methoxy polyethylene glycol (350) monomethacrylate,
polyethylene glycol (600) monomethacrylate,
stearyl methacrylate,
tridecyl methacrylate,
hydroxyethyl methacrylate acetate,
and mixtures thereof;
wherein the solvent-sensitivity enhancing monomer or oligomer is different from the adhesion promoter.
13. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising up to 5 wt % of a plasticizer.
14. The removable, adhesion-promoting nail coating composition of claim 13 , wherein said plasticizer is selected from the group consisting of:
esters,
low volatility solvents
paraffinic hydrocarbons
butyrolactone,
xylene,
methyl isobutyl ketone,
non-ionic surfactants,
non-ionic silicones,
isostearyl isononanoate,
silicones,
diisobutyl adipate,
trimethyl pentanyl diiisobutyrate,
acetyl tributyl citrate,
and mixtures thereof.
15. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising up to 10 wt % of a photoinitiator.
16. The removable, adhesion-promoting nail coating composition of claim 15 , wherein said photoinitiator is selected from the group consisting of ethyl trimethylbenzoyl phenylphosphinate, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, hydroxycyclohexyl phenyl ketone, benzyl dimethyl ketal, and mixtures thereof.
17. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising up to 5 wt % of a UV-absorber.
18. The removable, adhesion-promoting nail coating composition of claim 17 , wherein said UV-absorber is selected from the group consisting of:
hydroxy benzotriazole compounds,
2-(2-hydroxy-5′-methylphenyl)benzotriazole,
benzophenones 1-12,
3-benzylidene camphor,
benzyl salicylate,
borneolone,
bumetrizole,
PABA,
butyl PABA,
butyl methoxydibenzoymethane,
cinoxate,
DEA-methoxycinnamate,
dibenzoxazoyl naphthalene,
digalloyl trioleate,
diisopropyl methyl cinnamate,
and mixtures thereof.
19. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising a filler.
20. The removable, adhesion-promoting nail coating composition of claim 19 , wherein said filler is selected from the group consisting of silica, metal oxide, nanosilica, nanoalumina, and mixtures thereof.
21. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising up to 10 wt % of a colorant.
22. The removable, adhesion-promoting nail coating composition of claim 21 , wherein said colorant is selected from the group consisting of dyes, pigments, effects pigments and mixtures thereof.
23. The removable, adhesion-promoting nail coating composition of claim 1 , further comprising a rheology modifier.
24. The removable, adhesion-promoting nail coating composition of claim 23 , wherein said rheology modifier is selected from the group consisting of:
stearalkonium hectorite,
calcium aluminum borosilicate,
calcium sodium borosilicate,
synthetic fluorphlogopite,
silica,
titanium oxide,
tin oxide,
and mixtures thereof.
25. A method of providing ease of removal of a cured nail coating comprising adding at least one solvent-sensitivity enhancing monomer or oligomer that is an acrylated or methacrylated monomer of polyethyleneglycol (PEG), polypropyleneglycol (PPG), or polybutyleneglycol (PBG) to the nail coating composition of claim 1 before curing.
26. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the polymerizable (meth)acrylate is selected from the group consisting of hydroxypropyl methacrylate and hydroxyethyl methacrylate.
27. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the polymerizable (meth)acrylate is hydroxypropyl methacrylate.
28. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the polymerizable (meth)acrylate is hydroxyethyl methacrylate.
29. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the adhesion promoter is selected from the group consisting of hydroxypropyl methacrylate, hydroxyethyl methacrylate and tetrahydrofurfuryl methacrylate (THFMA).
30. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the adhesion promoter is tetrahydrofurfuryl methacrylate (THFMA).
31. The removable, adhesion-promoting nail coating composition of claim 1 , wherein the polymerizable (meth)acrylate and the adhesion promoter are hydroxypropyl methacrylate and hydroxyethyl methacrylate, respectively.
32. The removable, adhesion-promoting nail coating composition according to claim 1 , further comprising a non-reactive, solvent-dissolvable polymer.
33. The removable, adhesion-promoting nail coating composition of claim 32 , wherein said non-reactive, solvent-dissolvable polymer is selected from the group consisting of:
cellulose esters,
polyvinylbutyral resins,
tosylamide (toluensulfonamide) formaldehyde resins,
ethyl tosylamide,
adipic acid/fumaric acid/phthalic acid/tricyclodecane dimethanol copolymer,
adipic acid/neopentyl glycol/trimellitic anhydride copolymer,
phthalic anhydride/trimellitic anhydride/glycols copolymer,
polyethyl cellulose,
polyhydroxypropyl cellulose,
polyethyl acrylate oxide,
poly lactic acid,
nitrocellulose,
and mixtures thereof.
34. The removable, adhesion-promoting nail coating composition of claim 33 , wherein said cellulose ester is selected from the group consisting of cellulose acetate butyrate, cellulose acetate propionate, and mixtures thereof.