Nanocomposite comprising exfoliated nanoclay-styrenic concentrate and methods of preparation
View Patent ↗A composition is disclosed comprising a styrenic first polymer, nanoclay, and an emulsifier compound, which can be blended with an additional polymer. A nanocomposite exhibits improved heat resistant properties and stiffness. In one embodiment, the additional polymer is poly(phenylene ether). An article and a method for the preparation a nanocomposite are also disclosed. In one embodiment, the process of obtaining a nanocomposite comprises emulsion polymerizing styrenic monomers in the presence of an aqueous dispersion of nanoclay and emulsifier compound, wherein an aqueous mixed dispersion comprising styrenic polymer and nanoclay is formed; coagulating the aqueous mixed dispersion with a coagulating agent to form a coagulated mixed dispersion comprising nanoclay and styrenic polymer; solidifying the coagulated mixed dispersion to form a polymeric clay concentrate comprising the nanoclay and the styrenic polymer as a carrier resin; and mixing the polymeric nanoclay concentrate, directly or indirectly with an additional polymer to form a nanocomposite.
1. A composition for a polymeric nanoclay concentrate comprising:
a styrenic polymer in an amount of greater than or equal to 70 percent and less than or equal to 95 percent, based on total weight of composition; wherein the styrenic polymer is a homopolymer of styrene, chlorostyrene, or vinyltoluene, or a random copolymer comprising styrene and one or more monomers selected from the group consisting of acrylonitrile, butadiene, alpha-methylstyrene, ethylvinylbenzene, divinylbenzene, maleic anhydride, and C 1 to C 4 alkyl esters of acrylate or methacrylate;
a nanoclay in an amount of greater than or equal to 5 percent and less than or equal to 30 percent, based on total weight of composition;
an emulsifier compound in an amount of 1 to 10 percent, based on total weight of composition; wherein the emulsifier compound is an organic salt compound comprising an anionic substituent covalently bonded to an organic moiety and a cationic counter ion; and
a coagulating agent comprising calcium chloride;
wherein the nanoclay has been substantially untreated with respect to cation exchange; and
where the nanoclay comprises particles that are exfoliated in a polymeric matrix comprising the styrenic polymer.
2. The composition of claim 1 wherein the emulsifier compound is a C 4 to C 30 organic sulfonate compound.
3. The composition of claim 1 wherein the styrenic polymer was obtained by emulsion polymerization in the presence of an aqueous dispersion of the nanoclay and emulsifier compound to form a dispersed aqueous mixture of the nanoclay and styrenic polymer, which mixture was then coagulated to obtain the polymeric nanoclay concentrate.
4. The composition of claim 1 wherein the nanoclay comprises platelets of a layered silicate.
5. The composition of claim 4 wherein the layered silicate is selected from the group consisting of montmorillonite, hectorite, saponite, mica, vermiculite, bentonite, nontronite, beidellite, volkonskoite, magadite, kenyaite, and mixtures thereof.
6. The composition of claim 1 wherein the styrenic polymer contains at least 25 weight percent of structural units derived from a monomer represented by the following structure:
wherein R 1 is hydrogen, lower alkyl having from 1 to 7 carbon atoms, or halogen; Z 1 is vinyl, halogen, or lower alkyl having from 1 to 7 carbon atoms; and p is from 1 to 5.
7. The composition of claim 1 wherein the nanoclay is present in an amount of greater than or equal to 8 percent and less than or equal to 24 percent, by weight of the composition, and the styrenic polymer is present in an amount of greater than or equal to 76 percent and less than or equal to 92 percent, by weight of the composition.
8. The composition of claim 4 , wherein the layered silicate is bentonite.