IP Library Granted Patent US 8,410,205
Granted Patent B2
US 8,410,205 · App. 13/047,085 · Granted Apr 2, 2013

Matting agent composition containing low molecular weight polytrimethylene ether glycol

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Quick Facts
Patent No.
US 8,410,205
App. No.
13/047,085
Filed
Mar 14, 2011
Granted
Apr 2, 2013
Kind
B2
Examiner
CHIN, HUI H
Art Unit
1762
USPC
524/377
Abstract

The present invention is directed to a matting agent for reducing gloss of a coating. The matting agent comprises: a) a silica component; b) a polytrimethylene ether glycol; c) one or more solvents; and d) optionally, one or more polymers. This invention is further directed to a matting agent comprising components derived from renewable resources.

Claims (33)

1. A matting agent comprising:

a) a silica component,

b) a polytrimethylene ether glycol having a Mn (number average molecular weight) in a range of from 134 to 490; and

c) one or more solvents;

wherein said polytrimethylene ether glycol is fractionated and free from hexamers and heptamers of 1,3-propanediol.

2. The matting agent of claim 1 further comprising:

d) one or more polymers selected from acrylic polymer, polyester polymer, or a combination thereof.

3. The matting agent of claim 1 , wherein the polytrimethylene ether glycol has a Mn in a range of from 200 to 490.

4. The matting agent of claim 1 , wherein the polytrimethylene ether glycol has in a range of from 10% to 100% of dimers, percentage based on the total weight of the polytrimethylene ether glycol.

5. The matting agent of claim 1 , wherein the polytrimethylene ether glycol is polymerized from bio-derived 1,3-propanediol.

6. The matting agent of claim 1 , wherein said silica component comprises silica particles having an average particle size in a range of from 2 to 20 micrometers.

7. The matting agent of claim 6 , wherein said silica particles are hydrophobic silica particles.

8. The matting agent of claim 2 , wherein said acrylic polymers are selected from linear or branched acrylic polymers having one or more hydroxyl functional groups, or a combination thereof.

9. The matting agent of claim 2 , wherein said polyester polymers are selected from linear or branched polyester polymers having one or more hydroxyl functional groups, or a combination thereof.

10. A method for reducing gloss of a dry coating layer on a substrate, said coating layer is formed from a coating composition, said method comprising the steps of:

i) providing a matting agent comprising:

a) a silica component;

b) a polytrimethylene ether glycol having a Mn (number average molecular weight) in a range of from 134 to 490;

c) one or more solvents wherein said polytrimethylene ether glycol is fractionated and free from hexamers and heptamers of 1,3-propanediol; and

d) one or more polymers selected from acrylic polymers, polyester polymers, or a combination thereof.

ii) mixing said matting agent with said coating composition to form a matt coating mix;

iii) applying said matt coating mix over said substrate to form a wet coating layer; and

iv) curing said wet coating layer to form said dry coating layer.

11. The method of claim 10 , wherein said coating composition comprises a crosslinakble component and a crosslinking component.

12. The method of claim 11 , wherein said crosslinkable component comprises hydroxyl crosslinkable functional groups.

13. The method of claim 11 , wherein said crosslinking component comprises isocyanate crosslinking functional groups.

14. The method of claim 10 , wherein said silica component comprises silica particles having an average particle size in a range of from 2 to 20 micrometers.

15. The method of claim 14 , wherein said silica particles are hydrophobic silica particles.

16. The method of claim 10 , wherein said coating composition is selected from a one-pack coating composition or a two-pack coating composition.

17. The method of claim 10 , wherein said substrate is selected from tools, equipments, sporting goods, vehicle body, vehicle body parts, consumer electronics, consumer appliances, residential or industrial structures.

18. A substrate coated with the method of claim 10 .

19. A substrate coated with a matt coating mix comprising the matting agent of claim 1 and a coating composition.

20. The matting agent of claim 1 , wherein said polytrimethylene ether glycol is free from hexamers and heptamers of 1,3-propanediol as analyzed by GC-MS.

Assignments (5)
RELEASE OF SECURITY INTEREST Recorded Sep 29, 2016
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: AXALTA COATING SYSTEMS IP CO. LLC (FORMERLY KNOWN AS U.S. COATINGS IP CO. LLC)
Reel/Frame 040184/0192 →
SECURITY AGREEMENT Recorded Nov 19, 2013
From: U.S. COATINGS IP CO. LLC (N/K/A AXALTA COATING SYSTEMS IP CO. LLC)
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 031668/0001 →
CHANGE OF NAME Recorded Jun 18, 2013
From: U.S. COATINGS IP CO., LLC
To: AXALTA COATING SYSTEMS IP CO., LLC
Reel/Frame 030639/0164 →
SECURITY AGREEMENT Recorded Mar 28, 2013
From: U.S. COATINGS IP CO. LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 030119/0163 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 13, 2013
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: U.S. COATINGS IP CO. LLC
Reel/Frame 029803/0826 →