Urethane resin, fixing member, and image forming apparatus
View Patent ↗A urethane resin that is formed by polymerizing an acrylic resin including a hydroxyl group and an isocyanate is provided. The urethane resin has a Martens hardness of 1 N/mm 2 or more and 200 N/mm 2 or less at 150° C. and a recovery rate of 80% or more and 100% or less at 150° C.
1. A urethane resin that is formed by polymerizing
(a) an acrylic resin in which a ratio [A]/([A]+[B]) is from 80% to 100%, where [A] represents a molar content of hydroxyl groups of side chains having less than 10 carbon atoms and [B] represents a molar content of hydroxyl groups of side chains having 10 or more carbon atoms; and a hydroxyl value is from about 70 mg KOH/g to about 400 mg KOH/g;
(b) at least one silicone selected from compounds represented by a general formula (1) below
where R 1 represents an amino group, a hydroxyl group, a methoxy group, or an ethoxy group; R 2 represents a methyl group, a phenyl group, or an ethyl group; and n is from 3 to 1,000; and
(c) an isocyanate,
wherein the urethane resin has a Martens hardness of from 1 N/mm 2 to 200 N/mm 2 at 150° C. and a recovery rate of from 80% to 100% at 150° C.
2. The urethane resin according to claim 1 , wherein a mass percentage of a monomer having a silicone chain (Si—O) with respect to entire monomers used for the polymerization is from about 1 mass % to about 50 mass %.
3. The urethane resin according to claim 2 , further comprising a fluorine atom.
4. The urethane resin according to claim 3 , wherein the (a) acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobomyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobomyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
5. The urethane resin according to claim 2 , wherein the (a) acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobornyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobomyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
6. The urethane resin according to claim 1 , further comprising a fluorine atom.
7. The urethane resin according to claim 6 , wherein the (a) acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobornyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobornyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
8. The urethane resin according to claim 1 , wherein the (a) acrylic resin is prepared by polymerizing, as monomers, at least one selected from the croup consisting of isobomyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobornyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
9. A urethane resin that is formed by polymerizing
(a′) at least one acrylic resin selected from compounds represented by a general formula (2) below in which a ratio [A]/([A]+[B]) is from 80% to 100%, where [A] represents a molar content of hydroxyl groups of side chains having less than 10 carbon atoms and [B] represents a molar content of hydroxyl groups of side chains having 10 or more carbon atoms; and a hydroxyl value is from about 70 mg KOH/g to about 400 mg KOH/g,
where R 1 represents an amino group, a hydroxyl group, a methoxy group, or an ethoxy group; R 2 represents a methyl group, a phenyl group, or an ethyl group; and n is from 3 to 1,000; and
(b) an isocyanate,
wherein the urethane resin has a Martens hardness of from 1 N/mm 2 to 200 N/mm 2 at 150° C. and a recovery rate of from 80% to 100% at 150° C.
10. The urethane resin according to claim 9 , wherein a mass percentage of a monomer having a silicone chain (Si—O) with respect to entire monomers used for the polymerization is from about 1 mass % to about 50 mass %.
11. The urethane resin according to claim 10 , further comprising a fluorine atom.
12. The urethane resin according to claim 11 , wherein the (a′) at least one acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobornyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobornyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
13. The urethane resin according to claim 10 , wherein the (a′) at least one acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobomyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobornyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
14. The urethane resin according to claim 9 , further comprising a fluorine atom.
15. The urethane resin according to claim 14 , wherein the (a′) at least one acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobornyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobornyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
16. The urethane resin according to claim 9 , wherein the (a′) at least one acrylic resin is prepared by polymerizing, as monomers, at least one selected from the group consisting of isobornyl (meth)acrylate, dicyclopentadiene (meth)acrylate, isobornyl oxyethyl (meth)acrylate, dicyclopentenyl (meth)acrylate, and cyclohexyl (meth)acrylate.
17. A fixing member for an image forming apparatus, the fixing member being formed by polymerizing
(a′) at least one acrylic resin selected from compounds represented by a general formula (2) below in which a ratio [A]/([A]+[B]) is from 80% to 100%, where [A] represents a molar content of hydroxyl groups of side chains having less than 10 carbon atoms and [B] represents a molar content of hydroxyl groups of side chains having 10 or more carbon atoms: and a hydroxyl value is from about 70 mg KOH/g to about 400 mg KOH/g,
where R 1 represents an amino group, a hydroxyl group. a methoxy group, or an ethoxy group; R 2 represents a methyl group. aphenyl group, or an ethyl group; and n is from 3 to 1,000; and
(b) an isocyanate,
wherein the fixing member has a Martens hardness of from 1 N/mm 2 to 200 N/mm 2 at 150° C. and a recovery rate of from 80% to 100% at 150° C.
18. An image forming apparatus comprising the fixing member according to claim 17 .