Composition for building protection applications based on alkylalkoxy-siloxanes having improved water repellency properties
View Patent ↗The present invention relates to a composition for imparting water repellency to porous mineral substrates and for producing a water repellency effect on the surface of the substrate and to a process for the preparation of such a composition, said composition being based on at least one silane oligomer, at least one hydrolysis or condensation catalyst, at least one fluorine-containing polymer, optionally water and/or at least one organic solvent, optionally at least one emulsifier and optionally further auxiliaries.
1. A composition, comprising:
(a) a silane oligomer, comprising an alkylalkoxysiloxane of idealized formula (I)
wherein
n is a number from 1 to 40,
R independently of one another, is a C 1 -C 18 -alkyl group,
R 1 are, independently of one another, a hydrogen atom or an alkyl radical comprising 1 to 6 carbon atoms;
(b) a hydrolysis or condensation catalyst;
(c) a fluorine-comprising polymer; and
(e) at least one emulsifier selected from the group consisting of
an alkyl sulfate comprising a C 8 -C 18 -alkyl,
an alkyl ether sulfate comprising a C 8 -C 18 -alkyl in the hydrophobic radical and 1 to 40 ethylene oxide (EO) or propylene oxide (PO) units,
an alkaryl ether sulfate comprising a C 8 -C 18 -alkyl in the hydrophobic radical and 1 to 40 ethylene oxide (EO) or propylene oxide (PO) units,
an alkyl sulfonate comprising a C 8 -C 18 -alkyl,
an alkaryl sulfonate comprising a C 8 -C 18 -alkyl,
a monoester of sulfosuccinic acid with a monohydric alcohol comprising 5 to 15 carbon atoms,
a monoester of sulfosuccinic acid with a monohydric alkylphenol comprising 5 to 15 carbon atoms,
an alkali metal salt of a carboxylic acid comprising 8 to 20 carbon atoms in the alkyl, aryl, alkaryl, or aralkyl radical,
an ammonium salt of a carboxylic acid comprising 8 to 20 carbon atoms in the alkyl, aryl, alkaryl, or aralkyl radical,
an alkyl phosphate comprising 8 to 20 carbon atoms in the organic radical,
an alkaryl phosphate comprising 8 to 20 carbon atoms in the organic radical,
an alkyl ether phosphate comprising 8 to 20 carbon atoms in the alkyl radical and 1 to 40 EO units,
an alkaryl ether phosphate comprising 8 to 20 carbon atoms in the alkaryl radical and 1 to 40 EO units,
an alkylpolyglycol ether comprising 8 to 40 EO units and C 8 -C 20 -carbon atoms in the alkyl radicals,
an alkarylpolyglycol ether comprising 8 to 40 EO units and C 8 -C 20 -carbon atoms in the alkyl or aryl radicals,
an ethylene oxide/propylene oxide (EO/PO) block copolymer comprising 8 to 40 EO or PO units,
an adduct of an alkylamine comprising a C 8 -C 22 -alkyl radical with ethylene oxide or propylene oxide,
an alkylpolyglycoside comprising a linear or branched saturated or unsaturated C 8 -C 24 -alkyl radical and an oligoglycoside radical comprising 1 to 10 hexose or pentose units, and
a silicon-functional surfactant,
wherein the catalyst (b) comprises (b1) a salt of at least one selected from the group consisting of an element of the 1st main group of the periodic table of elements, an element of the 2nd main group of the periodic table of elements, an alcoholate, an amino alcohol, a carboxylic acid, and a mineral acid, or (b2) sodium methanolate, sodium ethanolate, 2-aminoethanol, 2-(N,N-dimethyl)aminoethanol, a titanate, or a zirconate, and
wherein an average molecular weight of the silane oligomer is ≦1200 g/mol.
2. The composition of claim 1 , wherein a content of the silane oligomer (a) is 1 to 98% by weight, based on the composition.
3. The composition of claim 1 , further comprising:
(d) at least one solvent or diluent selected from the group consisting of water,
an aliphatic hydrocarbon having a boiling point above room temperature,
an aromatic hydrocarbon having a boiling point above room temperature,
gasoline,
petroleum ether,
diesel,
kerosene,
toluene,
xylene,
an alcohol,
a polyol, and
a ketone.
4. The composition of claim 1 , wherein a content of the catalyst (b) is 0.1 to 3% by weight, based on an amount of the silane oligomer.
5. The composition of claim 1 , wherein the fluorine-comprising polymer (c) comprises at least one selected from the group consisting of a fluorine-comprising polymer, a fluorine-comprising copolymer, and a fluorine-comprising terpolymer,
wherein the fluorine-comprising polymer (c) comprises at least one CF 2 group or one CF 3 group.
6. The composition of claim 1 , wherein the fluorine-comprising polymer (c) comprises:
(c1) a fluorine-comprising polymer of formula (II)
wherein
X is C, P, or S,
R 2 is —H, —OH, —CH 3 , —C 2 H 4 , —CH═CH 2 , —C(—CH 3 )═CH 2 , >(CH—CH 2 ) q — or >(C(—CH 3 )CH 2 ) q — where q=2 to 200,
m is 1, 2, or 3,
n is 1 to 100, and
p is 0, 1, or 2,
with the precondition that m+p=2 if X═C or S, and m+p=3 if X═P, or
(c2) a fluorine-comprising polymer of formula (III)
wherein
R 3 is —H or —CH 3 ,
m is 1 to 200,
n is 0 to 200,
o is 1 to 100,
p is 1 to 100, and
q is 0 to 100.
7. The composition of claim 1 , wherein a content of the fluorine-comprising polymer is 0.5 to 6% by weight, based on the composition.
8. The composition of claim 1 , wherein a content of the emulsifier (e) is 0.01 to 5% by weight, based on a total weight of the composition.
9. The composition of claim 1 , further comprising:
(f) at least one auxiliary selected from the group consisting of an inorganic acid, an organic acid, a buffer substance, a fungicide, a bactericide, a algicide, a microbicide, an odorous substance, a corrosion inhibitor, a preservative, and a rheology auxiliary.
10. A process for preparing of the composition of claim 1 , comprising:
(i) initially introducing 5 to 70% by weight of a solvent;
(ii) stirring in the fluorine-comprising polymer;
(iii) adding remaining amount of solvent;
(iv) subsequently metering in a mixture of at least one silane oligomer and catalyst with stirring;
(v) adding an emulsifier and, optionally, an auxiliary; and
(vi) stirring further, emulsifying, or stirring further and emulsifying.
11. The composition of claim 3 , wherein the solvent or diluent (d) comprises a C 6 - to C 12 -alkane.
12. The composition of claim 1 , wherein the catalyst (b) comprises a salt of at least one selected from the group consisting of an element of the 1st main group of the periodic table of elements, an element of the 2nd main group of the periodic table of elements, an alcoholate, an amino alcohol, a carboxylic acid, and a mineral acid.
13. The composition of claim 1 , wherein the catalyst (b) is sodium methanolate or sodium ethanolate.
14. The composition of claim 1 , wherein the catalyst (b) is 2-aminoethanol or 2-(N,N-dimethyl)aminoethanol.
15. The composition of claim 1 , wherein the catalyst (b) is a titanate or a zirconate.
16. A method of repelling water, comprising:
treating a surface of a substrate with the composition of claim 1 , to obtain a treated substrate,
wherein when a water drop remains on the treated substrate surface for 10 minutes, it does not produce a wet spot.
17. The composition of claim 1 , wherein the catalyst (b) is a Zr or Ti tetraalcoholate.