Process for forming and devolatilizing brominated polybutadiene polymer particles
View Patent ↗Brominated butadiene polymers are recovered from solution and formed into particles by spraying the solution onto a heated, mechanically agitated bed of seed particles. The droplets contact the seed particles in the bed and form a polymer layer on the outside of the seed particles, thereby enlarging them. The solvent is removed from the droplets after they make contact with seed particles in the bed. The process allows for the simultaneous removal of solvent and formation of somewhat large particles. The process forms at most small amounts of agglomerates and fines.
1. A process for producing particles of a brominated butadiene polymer, comprising dispersing a solution of the brominated butadiene polymer to form droplets, and applying the droplets onto a mechanically agitated bed of seed particles heated to a temperature of 40 to 70° C. in a reaction vessel at a subatmospheric pressure, such that the droplets coat the surfaces of seed particles substantially without agglomerating individual particles and solvent volatilizes from the coated seed particles before the coated seed particles become contacted by successive droplets of the brominated butadiene solution that are subsequently introduced into the reaction vessel, to form substantially nonagglomerated product particles having a solid external layer of the brominated butadiene polymer, wherein the process is performed continuously and a stable population balance of particles is maintained in the reaction vessel.
2. The process of claim 1 wherein the volume of the product particles is about 2.9 to 1000 times that of the seed particles.
3. The process of claim 2 wherein the seed particles have a volume median particle diameter of from 50 microns to 3000 microns.
4. The process of claim 3 wherein the substantially nonagglomerated product particles have a volume median particle diameter of from 0.5 to 15 millimeters.
5. The process of claim 4 which is conducted in a horizontal plowshare reactor.
6. The process of claim 4 wherein the temperature of the bed of seed particles is below the highest glass transition temperature of the brominated butadiene polymer.
7. The process of claim 1 wherein the temperature of the bed of seed particles is below the highest glass transition temperature of the brominated butadiene polymer.