Modification of biomass for efficient conversion to fuels
View Patent ↗A process is disclosed for preparing biomass particles for thermolytic or enzymatic conversion whereby the biomass particles baying a moisture content of at least 20% are subjected to flash heating. The flash heating may be preceded by one or more adsorption/desorption cycles with water or steam. A swelling aid may be added during the adsorption part of an adsorption/desorption cycle.
1. A process for converting biomass, said process comprising:
(i) flash heating biomass particles having a moisture content of at least 20 wt. % to thereby provide modified biomass particles; and
(ii) subjecting said modified biomass particles to pyrolysis,
wherein said flash heating in step (i) comprises heating said biomass particles for less than 30 seconds, wherein said flash heating in step (i) comprises increasing the temperature from 90° C. or below to 110° C. or above, and wherein said flash heating in step (i) ruptures at least a portion of the ligno-cellulosic particle structure of said biomass particle.
2. The process of claim 1 ,
wherein step (i) is preceded by at least one absorption/desorption cycle wherein a liquid comprising water is absorbed into and desorbed from said biomass particles.
3. The process of claim 1 wherein the desorption part of the absorption/desorption cycle comprises squeezing water from the biomass particles in an extruder, centrifuge or a filter press.
4. The process of claim 1 wherein the moisture content of the biomass particles subjected to flash heating in step (i) is at least 30 wt. %.
5. The process of claim 1 wherein step (i) is preceded by contacting said biomass particles with water or steam.
6. The process of claim 1 wherein step (i) is preceded by mechanical treatment.
7. The process of claim 1 wherein step (i) is preceded by contacting the biomass particles with a swelling aid.
8. The process of claim 7 wherein the swelling aid is selected from the group consisting of water soluble bases, water soluble acids, water soluble salts, and mixtures thereof.
9. The process of claim 1 wherein the flash heating is carried out with radio frequency energy or microwave energy.
10. The process of claim 1 wherein the flash heating is followed by a pressure drop.
11. The process of claim 1 wherein the biomass particles are particles of a material selected from the group consisting of wood, grass, straw, bagasse, corn husks, citrus peels, algae, and mixtures thereof.
12. The process according to claim 1 , wherein said pyrolysis is fast pyrolysis carried out in the presence of a catalyst.
13. The process according to claim 1 , wherein said biomass particles comprise wood.