High melt flow propylene impact copolymer and method
View Patent ↗The present disclosure provides a polymerization process for the production of a high melt flow propylene impact copolymer. The process includes contacting an active propylene-based polymer having a melt flow rate greater than about 100 g/10 min with one or more olefins in a polymerization reactor to form the propylene impact copolymer with a melt flow rate greater than about 60 g/10 min. The production of the high melt flow propylene impact copolymer may occur in one or more polymerization reactors, utilizing standard hydrogen concentration, and no visbreaking.
1. A polymerization process comprising:
contacting propylene and optionally at least one other olefin with a catalyst composition in a first polymerization reactor under gas phase polymerization conditions, the catalyst composition comprising a procatalyst having a diether internal electron donor which is 9,9-bis(methoxymethyl)-9H-fluorene, a cocatalyst and a mixed external electron donor (M-EED) comprising a first selectivity control agent (SCA1) which is dicyclopentyldimethoxysilane and an activity limiting agent (ALA) which is isopropyl myristate;
forming, in the first polymerization reactor, an active propylene-based polymer having a melt flow rate greater than 100 g/10 min as measured in accordance with ASTM D1238-01 (230° C., 2.16 kg);
contacting the active propylene-based polymer with at least one olefin in a second reactor under polymerization conditions; and
forming a propylene impact copolymer having a melt flow rate greater than 60 g/10 min and an Izod impact strength of 9.85 kJ/m 2 .
2. The process of claim 1 comprising maintaining a H 2 /C 3 mole ratio of less than 0.3 in one or both reactors.
3. The process of claim 1 comprising maintaining a H 2 /C 3 mole ratio of less than 0.1 in the second polymerization reactor.
4. The process of claim 1 comprising introducing into the second reactor, a component selected from the group consisting of a mixed external electron donor (M-EED), a first selectivity control agent (SCA1), a second selectivity control agent (SCA2), an activity limiting agent (ALA), and combinations thereof.
5. The process of claim 1 comprising contacting the active propylene-based polymer with propylene and ethylene and forming a propylene impact copolymer having an Fc value from about 5 wt % to about 50 wt % and an Ec value from about 20 wt % to about 90 wt %.
6. The process of claim 1 comprising forming a propylene impact copolymer having a volatiles content of less than 65 μg/g as measured in accordance with VW standard PV3341.
7. The process of claim 1 comprising self-limiting the polymerization with the catalyst composition when the temperature is greater than 100° C. in a reactor selected from the group consisting of the first polymerization reactor, the second polymerization reactor, and combinations thereof.
8. A polymerization process comprising:
contacting, in a polymerization reactor under polymerization conditions, at least one olefin with an active propylene-based polymer having a melt flow rate greater than 100 g/10 min as measured in accordance with ASTM D-1238-01 (230° C., 2.16 kg) and a catalyst composition comprising a procatalyst having a diether internal electron donor which is 9,9-bis(methoxymethyl)-9H-fluorene and an activity limiting agent (ALA) which is isopropyl myristate; and
forming a propylene impact copolymer having a melt flow rate greater than 85 g/10 min, an Izod impact strength of 9.85 kJ/m 2 , and at least 5 ppm of the ALA.
9. The process of claim 8 comprising contacting the at least one olefin with the active propylene-based polymer in a gas phase polymerization reactor.
10. The process of claim 8 comprising maintaining a H 2 /C 3 mole ratio of less than 0.2.
11. The process of claim 8 wherein the active propylene-based polymer comprises a self-limiting catalyst composition, the process comprising self-limiting the polymerization when the temperature in the polymerization reactor is greater than 100° C.
12. The process of claim 8 comprising contacting propylene and ethylene with the active propylene-based polymer; and forming a propylene impact copolymer having an Fc value from about 5 wt % to about 50 wt % and an Ec value from about 20 wt % to about 90 wt %.
13. The process of claim 8 comprising forming a propylene impact copolymer having a volatiles content of less than 65 μg/g as measured in accordance with VW standard PV3341.
14. A propylene impact copolymer comprising:
a propylene-based polymer having a melt flow rate (MFR) greater than 100 g/10 min as measured in accordance with ASTM D-1238-01 (230° C., 2.16 kg);
a propylene/ethylene copolymer dispersed within the propylene-based polymer, and
the propylene impact copolymer having a melt flow rate greater than 60 g/10 min, an Fc value from about 5 wt % to about 50 wt %, an Ec value from about 20 wt % to about 90 wt %, an Izod impact strength of 9.85 kJ/m 2 and at least 5 ppm of an activity limiting agent (ALA) which is isopropyl myristate.
15. The propylene impact copolymer of claim 14 wherein the MFR of the propylene-based polymer is greater than 160 g/10 min and the MFR of the impact copolymer is greater than 85 g/10 min.
16. The propylene impact copolymer of claim 14 wherein the propylene-based polymer has a xylene solubles content less than 4%.
17. The propylene impact copolymer of claim 14 wherein the propylene-based polymer is uncracked.
18. The propylene impact copolymer of claim 14 comprising a volatiles content of less than 65 μg/g as measured in accordance with VW standard PV3341.
19. The propylene impact copolymer of claim 14 having a T mf greater than 170° C.