Liquid crystal composition and liquid crystal display device
View Patent ↗The invention is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced regarding at least two of the characteristics; and is to provide a AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth, wherein the liquid crystal composition has negative dielectric anisotropy and includes a two-ring compound having a large negative dielectric anisotropy and having at least three fluorines at the lateral positions as a first component, a specific two-ring or three-ring compound having a pyran ring as a second component, a specific compound having a small viscosity as a third component and a specific compound having a large negative dielectric anisotropy as a fourth component, and the liquid crystal display device contains this composition.
1. A liquid crystal composition that has negative dielectric anisotropy and includes at least one compound selected from the group of compounds represented by formula (1) as a first component and at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 1 and R 2 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkenyloxy having 2 to 11 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring A is independently
and at least one of the rings A is
X 1 , X 2 , X 3 and X 4 are independently hydrogen, fluorine or chlorine, and at least three of X 1 , X 2 , X 3 and X 4 are fluorine; Z 1 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; and k is 1, 2 or 3.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1) to formula (1-3):
wherein R 1 and R 2 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, alkenyloxy having 2 to 11 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
3. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1).
4. The liquid crystal composition according to claim 2 , wherein the first component is a mixture of at least one compound selected from the group of compounds represented by formula (1-1) and at least one compound selected from the group of compounds represented by formula (1-2).
5. The liquid crystal composition according to claim 1 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-7):
wherein R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
6. The liquid crystal composition according to claim 5 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-4) to formula (2-7).
7. The liquid crystal composition according to claim 1 , wherein the ratio of the first component is in the range of 5% by weight to 40% by weight and the ratio of the second component is in the range of 5% by weight to 60% by weight, based on the total weight of the liquid crystal composition.
8. The liquid crystal composition according to claim 1 , further including at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring B and the ring C are independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene or 3-fluoro-1,4-phenylene; Z 2 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; and m is 1, 2 or 3.
9. The liquid crystal composition according to claim 8 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to formula (3-11):
wherein R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
10. The liquid crystal composition according to claim 8 , wherein the ratio of the third component is in the range of 10% by weight to 80% by weight based on the total weight of the liquid crystal composition.
11. The liquid crystal composition according to claim 1 , further including at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 7 and R 8 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring D is independently 1,4-cyclohexylene or 1,4-phenylene; Z 3 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; X 5 and X 6 are independently fluorine or chlorine; and n is 1, 2 or 3.
12. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-1) to formula (4-9):
wherein R 7 and R 8 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
13. The liquid crystal composition according to claim 11 , wherein the ratio of the fourth component is in the range of 5% by weight to 40% by weight based on the total weight of the liquid crystal composition.
14. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is −2 or less.
15. A liquid crystal display device containing the liquid crystal composition according to claim 1 .
16. The liquid crystal display device according to claim 15 , wherein an operating mode of the liquid crystal display device is a VA mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display device is an active matrix mode.
17. The liquid crystal composition according to claim 8 , further including at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 7 and R 8 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring D is independently 1,4-cyclohexylene or 1,4-phenylene; Z 3 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; X 5 and X 6 are independently fluorine or chlorine; and n is 1, 2 or 3.
18. The liquid crystal composition according to claim 17 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-1) to formula (4-9):
wherein R 7 and R 8 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
19. The liquid crystal composition according to claim 17 , wherein the ratio of the fourth component is in the range of 5% by weight to 40% by weight based on the total weight of the liquid crystal composition.