IP Library Patent Application 13060812
Patent Application
App. No. 13/060,812

ELECTRODEPOSITABLE COMPOSITION

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Patent No.
US None
App. No.
13/060,812
Abstract

The present disclosure relates to a coating composition that can be applied to a conductive substrate via an anodic electrodeposition process, substrates coated with the coating composition and a process for applying the coating to a substrate. The electrodepositable coating composition is an aqueous dispersion comprising of an at least partially neutralized copolymer comprising α-olefin and unsaturated carboxylic acid and a curing agent. After a layer of the coating composition has been applied to the substrate, it can be heated to cure the coating and form a crosslinked network that provides a durable chip and corrosion resistant finish.

Claims (30)

1 . An electrodepositable composition which is an aqueous dispersion comprising a film forming binder wherein the film forming binder consists essentially of:

i) an at least partially neutralized copolymer of an α-olefin and unsaturated carboxylic acid, which is the reaction product of a neutralizing agent with a copolymer of an α-olefin and unsaturated carboxylic acid; and

ii) a curing agent.

2 . The electrodepositable composition of claim 1 wherein the copolymer is neutralized with a neutralizing agent selected from the group consisting of an inorganic base, an organic base and a combination thereof.

3 . The electrodepositable composition of claim 1 wherein the neutralizing agent is N(R2)3, wherein each R2 is independently selected from the group consisting of H, CH3, CH2CH3, CH2CH2CH3, CH(CH3)2, CH2OH, CH2CH2OH, CH2CH2CH2OH, CH2CH(OH)CH3, CH(CH3)CH2OH and CH(OH)CH2CH3.

4 . The electrodepositable composition of claim 1 wherein the curing agent is a peroxide.

5 . The electrodepositable composition of claim 4 wherein the curing agent is a metal peroxide.

6 . The electrodepositable composition of claim 5 wherein the curing agent is zinc peroxide.

7 . The electrodepositable composition of claim 1 wherein: (a) the unsaturated carboxylic acid monomer is incorporated into the copolymer such that from 5 to 25 percent of the copolymer, by weight, is derived from the weight unsaturated carboxylic acid monomer; and (b) the copolymer has a melt index of 10 to 1000 prior to being neutralized.

8 . The electrodepositable composition of claim 1 wherein the neutralizing agent is present in an amount that is theoretically capable of neutralizing in the range of from 30 to 150 percent of the carboxylic acid groups of the copolymer comprising α-olefin and unsaturated carboxylic acid.

9 . An electrodepositable aqueous dispersion comprising a film-forming binder wherein the film forming binder consists essentially of:

i) an at least partially neutralized copolymer comprising α-olefin and unsaturated carboxylic acid; and

ii) zinc peroxide; and

wherein the neutralizing agent for the copolymer comprising α-olefin and unsaturated carboxylic acid is selected from the group consisting of ethanolamine, N-methylethanolamine, N-ethylethanolamine, N,N-dimethylethanolamine, dimethylamine, diethylamine, diisopropylamine, dipropylamine, trimethylamine, triethylamine and a combination thereof.

10 . A substrate coated with a layer of an electrodepositable coating composition wherein the electrodepositable coating composition is an aqueous dispersion comprising a film forming binder wherein the film forming binder consists essentially of:

i) an at least partially neutralized copolymer comprising α-olefin and unsaturated carboxylic acid; and

ii) a curing agent.

11 . A substrate coated with a dried and cured layer of an electrodepositable coating composition wherein the electrodepositable coating composition is an aqueous dispersion comprising a film forming binder wherein the film forming binder consists essentially of:

i) an at least partially neutralized copolymer comprising α-olefin and unsaturated carboxylic acid; and

ii) a curing agent.

12 - 18 . (canceled)

19 . A process of producing a layer of a coating composition on a substrate said process comprising the steps of;

A) providing a bath of an anodic electrodepositable coating composition wherein the electrodepositable coating composition is an aqueous dispersion comprising a film forming binder wherein the film forming binder consists essentially of:

i) an at least partially neutralized copolymer comprising α-olefin and unsaturated carboxylic acid; and

ii) a curing agent;

B) immersing the substrate in said anodic electrodepositable coating composition;

C) applying a voltage between a cathode and said substrate, which serves as a anode,

D) removing the substrate from the bath; and

E) heating the applied layer of electrodeposited coating composition.

20 - 27 . (canceled)

Assignments (6)
RELEASE OF SECURITY INTEREST Recorded Sep 29, 2016
From: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
To: AXALTA COATING SYSTEMS IP CO. LLC (FORMERLY KNOWN AS U.S. COATINGS IP CO. LLC)
Reel/Frame 040184/0192 →
SECURITY AGREEMENT Recorded Nov 19, 2013
From: U.S. COATINGS IP CO. LLC (N/K/A AXALTA COATING SYSTEMS IP CO. LLC)
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 031668/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2013
From: GAM, ALLISA
To: E. I. DU PONT DE NEMOURS AND COMPANY
Reel/Frame 030843/0608 →
CHANGE OF NAME Recorded Jun 18, 2013
From: U.S. COATINGS IP CO., LLC
To: AXALTA COATING SYSTEMS IP CO., LLC
Reel/Frame 030639/0164 →
SECURITY AGREEMENT Recorded Mar 28, 2013
From: U.S. COATINGS IP CO. LLC
To: BARCLAYS BANK PLC, AS COLLATERAL AGENT
Reel/Frame 030119/0163 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 13, 2013
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: U.S. COATINGS IP CO. LLC
Reel/Frame 029803/0826 →