Liquid crystal composition and liquid crystal display device
View Patent ↗Disclosed is a liquid crystal composition that can satisfy at least one of properties such as a high upper limit temperature of a nematic phase, a low lower limit temperature of a nematic phase, a low viscosity, a proper optical anisotropy, a negatively high dielectric anisotropy, a high specific resistance, a high stability against ultraviolet light, and a high stability against heat, or has a proper balance between at least two of the above properties. The liquid crystal composition comprises a first component of a dicyclic compound which has a negatively high dielectric anisotropy and contains fluorines at least three of lateral positions, a second component of a specific compound having a low viscosity, and a third component of a specific compound having a negatively high dielectric anisotropy and contains a negatively dielectric anisotropy. The liquid crystal display element comprises the composition.
1. A liquid crystal composition that has negative dielectric anisotropy and includes at least one compound selected from the group of compounds represented by formula (1) as a first component and at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; X 1 , X 2 , X 3 and X 4 are independently hydrogen, fluorine or chlorine, and at least three of them are fluorine; the ring A and the ring B are independently 1,4-cyclohexylene, 1,4-phenylene or 3-fluoro-1,4-phenylene; Z 1 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; and m is 1, 2 or 3.
2. The liquid crystal composition according to claim 1 , that has negative dielectric anisotropy and includes at least one compound selected from the group of compounds represented by formula (1-1) as a first component and at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 1 and R 2 are independently alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; X 1 , X 2 , X 3 and X 4 are independently hydrogen, fluorine or chlorine, and at least three of them are fluorine; the ring A and the ring B are independently 1,4-cyclohexylene, 1,4-phenylene or 3-fluoro-1,4-phenylene; Z 1 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; m is 1, 2 or 3; and the ring B is 1,4-phenylene and Z 1 is a single bond when m is 1.
3. The liquid crystal composition according to claim 1 , that has negative dielectric anisotropy and includes at least one compound selected from the group of compounds represented by formula (1-1) as a first component and at least one compound selected from the group of compounds represented by formula (2-1) as a second component:
wherein R 1 and R 2 are independently alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; and X 1 , X 2 , X 3 and X 4 are independently hydrogen, fluorine or chlorine, and at least three of X 1 , X 2 , X 3 and X 4 are fluorine.
4. The liquid crystal composition according to claim 3 , wherein the ratio of the first component is in the range of 5% by weight to 50% by weight and the ratio of the second component is in the range of 10% by weight to 70% by weight, based on the total weight of the liquid crystal composition.
5. The liquid crystal composition according to claim 2 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1-1) to formula (1-1-3):
wherein R 1 and R 2 are independently alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
6. The liquid crystal composition according to claim 5 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1-1).
7. The liquid crystal composition according to claim 5 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1-2).
8. The liquid crystal composition according to claim 5 , wherein the first component is a mixture of at least one compound selected from the group of compounds represented by formula (1-1-1) and at least one compound selected from the group of compounds represented by formula (1-1-2).
9. The liquid crystal composition according to claim 1 , that has negative dielectric anisotropy and includes at least one compound selected from the group of compounds represented by formula (1-2) as a first component and at least one compound selected from the group of compounds represented by formula (2) as a second component:
wherein R 1 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 3 and R 4 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; X 1 , X 2 , X 3 and X 4 are independently hydrogen, fluorine or chlorine, and at least three of them are fluorine; the ring A and the ring B are independently 1,4-cyclohexylene, 1,4-phenylene or 3-fluoro-1,4-phenylene; Z 1 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; and m is 1, 2 or 3.
10. The liquid crystal composition according to claim 9 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-2-1) to formula (1-2-3):
wherein R 1 is alkyl having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; and R 4 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
11. The liquid crystal composition according to claim 10 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-2-1).
12. The liquid crystal composition according to claim 1 , wherein the second component is at least one compound selected from the group of compounds represented by formula (2-1) to formula (2-12):
wherein R 5 and R 6 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
13. The liquid crystal composition according to claim 12 , wherein the ratio of the second component is in the range of 10% by weight to 65% by weight based on the total weight of the liquid crystal composition.
14. The liquid crystal composition according to claim 1 , further including at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 7 and R 8 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; the ring C is independently 1,4-cyclohexylene or 1,4-phenylene; Z 2 is independently a single bond, ethylene, methyleneoxy or carbonyloxy; X 5 and X 6 are independently fluorine or chlorine; and n is 1, 2 or 3.
15. The liquid crystal composition according to claim 14 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1) to formula (3-9):
wherein R 7 and R 8 are independently alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
16. The liquid crystal composition according to claim 14 , wherein the ratio of the third component is in the range of 5% by weight to 50% by weight based on the total weight of the liquid crystal composition.
17. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nanometers is 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is −2 or less.
18. A liquid crystal display element containing the liquid crystal composition according to claim 1 .
19. The liquid crystal display element according to claim 18 , wherein an operating mode of the liquid crystal display element is a VA mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display element is an active matrix mode.