Process for producing a molding composition or a molding with an increase in the melt stiffness
View Patent ↗A polyamide molding composition is condensed up in the melt by means of a masterbatch containing a compound having at least two carbonate units and also a polyetheramide in which at least 50% of the end groups are present as amino end groups, whereupon the melt mixture is discharged and solidified to give a molding composition or a molding. The product obtained has an increased amino end group content and consequently an improved hydrolysis resistance.
1. A process for producing a molding composition or a molding, the process comprising:
a) mixing
(i) a polyamide molding composition, comprising a polyamide with at least 50% of its end groups being present as amino end groups and a proportion of the polyamide being from 10 to 99 parts by weight, and
(ii) a masterbatch comprising a compound having at least two carbonate units and also a polyetheramide, with a proportion of polyetheramide in the masterbatch being from 1 to 90 parts by weight, to obtain a mixture
wherein a sum of parts by weight of the polyamide and the polyetheramide is 100 and at least 50% of polyetheramide end groups are present as amino end groups;
b) optionally, storing, transporting, or storing and transporting the mixture;
c) mixing the mixture as a melt and introducing shear, to obtain a melt mixture; and
d) discharging the melt mixture, to obtain a discharged melt mixture, and
e) solidifying the discharged melt mixture, to obtain the molding composition or molding,
wherein the polyamide molding composition e) comprises 0.005 to 10% by weight, based on the polyamide, of the compound having at least two carbonate units.
2. The process of claim 1 , wherein
the polyamide molding composition e) further comprises from 0.1 to 90 parts by weight of the polyetheramide, where a sum of the parts by weight of the polyamide and the polyetheramide of the polyamide molding composition and the polyetheramide of the masterbatch is 100 and at least 50% of polyetheramide end groups are present as amino end groups.
3. The process of claim 1 , wherein
the molding composition or molding e) comprises from 10 to 99 parts by weight of the polyamide and from 1 to 90 parts by weight of the polyetheramide, and the sum of the parts by weight of the polyamide and polyetheramide is 100.
4. The process of claim 1 , wherein, in the case of a multicomponent molding, a component comprising the molding composition e) produced by the method of claim 1 comprises from 10 to 99 parts by weight of the polyamide and from 1 to 90 parts by weight of the polyetheramide, and the sum of the parts by weight of the polyamide and polyetheramide is 100.
5. The process of claim 1 , wherein the molding composition or molding e) comprises at least 50% by weight of the mixture of the polyamide and polyetheramide.
6. The process of claim 1 , wherein a polyetherdiamine present as comonomer in the polyetheramide has a weight average molar mass of from 200 to 5000 g/mol and its proportion in the polyetheramide is from 4 to 60% by weight.
7. The process of claim 1 , wherein a concentration of the compound having at least two carbonate units in the masterbatch is from 0.15 to 50% by weight.
8. A molding composition, produced by the process of claim 1 .
9. A molding produced, by the process of claim 1 .
10. The molding of claim 9 , in the form of a profile, a plate, or a film.
11. A molding of claim 9 , in the form of a liner, a gas pipe, a layer of an offshore pipeline, a layer of a subsea pipeline, a layer of a supply line, a refinery line, a hydraulic line, a line for at least one chemical, a cable conduit, a filling station supply line, a ventilation line, an air intake pipe, a tank filling port, a storage container, or a fuel tank.
12. The process of claim 2 , wherein the molding composition or molding e) comprises from 10 to 99 parts by weight of the polyamide and from 1 to 90 parts by weight of the polyetheramide, and the sum of the parts by weight of the polyamide and polyetheramide is 100.
13. The process of claim 2 , wherein, in the case of a multicomponent molding, a the component comprising the molding composition e) produced by the method of claim 2 comprises from 10 to 99 parts by weight of the polyamide and from 1 to 90 parts by weight of the polyetheramide, and the sum of the parts by weight of polyamide and polyetheramide is 100.
14. The process of claim 3 , wherein, in the case of a multicomponent molding, a the component comprising the molding composition e) produced by the method of claim 3 comprises from 10 to 99 parts by weight of the polyamide and from 1 to 90 parts by weight of the polyetheramide, and the sum of the parts by weight of polyamide and polyetheramide is 100.
15. The process of claim 2 , wherein the molding composition or molding e) comprises at least 50% by weight of the mixture of the polyamide and polyetheramide.
16. The process of claim 3 , wherein the molding composition or molding e) comprises at least 50% by weight of the mixture of the polyamide and polyetheramide.
17. The process of claim 4 , wherein the molding composition or molding e) comprises at least 50% by weight of the mixture of the polyamide and polyetheramide.
18. The process of claim 2 , wherein a polyetherdiamine present as comonomer in the polyetheramide has a weight average molar mass of from 200 to 5000 g/mol and its proportion in the polyetheramide is from 4 to 60% by weight.
19. The process of claim 3 , wherein a polyetherdiamine present as comonomer in the polyetheramide has a weight average molar mass of from 200 to 5000 g/mol and its proportion in the polyetheramide is from 4 to 60% by weight.
20. The process of claim 4 , wherein a polyetherdiamine present as comonomer in the polyetheramide has a weight average molar mass of from 200 to 5000 g/mol and its proportion in the polyetheramide is from 4 to 60% by weight.