Separator for lithium ion secondary battery, method for manufacture thereof, and lithium ion secondary battery
Disclosed are a separator for lithium ion secondary batteries, having an inorganic layer formed from inorganic particles, characterized in that the inorganic particles have a particle diameter distribution in which the 50% cumulative particle diameter D 50 is in the range of 100 nm to 500 nm, the 10% cumulative particle diameter D 10 is 0.5D 50 or more, and the 90% cumulative particle diameter D 90 is 2D 50 or less; a method for manufacturing the separator; and a lithium ion secondary battery using the separator. When the separator is used, there can be produced a lithium ion secondary battery in which a short circuit caused by contraction or melting can be definitely prevented, as well as the current density applied to the electrodes during charging and discharging is uniform so that charging and discharging can be efficiently achieved.
1. A separator for lithium ion secondary batteries, comprising an inorganic layer formed from inorganic particles, and a porous base material consisting essentially of an organic resin and selected from a woven fabric, a knitted fabric, and a non-woven fabric, wherein the inorganic particles have a particle diameter distribution in which the 50% cumulative particle diameter D 50 is in the range of 100 nm to 500 nm, the 10% cumulative particle diameter D 10 is 0.5D 50 or more, and the 90% cumulative particle diameter D 90 is 2D 50 or less, and wherein the inorganic layer is formed on the porous base material.
2. The separator for lithium ion secondary batteries according to claim 1 , wherein inorganic particles are present also in the voids of the porous base material.
3. A method for manufacturing the separator for lithium ion secondary batteries of claim 1 , the method comprising:
applying, on a porous base material consisting essentially of an organic resin and selected from a woven fabric, a knitted fabric, and a non-woven fabric, a dispersion liquid containing inorganic particles having a particle diameter distribution in which the 50% cumulative particle diameter D 50 is in the range of 100 nm to 500 nm, the 10% cumulative particle diameter D 10 is 0.5D 50 or more, and the 90% cumulative particle diameter D 90 is 2D 50 or less;
drying the dispersion liquid; and
thereby forming an inorganic layer formed from inorganic particles on the porous base material,
wherein a dispersion medium having a surface contractile force, which acts on the inorganic layer formed from inorganic particles during drying, of 20 kg/cm 2 or more is used.
4. A lithium ion secondary battery using the separator for lithium ion secondary batteries according to claim 1 .
5. A lithium ion secondary battery using the separator for lithium ion secondary batteries according to claim 2 .
6. The separator for lithium ion secondary batteries according to claim 1 , having a peak of pore diameters in the range of 0.04 μm to 0.08 μm.
7. The method according to claim 3 , said separator for lithium ion secondary batteries having a peak of pore diameters in the range of 0.04 μm to 0.08 μm.
8. A method for manufacturing a separator for lithium ion secondary batteries, the method comprising:
applying, on a porous base material consisting essentially of an organic resin and selected from a woven fabric, a knitted fabric, or a non-woven fabric, a dispersion liquid containing inorganic particles having a particle diameter distribution in which the 50% cumulative particle diameter D 50 is in the range of 100 nm to 500 nm, the 10% cumulative particle diameter D 10 is 0.5D 50 or more, and the 90% cumulative particle diameter D 90 is 2D 50 or less;
drying the dispersion liquid; and
thereby forming an inorganic layer formed from inorganic particles on the porous base material.
9. The separator for lithium ion secondary batteries according to claim 1 , wherein the 10% cumulative particle diameter D 10 is between 0.5D 50 and D 50 (including 0.5D 50 and excluding D 50 )”, and the 90% cumulative particle diameter D 90 is between D 50 and 2D 50 (excluding D 50 and including 2D 50 ).
10. The method according to claim 3 , wherein the 10% cumulative particle diameter D 10 is between 0.5D 50 and D 50 (including 0.5D 50 and excluding D 50 )”, and the 90% cumulative particle diameter D 90 is between D 50 and 2D 50 (excluding D 50 and including 2D 50 ).