Additive for performance enhancement of biopolymer articles
View Patent ↗Embodiments relate to an additive for a biopolymer article, a method for forming the additive and biopolymer articles and sheeting containing or formed using the additive. The additive includes at least one impact modifier between 10-90 weight % of the total weight of the additive; at least one polymer color concentrate between 5-50 weight % of the total weight of the additive; and at least one carrier resin between 5-50 weight % of the total weight of the additive.
1. A biopolymer composition comprising:
a polylactic acid resin present in an amount between 75 and 92 weight percent of the total weight of the composition,
an additive present in an amount between 8 and 25 weight percent of the total weight of the composition, the additive comprising:
an ethylene-butyl acrylate-glycidyl methacrylate terpolymer impact modifier present in an amount between 50 and 67 weight percent of the total weight of the additive; and
a carrier resin present in an amount between 33 and 50 weight percent of the total weight of the additive,
wherein the carrier resin is an aliphatic-aromatic polyester polymer formed from the polymerization of adipic acid, terephthalic acid, and 1,4-butanediol monomers, and the weight ratio of the ethylene-butyl acrylate-glycidyl methacrylate terpolymer impact modifier to the carrier resin is in a range of from 1:1 to 2:1.
2. The biopolymer composition of claim 1 , further comprising TiO 2 .
3. The biopolymer composition of claim 1 , wherein the carrier resin is present in an amount of 33 weight percent of the total weight of the additive, and the impact modifier is present in an amount of 67 weight percent of the total weight of the additive.
4. A biopolymer article formed from a biopolymer resin comprising:
a polylactic acid resin present in an amount between 75 and 92 weight percent of the total weight of the biopolymer article; and
an additive pellet added to the biopolymer resin such that the additive is present in an amount between 8 and 25 weight percent of the total weight of the biopolymer article, the additive pellet comprising a mixture of:
an ethylene-butyl acrylate-glycidyl methacrylate terpolymer impact modifier in an amount between 50 and 67 weight percent of the total weight of the additive pellet;
a carrier resin present in an amount between 33 and 50 weight percent of the total weight of the additive pellet,
wherein the carrier resin is an aliphatic-aromatic polyester polymer formed from the polymerization of adipic acid, terephthalic acid, and 1,4-butanediol monomers, wherein the carrier resin is compatible with the polylactic acid resin, and the weight ratio of the ethylene-butyl acrylate-glycidyl methacrylate terpolymer impact modifier to the carrier resin is in a range from 1:1 to 2:1, whereby the biopolymer article has a thickness between about 10 mils and about 80 mils, a depth and a width.
5. The biopolymer article of claim 4 , having a Gardner impact resistance value of about 17 in-lbs at 30 mil thickness.
6. The biopolymer article of claim 4 , further comprising TiO 2 .
7. The biopolymer article of claim 4 , having a depth to width ratio of 10:1 to 1:4.
8. The biopolymer article of claim 4 , having a depth to width ratio of 10:1 to 2.1.
9. The biopolymer article of claim 4 , having a depth to width ratio of 8:1 to 4:1.
10. The biopolymer article of claim 4 , having a depth to width ratio of 2:1 to 1:4.
11. The biopolymer article of claim 4 , which has been thermoformed into a multi-compartment breakaway cup; the cup having a depth to width ratio of 10:1 to 2:1; the multi-compartments being scored for separation into individual compartments.
12. A biopolymer extruded sheeting comprising:
a polylactic acid resin in an amount between 75 and 92 weight percent of the total weight of the extruded sheeting; and
an additive pellet added to the polylactic acid resin such that the additive pellet is present in an amount between 8 and 25 weight percent of the total weight of the extruded sheeting; the additive pellet containing a mixture of:
an ethylene-butyl acrylate-glycidyl methacrylate terpolymer impact modifier present in amount between 50 and 67 weight percent of the total weight of the additive pellet; and
a carrier resin present in an amount between 33 and 50 weight percent of the total weight of the additive pellet,
wherein the carrier resin is an aliphatic-aromatic polyester polymer formed from the polymerization of adipic acid, terephthalic acid, and 1,4-butanediol monomers, and
wherein the weight ratio of the ethylene-butyl acrylate-glycidyl methacrylate terpolymer impact modifier to the carrier resin is in a range from 1:1 to 2:1, whereby the biopolymer extruded sheeting has a thickness between about 10 mils and about 80 mils.
13. The biopolymer extruded sheeting of claim 12 , having a Gardner Impact value of about 17 in-lbs at 30 mils thickness.
14. The biopolymer extruded sheeting of claim 12 , further comprising TiO 2 .
15. The biopolymer extruded sheeting of claim 12 , wherein the carrier resin is present in an amount of 33 weight percent of the total weight of the additive, and the impact modifier is present in an amount of 67 weight percent of the total weight of the additive.