IP Library Granted Patent US 8,597,374
Granted Patent B2
US 8,597,374 · App. 13/079,479 · Granted Dec 3, 2013

Compositions for spray dyeing of cellulosic fabrics

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Quick Facts
Patent No.
US 8,597,374
App. No.
13/079,479
Granted
Dec 3, 2013
Kind
B2
Abstract

Compositions are provided for spray dyeing of a cellulosic, such as cotton, fabric or garment. The compositions include a reactive dye, a wetter, an alkali, and water. The present compositions are made by first mixing the reactive dye, the wetter, and the water to form a solution, and thereafter adding the alkali to the solution.

Claims (8)

1. A method of making a composition for spray application onto surfaces of a cotton fabric, consisting of: mixing together a reactive dye, a wetter, and water to form a solution, the wetter being selected from the group consisting of a first surfactant, wherein the first surfactant is a blend of sulfuric acid disodium salt and phosphoric acid trisodium salt, and a second surfactant, wherein the second surfactant is sodium dioctyle sulfosuccinate; and adding an alkali to the solution to complete the composition at a time that allows spray application of the solution onto the surfaces of a cotton fabric before the dye hydrolyzes, the alkali being selected from the group consisting of a first combination of soda ash, potassium carbonate and phosphate, and a second combination of sodium silicate and a caustic.

2. The method of claim 1 , wherein the wetter, the reactive dye, and the alkali are anionic or non-ionic.

3. The method of claim 1 , wherein the wetter comprises an amount between 5 g/l and 40 g/l.

4. The method of claim 1 , wherein the reactive dye is an azo metal complex or dioxazine.

5. The method of claim 4 , wherein the reactive dye comprises an amount between 10 g/l and 80 g/l.

6. The method of claim 1 , wherein the alkali comprises an amount between 3 g/l and 20 g/l.

7. The method of claim 6 , wherein the alkali has a pH between 10.0 and 11.0.

8. A method of making a composition for spray application onto surfaces of a cotton fabric consisting of: mixing together a reactive dye, a wetter, water and at least one of a chelator, a dye leveling agent, a defoamer, and an anti-reducing agent, to form a solution, the wetter being selected from the group consisting of a first surfactant, wherein the first surfactant is a blend of sulfuric acid disodium salt and phosphoric acid trisodium salt, and a second surfactant, wherein the second surfactant is sodium dioctyle sulfosuccinate; and adding an alkali to the solution to complete the composition at a time that allows spray application of the solution onto the surfaces of a cotton fabric before the dye hydrolyzes, the alkali being selected from the group consisting of a first combination of soda ash, potassium carbonate and phosphate, and a second combination of sodium silicate and a caustic.

Assignments (5)
RELEASE OF PATENT SECURITY INTEREST RECORDED AT R/F 45029/0132 Recorded Dec 15, 2025
From: JPMORGAN CHASE BANK, N.A.
To: MAIDENFORM LLC; HBI BRANDED APPAREL ENTERPRISES, LLC
Reel/Frame 074166/0114 →
RELEASE OF PATENT SECURITY INTEREST RECORDED AT R/F 59910/0685 Recorded Dec 15, 2025
From: JPMORGAN CHASE BANK, N.A.
To: MAIDENFORM LLC; HBI BRANDED APPAREL ENTERPRISES, LLC
Reel/Frame 074165/0634 →
FOURTH AMENDED AND RESTATED PATENT SECURITY AGREEMENT Recorded May 9, 2022
From: HANESBRANDS INC.; ALTERNATIVE APPAREL, INC.; BA INTERNATIONAL, L.L.C.; CC PRODUCTS LLC; CEIBENA DEL, INC.; EVENT 1 LLC; GEARCO LLC; GFSI HOLDINGS LLC; GFSI LLC; GTM RETAIL, INC.; HANES GLOBAL HOLDINGS U.S. INC.; HANES JIBOA HOLDINGS, LLC; HANES MENSWEAR, LLC; HANESBRANDS DIRECT, LLC; HANESBRANDS EXPORT CANADA LLC; HBI BRANDED APPAREL ENTERPRISES LLC; HBI INTERNATIONAL HOLDINGS U.S., INC.; HBI SOURCING, LLC; INNER SELF LLC; IT'S GREEK TO ME, INC.; KNIGHTS APPAREL, LLC; KNIGHTS HOLDCO, LLC; MAIDENFORM (BANGLADESH) LLC; MAIDENFORM (INDONESIA) LLC; MAIDENFORM BRANDS LLC; MAIDENFORM INTERNATIONAL LLC; MAIDENFORM LLC; MF RETAIL LLC; PLAYTEX DORADO, LLC; PLAYTEX INDUSTRIES, INC.; SEAMLESS TEXTILES LLC
To: JPMORGAN CHASE BANK, N.A.
Reel/Frame 059910/0685 →
SECURITY INTEREST Recorded Jan 9, 2018
From: HBI BRANDED APPAREL ENTERPRISES, LLC; IT'S GREEK TO ME, INC.; MAIDENFORM LLC
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 045029/0132 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 5, 2011
From: MAY, RUTH E
To: HBI BRANDED APPAREL ENTERPRISES, LLC
Reel/Frame 026075/0149 →