Rapid curing water resistant composition for grouts, fillers and thick coatings
View Patent ↗A premixed composition is formed from modified polyacrylate polymer, silicone emulsion, one or more amine compounds, and silane, that cures rapidly to form a composition that can be used as a grout or coating. The premixed composition includes a latex resin including an acrylic-based polymer, a silicone emulsion, one or more amine compounds, and a silane, and optionally various fillers, pigments, and adjuvants. These components in the proper proportions form a stable viscous suspension that can be floated into tile joints, and cleaned from an adjacent tile surface. The composition rapidly cures to form a hard mass that is resistant to abrasion, in both dry and wet conditions, is color consistent, and is resistant to staining.
1. A premixed composition suitable for use as a grout or coating, comprising:
a latex resin having a glass transition temperature (Tg) above 25° C.;
a silicone emulsion;
a silane;
one or more amine compounds; and
sand, wherein said composition is greater than 95% cleaned from a tile following application to or near the tile after 10 minutes drying time by less than 5 cycles of a brush abrasion machine.
2. The premixed composition of claim 1 , wherein said one or more amine compounds have 3-5 carbon atoms per amine group.
3. The premixed composition of claim 2 , wherein said one or more amine compounds comprises alkanolamine.
4. The premixed composition of claim 2 , wherein said one or more amine compounds comprises a primary amine having a primary amine group attached to a secondary or tertiary carbon atom.
5. The premixed composition of claim 1 , wherein said one or more amine compounds are 1 wt. %-10 wt. % of dry latex resin weight.
6. The premixed composition of claim 1 , wherein said latex resin comprises a polymer obtained by co-polymerization of one or more of (i) styrene and (ii) an acrylate monomer, together with another copolymerizable monomer.
7. The premixed composition of claim 6 , wherein said latex resin comprises a copolymer of styrene, said copolymer having up to 70 percent styrene by weight.
8. The premixed composition of claim 6 , wherein said latex resin comprises said acrylate monomer and said acrylate monomer is butylacrylate.
9. A premixed composition suitable for use as a grout or coating, comprising:
a latex resin having a glass transition temperature (Tg) above 25° C.;
a silicone emulsion;
a silane;
one or more amine compounds; and
sand, wherein said one or more amine compounds are selected from the group consisting of 2-Amino-2-Methyl-1-Propanol, 1-Amino-2-Propanol, 2-Amino-1-Propanol, Cyclopentylamine, 2-Amino-3-Methyl-Butanol, and combinations thereof.
10. A premixed composition suitable for use as a grout or coating, comprising:
a latex resin having a glass transition temperature (Tg) above 25° C.;
a silicone emulsion;
a silane;
one or more amine compounds; and
sand, wherein said silicone emulsion comprises 30 to 60 percent by weight of polymethylethoxy siloxane.
11. A premixed composition suitable for use as a grout or coating, comprising:
a latex resin having a glass transition temperature (Tg) above 25° C.;
a silicone emulsion;
a silane;
one or more amine compounds; and
sand, wherein said silane comprises alkylalkoxy silane.
12. A premixed composition suitable for use as a grout or coating, comprising:
a latex resin having a glass transition temperature (Tg) above 25° C.;
a silicone emulsion;
a silane;
one or more amine compounds; and
sand, wherein said premixed composition has:
a Shore D hardness of at least 20 after a one-day dry cure, and
a Shore D hardness of at least 18 after being subjected to immersion in water for one day following a one-day dry cure; and
a Shore D hardness of at least 40 after a three-day dry cure, and
a Shore D hardness of at least 35 after being subjected to immersion in water for one day following a three-day dry cure; and
a Shore D hardness of at least 60 after a seven-day dry cure, and
a Shore D hardness of at least 50 after being subjected to immersion in water for one day following a seven-day dry cure.
13. A method of grouting tile, comprising the steps of:
providing a premixed composition, comprising:
a) a latex resin having a glass transition temperature (Tg) above 25° C.,
b) a silicone emulsion,
c) a silane,
d) one or more amine compounds, and
e) sand;
applying the premixed composition in spaces between a plurality of tiles installed on a substrate surface; and
allowing the premixed composition to dry to cure, wherein said composition is greater than 95% cleaned from tile following application to the tile after 10 minutes drying time by less than 5 cycles of a brush abrasion machine.
14. The method of claim 13 , wherein said one or more amine compounds have 3-5 carbon atoms per amine group.
15. The method of claim 14 , wherein said one or more amine compounds comprises alkanolamine.
16. A method of grouting tile, comprising the steps of:
providing a premixed composition, comprising:
a) a latex resin having a glass transition temperature (Tg) above 25° C.,
b) a silicone emulsion,
c) a silane,
d) one or more amine compounds, and
e) sand;
applying the premixed composition in spaces between a plurality of tiles installed on a substrate surface; and
allowing the premixed composition to dry to cure, wherein said one or more amine compounds have 3-5 carbon atoms per amine group, and wherein said one or more amine compounds comprises a primary amine having a primary amine group attached to a secondary or tertiary carbon atom.
17. The method of claim 13 , wherein said one or more amine compounds are 1 wt. %-10 wt. % of dry latex resin weight.
18. A method of grouting tile, comprising the steps of:
providing a premixed composition, comprising:
a) a latex resin having a glass transition temperature (Tg) above 25° C.,
b) a silicone emulsion,
c) a silane,
d) one or more amine compounds, and
e) sand;
applying the premixed composition in spaces between a plurality of tiles installed on a substrate surface; and
allowing the premixed composition to dry to cure, wherein said one or more amine compounds are selected from the group consisting of 2-Amino-2-Methyl-1-Propanol, 1-Amino-2-Propanol, 2-Amino-1-Propanol, Cyclopentylamine, 2-Amino -3-methyl-butanol, and combinations thereof.