Process for producing an oxide
View Patent ↗The present invention relates to a method for producing an oxide containing a conductive mayenite type compound and having an electron concentration of 1×10 18 /cm 3 or more, from a raw material which is a combination of a calcium compound and an aluminum compound or is a compound containing calcium and aluminum, each having a molar ratio of calcium oxide and aluminum oxide ranging from 9:10 to 14:5 in terms of the oxides, the method including the steps of: heating and holding the raw material at 900 to 1,300° C. to produce a calcined powder containing at least one oxide selected from the group consisting of a calcium aluminate, calcium oxide and aluminum oxide; and heating and holding the calcined powder at 1,200° C. to less than 1,415° C. under a reduction atmosphere in an inert gas atmosphere or a vacuum atmosphere each having an oxygen partial pressure of 1,000 Pa or less.
1. A method for producing an oxide containing a conductive mayenite compound and having an electron concentration of 1×10 18 /cm 3 or more, from a raw material which is a combination of a calcium compound and an aluminum compound or is a compound containing calcium and aluminum, each having a molar ratio of calcium oxide and aluminum oxide ranging from 9:10 to 14:5 in terms of the oxides, said method comprising the steps of:
heating and holding the raw material at 900 to 1,250° C. to produce a calcined powder containing at least one oxide selected from the group consisting of a calcium aluminate, calcium oxide and aluminum oxide; and
heating and holding the calcined powder at 1,270° C. to less than 1,415° C. under reducing conditions in an inert gas atmosphere or a vacuum each having an oxygen partial pressure of 1,000 Pa or less.
2. The method for producing an oxide according to claim 1 , wherein the calcium compound comprises at least one selected from the group consisting of calcium carbonate, calcium oxide and calcium hydroxide, and the aluminum compound comprises at least one member selected from the group consisting of aluminum hydroxide and aluminum oxide.
3. The method for producing an oxide according to claim 1 , wherein the reducing conditions are formed by at least one member selected from the group consisting of hermetically sealing a carbon crucible in which the calcined powder has been placed and a reducing agent.
4. The method for producing an oxide according to claim 3 , wherein the reducing agent is a carbon material.
5. The method for producing an oxide according to claim 4 , wherein the carbon material is at least one selected from the group consisting of a carbon allotrope, an acetylide compound, a covalently-bound metal carbide, an ionic metal carbide and a hydrocarbon compound.
6. The method for producing an oxide according to claim 1 , wherein the electron concentration of the oxide is 1×10 19 /cm 3 or more.