Granted Patent B2

US 8,603,721 · App. 13/081,090 · Granted Dec 10, 2013

Abstract

Claims (32)

1. A process for preparing toner particles which comprises:

(a) selecting a carbon black;

(b) measuring the surface level of sulfur of the carbon black by X-ray Photoelectron Spectroscopy to ensure that the surface level of sulfur is no more than about 0.05 atomic percent;

(c) mixing the carbon black with a resin to generate a toner composition; and

(d) forming toner particles from the toner composition.

2. A process according to claim 1 wherein the carbon black has an average particle diameter of from about 100 nm to about 300 nm.

3. A process according to claim 1 wherein the surface level of sulfur of the carbon black as measured by X-ray Photoelectron Spectroscopy is no more than about 0.04 atomic percent.

4. A process according to claim 1 wherein the surface level of sulfur of the carbon black as measured by X-ray Photoelectron Spectroscopy is no more than about 0.03 atomic percent.

5. A process according to claim 1 wherein the toner particles are prepared by an emulsion aggregation process.

6. A process for preparing toner particles which comprises:

(a) selecting a carbon black;

(b) measuring the surface level of sulfur of the carbon black by X-ray Photoelectron Spectroscopy to ensure that the surface level of sulfur is no more than about 0.05 atomic percent;

(c) generating polyester latex particles by melt mixing a polyester resin in the absence of an organic solvent, optionally adding a surfactant to the resin, and adding to the resin a basic agent and water to form an emulsion of resin particles;

(d) mixing the carbon black with the polyester latex particles by an emulsion aggregation process to generate a toner composition; and

(e) forming toner particles from the toner composition.

7. A process according to claim 6 wherein the carbon black has an average particle diameter of from about 100 nm to about 300 nm.

8. A process according to claim 6 wherein the surface level of sulfur of the carbon black as measured by X-ray Photoelectron Spectroscopy is no more than about 0.04 atomic percent.

9. A process according to claim 6 wherein the surface level of sulfur of the carbon black as measured by X-ray Photoelectron Spectroscopy is no more than about 0.03 atomic percent.

10. A process according to claim 6 wherein a surfactant is added to the resin.

11. A process according to claim 6 wherein, subsequent to adding to the resin a basic agent and water to form an emulsion of resin particles, the emulsion has a pH of from about 5 to about 11.

12. A process for preparing toner particles which comprises:

(a) selecting a carbon black;

(b) measuring the surface level of sulfur of the carbon black by X-ray Photoelectron Spectroscopy to ensure that the surface level of sulfur is no more than about 0.05 atomic percent;

(c) generating polyester latex particles by:

(i) providing at least one polyester resin possessing at least one acid group in a reaction vessel;

(ii) neutralizing the at least one acid group by contacting the resin with a base;

(iii) adding water and emulsifying the neutralized resin by contacting the neutralized resin with at least one surfactant in the absence of an organic solvent to provide a latex emulsion containing latex particles; and

(iv) continuously recovering the latex particles;

(d) mixing the carbon black with the polyester latex particles by an emulsion aggregation process to generate a toner composition; and

(e) forming toner particles from the toner composition.

13. A process according to claim 12 wherein the base is selected from ammonium hydroxide, potassium hydroxide, sodium hydroxide, sodium carbonate, sodium bicarbonate, lithium hydroxide, potassium carbonate, triethyl amine, triethanolamine, pyridine, diphenylamine, poly(ethylene amine), or mixtures thereof.

14. A process according to claim 12 wherein the carbon black has an average particle diameter of from about 100 nm to about 300 nm.

Assignments (9)